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Original Articles

ASYMMETRIC REDUCTION OF CHIRAL SULFOXIDES BY OPTICALLY ACTIVE LITHIUM ALUMINUM HYDRIDE COMPLEXES WITH ALCOHOLS

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Pages 301-303 | Received 03 Oct 1974, Published online: 13 Dec 2006

References

  • Mikolajczyk , M. and Drabowicz , J. 1974 . Synthesis , : 124 Part IV of the series “Organosulphur compounds” part III
  • Morrison , J. D. and Mosher , H. S. 1971 . “Asymmetric Organic Reactions” , 335 – 362 . Englewood Cliffs, New Jersey : Prentice-Hall, Inc. .
  • Balenovic , K. and Bregant , N. 1964 . Chem. and Ind. , 1577
  • Mikolajczyk , M. and Para , M. 1969 . Chem. Commun. , 1192
  • A similar approach has been used by Holt et al. 6 to prepare new optically active organosilicon compounds.
  • Holt , A. , Jarvie , A. W. P. and Jervis , G. J. 1968 . Tetrahedron Letters , : 4087 J. Chem. Soc., Perkin II, 114 (1973)
  • Bordwell , F. G. and McKellin , M. H. 1951 . J. Am. Chem. Soc. , 73 : 2251 E. N. Karaulova and G. D. Halpern, Zhur. Obs. Khim., 29, 3033 (1959); H. C. Brown, P. M. Weissman, and N. M. Yoon, J. Am. Chem. Soc., 88, 1458 (1966)
  • See ref. 2 pp. 202–218
  • Henson , P. D. , Nauman , K. and Mislow , K. 1969 . J. Am. Chem. Soc. , 91 : 5645
  • Hunig , S. and Boes , O. 1953 . Ann. , 579 : 23 D. Jerchel, L. Dippelhofer, and D. Renner, Chem. Ber., 87, 947 (1954)
  • Negative result obtained with the sulfoxides 1a and 1f may be due to small differences in the reactivity of enantiomers towards the chiral reducing complex.

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