SYNTHESIS, REACTIONS, AND STEREOCHEMICAL CORRELATIONS OF AN OPTICALLY ACTIVE TERVALELENT PHOSPHORUS THIO ESTER

References

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• In Scheme 1, the reagents are designated only for those reactions which are first reported at this time
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• The previously assigned9 value of [∝]D-24° (benzene(for 100% ee (—(-2 was based upon its conversion into (+(-Me(i-PrO(P(S(CI (7(, which had been erroneously assumed to have [∝]D-69.9° (CCI4(for 100% ee material. While the specific rotation for 7 was reported9 only for a chloroform solution, values of [∝]D + 66.0° (benzene(and [∝]D + 77.7° (neat, 1 dcm(also had been recorded (L. P. Reiff, unpublished data(. However, this sample was apparently only 78.5% ee, because 100% ee 7 has since been tentatively assigned as [∝]D + 98.9° (neat, 1 dcm).10
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