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Original Articles

Dynamic Model of the Homopolymerization of Propylene with the Me2Si(2-Me-Ind)2ZrCl Catalyst: The Effect of Reaction Variables

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Pages 85-94 | Published online: 14 Feb 2007

REFERENCES

  • Kaminsky , W. Polymerization catalysis . Catal. Today 2000 , 62 ( 1 ), 23 – 34 . [CSA]
  • Kaminsky , W. ; Laban , A. Metallocene catalysis . Appl. Catal. A-Gen. 2001 , 222 , 47 – 61 . [CSA] [CROSSREF]
  • Gladysz , J.A. Frontiers in metal-catalyzed polymerization: designer metallocenes, designs on ner monomers, demystifing MAO, metathesis déshabillé . Chem. Rev. 2000 , 100 ( 4 ), 1167 – 1168 . [PUBMED] [INFOTRIEVE] [CSA] [CROSSREF]
  • Ewen , J. ; Jones , R. ; Razavi , A. ; Ferrara , J. Syndiospecific propylene polymerizations with Group IVB metallocenes . J. Am. Chem. Soc. 1988 , 110 ( 18 ), 6255 – 6256 . [CSA] [CROSSREF]
  • Kukral , J. ; Lehmus , P. ; Feifel , T. ; Troll , C. ; Rieger , B. Dual-side ansa-zirconocene dichlorides for high molecular weight isotactic polypropene elastomers . Organometallics 2000 , 19 ( 19 ), 3767 – 3775 . [CSA] [CROSSREF]
  • Ewen , J.A. ; Elder , M.J. ; Jones , R.L. ; Rheingold , A.L. ; Liable-Sands , L.M. ; Sommer , R.D. Chiral ansa metallocenes with Cp ring-fused to thiophenes and pyrroles: syntheses, crystal structures, and isotactic polypropylene catalysts . J. Am. Chem. Soc. 2001 , 123 ( 28 ), 4763 – 4773 . [PUBMED] [INFOTRIEVE] [CSA] [CROSSREF]
  • Bubeck , R.A. Structure-properties relationships in metallocene polyethylenes . Mater. Sc. and Eng. R: Reports 2002 , 39 ( 1 ), 1 – 28 . [CSA] [CROSSREF]
  • Resconi , L. ; Cavallo , L. ; Fait , A. ; Piemontesi , F. Selectivity in propene polymerization with metallocene catalysts . Chem. Rev. 2000 , 100 ( 4 ), 1253 – 1346 . [PUBMED] [INFOTRIEVE] [CSA] [CROSSREF]
  • Huang , J. ; Rempel , G. Ziegler-Natta catalysts for olefin polymerization: mechanistic insights from metallocene systems, Prog . Polym. Sci. 1995 , 20 ( 3 ), 459 – 526 . [CSA]
  • Ochoteco , E. ; Vecino , M. ; Montes , M. ; de la Cal . Kinetics and properties in metallocene catalysed propene polymerizations . Chem. Eng. Sci. 2001 , 56 ( 13 ), 4169 – 4179 . [CSA] [CROSSREF]
  • Matos , V. ; Mattos , A. ; Nele , M. ; Pinto , J. Method for quantitative evaluation constants in olefin polymerizations . II. Kinetic study of a high-activity Ziegler-Natta catalyst used for bulk propylene polymerization. J. Appl. Polym. Sci. 2002 , 86 ( 13 ), 3226 – 3245 . [CSA]
  • Guevara , J. ; Quijada , R. ; Saavedra , P. ; Palza , H. ; Galland , G. Estudio de la polimerización de propeno utilizando diferentes catalizadores metalocenos . Bol. Soc. Chil. Quim. 2002 , 47 , 81 – 90 . [CSA]
  • Chen , E. ; Marks , T. Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure-activity relationships . Chem. Rev. 2000 , 100 ( 4 ), 1391 – 1434 . [PUBMED] [INFOTRIEVE] [CSA] [CROSSREF]
  • Fischer , D. ; Mulhaupt , R. Reversible and irreversible deactivation of propene polymerization using homogeneous Cp2ZrCl2/methylaluminoxane Ziegler-Natta catalysts . J. Organomet. Chem. 1991 , 417 (1–2) , C7 – C11 . [CSA] [CROSSREF]
  • Brintzinger , H. ; Fisher , D. ; Mulhaupt , R. ; Rieger , B. ; Waymouth , R. Stereospecific olefin polymerization with chiral metallocene catalysts . Angew. Chem. Int. Ed. Engl. 1995 , 34 , 1143 – 1170 . [CSA] [CROSSREF]
  • Chaves , E.G. ; Marquez , M.G. Effect of experimental conditions on propylene polymerization with ethylene (fluorenyl) (cyclopentadienyl) zirconium dichloride/methylalminoxane catalyst system . Eur. Poly. J. 2001 , 37 ( 6 ), 1175 – 1180 . [CSA] [CROSSREF]
  • D'Agnillo , L. ; Soares , J. ; Pendilis , A. Controlling molecular weight distributions of polyethylene by combining soluble metallocene/MAO catalyst . J. Polym. Sci. Pol. Chem. 1998 , 36 ( 5 ), 831 – 840 . [CSA] [CROSSREF]
  • Chien , J. ; Yu , Z. ; Marques , M. ; Flores , J. ; Rausch , M. Polymerization of olefins and diolefins catalyzed by monocyclopentadienyltitanium complexes containing a (dimethylalumino)ethyl substituent and comparison with ansa-zirconocene systems . J. Polym. Sci. Pol. Chem. 1998 , 36 ( 2 ), 319 – 328 . [CSA] [CROSSREF]
  • Fait , A. ; Resconi , L. ; Guerra , G. ; Corradini , P. A possible interpretation of the nonlinear propagation rate laws for insertion polymerization: a kinetic model based on a single-center, two-state catalyst. Macromolecules 1999, 32 (7), 2104–2109. [CSA] [CROSSREF]
  • Fischer , D. ; Jungling , S. ; Mulhaupt , R. Donor- and acceptor-modified metallocene-based homogeneous Ziegler-Natta catalyst . Makromol. Chem. Macromol. Symp. 1993 , 66 , 191 – 202 . [CSA]
  • Vela Estrada , J.L. ; Hamielec , A. Modelling of ethylene polymerization with Cp2ZrCl2/MAO catalyst . Polymer 1994 , 35 ( 4 ), 808 – 818 . [CSA] [CROSSREF]
  • Soares , J. Mathematical modelling of the microstructure of polyolefins made by coordination polymerization: a review . Chem. Eng. Sci. 2001 , 56 ( 13 ), 4131 – 4153 . [CSA] [CROSSREF]
  • Soares , J. Polyolefins with long chain branches made with single-site coordination catalysts: a review of mathematical modeling techniques for polymer microstrusture . Macromol. Mater. Eng. 2004 , 289 ( 1 ), 70 – 87 . [CSA] [CROSSREF]
  • Choi , K. ; Tang , S. ; Sirohi , A. Estimation of kinetic parameters in transition-metal-catalyzed gas olefin copolymerization processes . Ind. Eng. Chem. Res. 1997 , 36 ( 4 ), 1095 – 1102 . [CSA] [CROSSREF]
  • Beigzadeh , D. ; Soares , J. ; Hamielec , A. Recipes for synthesizing polyolefins with tailor-made molecular weight, polydispersity index, long-chain branching frequencies, and chemical composition using combined metallocene system in a CSTR at steady state . J. Appl. Polym. Sci. 1999 , 71 ( 11 ), 1753 – 1770 . [CSA] [CROSSREF]
  • Zacca , J. ; Debling , J. ; Ray , H. Reactor residence-time distribution effects on the effects on the multistage polymerization of olefins . II. Polymer properties: bimodal polypropylene and linear low-density polyethylene. Chem. Eng. Sci. 1997 , 52 ( 12 ), 1941 – 1967 . [CSA]
  • Box , G. ; Hunter , W. ; Hunter , J. Statistics for Experiments , Wiley : New York , 1978 .
  • Collins , S. ; Kunts , B.A. ; Taylor , N.J. ; Ward , D.G. X-ray structures of ethylenebis(tetrahydroindenyl)-titanium and zirconium dichlorides: a revision . J. Organomet. Chem. 1988 , 342 ( 1 ), 21 – 40 . [CSA] [CROSSREF]
  • Bravakis , A.M. ; Bailey , A.L. ; Pigeon , M. ; Collins , S. Synthesis of elastomeric poly(propylene) using unsymmetrical zirconocene catalysts: marked reactivity differences of “rac” and “meso”-like diastereomers . Macromolecules 1998 , 31 ( 4 ), 1000 – 1009 . [CSA] [CROSSREF]
  • Koltzenburg , S. The influence of methylaluminoxane (MAO) on the isoselective propene polymerization with the homogeneous metallocene Me2Si(Benz[e]Ind)2 . J. Mol. Catal. A-Chem. 1997 , 116 ( 3 ), 355 – 363 . [CSA] [CROSSREF]
  • Kleinschmidt , R. ; van der Leek , Y. ; Reffke , M. ; Fink , G. Kinetics and mechanistic insight into propylene polymerization with different metallocenes and various aluminium alkyls as cocatalysts . J. Mol. Catal. A-Chem. 1999 , 148 (1–2) , 29 – 41 . [CSA] [CROSSREF]
  • Tekie , J. ; Mizan , T. ; Morsi , B. ; Maier , E. ; Singh , C. Gas-liquid mass transfer in a slurry reactor operating under olefinic polymerization process conditions . Chem. Ing. Sci. 1996 , 51 ( 4 ), 549 – 559 . [CSA]
  • Kaminsky , W. ; Kulper , K. ; Niedoba , S. Olefin polymerization with highly active soluble zirconium compounds using aluminoxan as cocatalyst . Makromol. Chem. Macromol. Symp. 1986 , 3 (1) , 377 . [CSA]
  • Kaminsky , W. New polymers by metallocene catalysis . Macromol. Chem. Phys. 1996 , 197 ( 12 ), 3907 – 3945 . [CSA] [CROSSREF]

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