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Ironmaking & Steelmaking
Processes, Products and Applications
Volume 45, 2018 - Issue 2
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Original Articles

Effect of TiO2 on the crystallisation behaviour of CaF2–CaO–Al2O3–MgO slag for electroslag remelting of Ti-containing tool steel

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Pages 135-144 | Received 04 Sep 2016, Accepted 10 Oct 2016, Published online: 06 Nov 2016

References

  • M. H. Zhou: ‘The discussion of the influence of slag system on the Ti loss in the ESR of GH2132’, Special Steel Technol., 2007, 13, (2), 38–40.
  • A. Mitchell: ‘Melting and refining of superalloys and titanium alloys', ISIJ Int., 1992, 32, (5), 557–562. doi: 10.2355/isijinternational.32.557
  • Z. X. Xue, Y. X. Zheng, F. Jiang, Y. Q. Du, B. S. Guo, P. Lin and C. B. Shi: ‘Control of the surface quality and Ti loss of 825 superalloy in drawing-ingot-type electroslag rapid remelting’, Special Steel, 2016, 37, (4), 37–40.
  • Z. H. Jiang and X. Geng: ‘Research on the surface quality of ESR large slab ingots', Adv. Mater. Res., 2011, 146, 670–673. doi: 10.4028/www.scientific.net/AMR.339.670
  • X. C. Lu: ‘Effect of titanium on surface formability of ESR super alloy ingot’, Foundry, 2002, 51, (6), 378.
  • C. B. Shi, J. Li, J. W. Cho, F. Jiang and I. H. Jung: ‘Effect of SiO2 on the crystallization behaviors and in-mold performance of CaF2–CaO–Al2O3 slags for drawing-ingot-type electroslag remelting’, Metall. Mater. Trans. B, 2015, 46, (5), 2110–2120. doi: 10.1007/s11663-015-0402-2
  • W. Li, W. Wang, Y. Hu and Y. Chen: ‘The estimation and control of the electroslag remelting melt rate by mechanism-based modeling’, Metall. Mater. Trans. B, 2012, 43, (2), 276–289. doi: 10.1007/s11663-011-9606-2
  • J. L. Li, Q. F. Shu, X. M. Hou and K. Chou: ‘Effect of TiO2 addition on crystallization characteristics of CaO–Al2O3-based mold fluxes for high Al steel casting’, ISIJ Int., 2015, 55, (4), 830–836. doi: 10.2355/isijinternational.55.830
  • Z. Q. Hao, W. Q. Chen, C. Lippold and H. X. Mao: ‘Effect of titania content on physicochemical properties of mold flux in titanium stabilized stainless steel’, The Chin. J. Process. Eng., 2009, 9, (3), 514–518.
  • H. Nagata and K. Nagata: ‘Crystallization of CaO–SiO2–TiO2 slag as a candidate for fluorine free mold flux’, ISIJ Int., 2006, 46, (3), 441–449. doi: 10.2355/isijinternational.46.345
  • L. S. Li, X. R. Wu, L. Yu and Y. C. Dong: ‘Effect of TiO2 on crystallization of V concentrating phase in V bearing steelmaking slag’, Ironmaking Steelmaking, 2008, 35, (5), 367–370. doi: 10.1179/174328108X284561
  • Y. Kashiwaya, C. E. Cicutti, A. W. Cramb and K. Ishii: ‘Development of double and single hot thermocouple technique for in situ observation and measurement of mold slag crystallization’, ISIJ Int., 1998, 38, (4), 348–356. doi: 10.2355/isijinternational.38.348
  • Y. Kashiwaya, C. E. Cicutti and A. W. Cramb: ‘An investigation of the crystallization of a continuous casting mold slag using the single hot thermocouple technique’, ISIJ Int., 1998, 38, (4), 357–365. doi: 10.2355/isijinternational.38.357
  • L. J. Zhou, W. L. Wang, D. Y. Huang, J. Wei and J. Li: ‘In situ observation and investigation of mold flux crystallization by using double hot thermocouple technology’, Metall. Mater. Trans. B, 2012, 43, (4), 925–936. doi: 10.1007/s11663-012-9669-8
  • J. X. Gao, G. H. Wen and Q. H. Sun: ‘The influence of Na2O on the solidification and crystallization behavior of CaO-SiO2-Al2O3-based mold flux’, Metall. Mater. Trans. B, 2015, 46, (4), 1850–1859. doi: 10.1007/s11663-015-0366-2
  • B. X. Lu, K. Chen, W. L. Wang and B. Jiang: ‘Effects of Li2O and Na2O on the crystallization behavior of lime-alumina-based mold flux for casting high-Al steels', Metall. Mater. Trans. B, 2014, 45, (4), 1496–1509. doi: 10.1007/s11663-014-0063-6
  • J. Yang, Y. R. Cui, L. Wang, Y. Sasaki, J. Zhang, O. Ostrovski and Y. Kashiwaya: ‘In-situ study of crystallization behavior of a mold flux using single and double hot thermocouple technique’, Steel Res. Int., 2015, 86, (6), 636–643. doi: 10.1002/srin.201400346
  • B. X. Lu and W. L. Wang: ‘Effects of fluorine and BaO on the crystallization behavior of lime-alumina-based mold flux for casting high-Al steels', Metall. Mater. Trans. B, 2015, 46, (2), 825–862. doi: 10.1007/s11663-014-0285-7
  • Q. F. Shu, Z. Wang, J. L. Klug, K. Chou and P. R. Scheller: ‘Effects of B2O3 and TiO2 on crystallization behavior of slags in Al2O3–CaO–MgO–Na2O–SiO2 system’, Steel Res. Int., 2013, 84, (11), 1138–1145. doi: 10.1002/srin.201200341
  • C. B. Shi, M. D. Seo, H. Wang, J. W. Cho and S. H. Kim: ‘Crystallization kinetics and mechanism of CaO–Al2O3-based mold flux for casting high-aluminum TRIP steels', Metall. Mater. Trans. B, 2015, 46, (1), 345–356. doi: 10.1007/s11663-014-0180-2
  • B. X. Lu, W. L. Wang, J. Li, H. Zhao and D. Y. Huang: ‘Effects of basicity and B2O3 on the crystallization and heat transfer behaviors of low fluorine mold flux for casting medium carbon steels', Metall. Mater. Trans. B, 2013, 44, (2), 365–377. doi: 10.1007/s11663-012-9784-6
  • J. Wei, W. L. Wang, L. J. Zhou, D. Y. Huang, H. Zhao and F. J. Ma: ‘Effect of Na2O and B2O3 on the crystallization behavior of low fluorine mold fluxes for casting medium carbon steels', Metall. Mater. Trans. B, 2014, 45, (2), 643–652. doi: 10.1007/s11663-013-9957-y
  • C. B. Shi, M. D. Seo, J. W. Cho and S. H. Kim: ‘Crystallization characteristics of CaO–Al2O3-based mold flux and their effects on in-mold performance during high-aluminum TRIP steels continuous casting’, Metall. Mater. Trans. B, 2014, 45, (3), 1081–1097. doi: 10.1007/s11663-014-0034-y
  • C. B. Shi, D. L. Zheng, S. H. Shin, J. W. Cho and J. Li: ‘Effect of TiO2 on the viscosity and structure of ESR-type TiO2-containing slag’, Int. J. Miner. Metall. Mater., 2016 (accepted).
  • J. W. Cho, T. Emi, H. Shibata and M. Suzuki: ‘Heat transfer across mold flux film in mold during initial solidification in continuous casting of steel’, ISIJ Int., 1998, 38, (8), 834–842. doi: 10.2355/isijinternational.38.834
  • M. Hayashi, R. A. Abas and S. Seetharaman: ‘Effect of crystallinity on thermal diffusivities of mould fluxes for the continuous casting of steels', ISIJ Int., 2004, 44, (4), 691–697. doi: 10.2355/isijinternational.44.691
  • C. B. Shi, J. W. Cho, D. L. Zheng and J. Li: ‘Fluoride evaporation and crystallization behavior of CaF2–CaO–Al2O3–(TiO2) slag for electroslag remelting of Ti-containing steels', Int. J. Miner. Metall. Mater., 2016, 23, (6), 627–636. doi: 10.1007/s12613-016-1275-3
  • M. Avrami: ‘Kinetics of phase change. I general theory’, J. Chem. Phys., 1939, 7, (12), 1103–1112. doi: 10.1063/1.1750380
  • M. Avrami: ‘Kinetics of phase change. II transformation-time relations for random distribution of nuclei’, J. Chem. Phys., 1940, 8, (2), 212–224. doi: 10.1063/1.1750631
  • M. Avrami: ‘Granulation, phase change, and microstructure kinetics of phase change. III’, J. Chem. Phys., 1941, 9, (2), 177–184. doi: 10.1063/1.1750872
  • M. D. Seo, C. B. Shi, J. Y. Baek, J. W. Cho and S. H. Kim: ‘Kinetics of isothermal melt crystallization in CaO–SiO2–CaF2-based mold fluxes', Metall. Mater. Trans. B, 2015, 46, (5), 2374–2383. doi: 10.1007/s11663-015-0358-2

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