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Original Articles

THE SYNTHESIS AND CHARACTERIZATION OF BORANE(3) COMPLEXES OF 1,3-DI(TERTBUTYL)2,4-DIFLUORODIAZADIPHOSPHETIDINE. THE CRYSTAL AND MOLECULAR STRUCTURE OF THE BIS BORANE(3) COMPLEX

, &
Pages 279-284 | Received 09 Jan 1980, Accepted 31 Mar 1980, Published online: 19 Dec 2006

References

  • Haiduc , I. 1970 . The Chemistry of Inorganic Ring Systems , New York : J. Wiley . Reviews outlining some aspects of diazadiphosphetidine ligand chemistry have appeared: R. A. Shaw, Phosphorus and Sulfur, 4, 101 (1978), Part 2
  • Hawker , P. N. , Jenkins , L. S. and Willey , G. R. 1976 . J. Organomet. Chem. , 118 : C14
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  • King , R. B. and Gimeno , J. 1977 . Chem. Commun. , : 142 M. G. Newton, R. B. King, M. Chang, and J. Gimeno, J. Amer. Chem., Soc., 99, 2802 (1977); R. B. King, M. G. Newton, J. Gimeno, and M. Chang, Inorg. Chim. Acta, 23, L35 (1977); R. B. King and K. N. Chen, Inorg. Chim. Acta, 23, L19 (1977); M. G. Newton, R. B. King, M. Chang, N. S. Pantaleo, and J. Gimeno, Chem. Commun., 531 (1977); M. G. Newton, R. B. King, M. Chang, and J. Gimeno, J. Amer. Chem. Soc., 100, 1632 (1978); M. Chang, M. G. Newton, and R. B. King, Inorg. Chim. Acta, 30, L341 (1978); R. B. King and J. Gimeno, Inorg. Chem., 17, 2390 (1978); R. B. King and J. Gimeno, Inorg. Chem., 17, 2396 (1978) and R. B. King, J. Gimeno, and T. J. Lotz;, Inorg. Chem., 17, 2401 (1978)
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  • The parent ion regions of the borane complexes are not intense or well resolved. The ion intensities for the parent ion minus hydrogen from the borane group are integrated together
  • The infrared spectrum (cm−1) for a liquid thin film of 1 shows the following absorption: 3000–2825(s, br), 1463(m), 1393(m), 1368(s), 1310(w), 1245(m), 1210(s), 1130(w), 1040(s), 933(s), 912(s), 850(w), 810(sh), 800(m), 750(s), 718(s), 640(m), 590(m), 540(w), 440(m), 385(m), 355(w). The B-P stretching modes can be tentatively assigned at 538 cm−1 for 2 and 525 cm−1 for 3. These frequencies are about 50 cm−1 lower than the frequencies observed in the mono-borane(3) and bis-borane(3) complexes of (F2P)2NCH3.4
  • Campana , C. F. , Sheppard , D. F. and Litchman , W. N. Inorg. Chem. , submitted to
  • All X-ray structure calculations were performed using the Syntex XTL Structure Determination Package
  • Fleming , S. , Lupton , M. K. and Jekot , K. 1972 . Inorg. Chem. , 11 : 2534
  • Jessup , J. , Byers , D. and Paine , R. T. unpublished results
  • Muir , K. W. 1975 . J. Chem. Soc. (Dalton) , : 259
  • Manojlovic-Muir , L. and Muir , K. W. 1974 . J. Chem. Soc. (Dalton) , : 2395
  • Cruickshank , D. W. J. 1964 . Acta Cryst. , 17 : 671
  • Peterson , M. B. and Wagner , A. J. 1973 . J. Chem. Soc., (Dalton) , : 106
  • LaPrade , M. D. and Nordman , C. E. 1969 . Inorg. Chem. , 8 : 1669

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