References
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- The electric polarization at the interface with the isotropic droplet which could be due to ordoelectricity, can be neglected. Its amplitude is at least one order of magnitude smaller than the contribution arising from the other interface, since no parity effect is observed in the measurements of the total polarization of the film versus its number of layers [4]. Let us recall also that the electric polarization of the interface with air probably arises from the reduced polarizability of the aliphatic tips of the molecules in contact with air, resulting from the reduced dielectric constant of their surroundings compared to those in the bulk. Another contribution could also come from the average electropositivity of the molecule. This chemical property always makes the liquid crystal slightly positively charged, as is demonstrated from the slow drift of the droplet towards the negative electrode.
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- Candel , V. and Galerne , Y. , eds. to be published).
- Let us remark that in this experiment, the liquid crystal droplet behaves as a dielectric, and that the electric field is established by means of residual conduction in or at the surface of the glass plate which supports the sample. So, it does not really matter whether the droplet is in contact with the electrodes or not; the electric field E is everywhere equal to the applied voltage divided by the distance between the electrodes.
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