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Original Articles

Studies on the Thermal Behavior of Polyurethanes

, , , &
Pages 95-108 | Published online: 14 Feb 2007

REFERENCES

  • Ravey , M. ; Pearce , E.M. Flexible polyurethane foam. I. Thermal decomposition of a polyether-based, water-blown commercial type of flexible polyurethane foam . J. Appl. Polym. Sci. 1997 , 63 ( 1 ), 47 – 74 . [CSA]
  • Dyer , E. ; Newborn , G.E. Thermal decomposition of carbamates of methylenebis-(4-phenyl isocyanate) . J. Amer. Chem. Soc. 1958 , 80 , 5495 – 5498 . [CSA] [CROSSREF]
  • Herzog , K. Decomposition behavior of polyurethane studied by linear temperature programmed pyrolysis FTIR spectroscopy . Makromol. Chem. Macromol. Symp. 1991 , 52 , 307 – 312 . [CSA]
  • Yoshitake , N. ; Furukawa , M. Thermal decomposition mechanism of alpha, gamma-diphenyl alkyl allophanate as a model polyurethane by pyrolysis high-resolution gas chromatography/FT-IR . J. Anal. Appl. Pyrolysis 1995 , 33 , 269 – 281 . [CSA] [CROSSREF]
  • Grassie , N. ; Zulfiqar , M. Thermal decomposition of polyurethane from 1,4-butanediol and methylene bis(4-phenyl isocyanate) . J. Polym. Sci. Part A: Polym. Chem. 1978 , 16 ( 7 ), 1563 – 1574 . [CSA]
  • Grassie , N. ; Zulfiqar , M. ; Guy , M. Thermal decomposition of a series of polyester polyurethanes . J. Polym. Sci. Part A: Polym. Chem. 1980 , 18 ( 1 ), 265 – 274 . [CSA]
  • Chambers , J. ; Jiricny , J. ; Reese , C.B. The thermal decomposition of polyurethanes and polyisocyanurates . Fire Mater. 1981 , 5 ( 4 ), 133 – 141 . [CSA] [CROSSREF]
  • Hobbs , M.L. ; Erickson , K.L. ; Chu , T.Y. Modeling decomposition of unconfined rigid polyurethane foam . Polym. Deg. Stab. 2000 , 69 , 47 – 66 . [CSA] [CROSSREF]
  • Branca , C. ; Di Blasi , C. ; Casu , A. ; Morone , V. ; Costa , C. Reaction kinetics and morphological changes of a rigid polyurethane foam during combustion . Thermo. Acta 2003 , 399 , 127 – 137 . [CSA] [CROSSREF]
  • Bilbao , R. ; Mastral , J.F. ; Ceamanos , J. ; Aldea , M.E. Kinetics of the thermal decomposition of polyurethane foams in nitrogen and air atmospheres . J. Anal. Appl. Pyrolysis 1996 , 37 , 69 – 82 . [CSA] [CROSSREF]
  • Benbow , A.W. ; Cullis , C.F. Combustion of flexible polyurethane foams—mechanisms and evaluation of flame retardance . Comb. Flame 1975 , 24 ( 2 ), 217 – 230 . [CSA] [CROSSREF]
  • Ohlemiller , T.J. ; Bellan , J. ; Rogers , F. Model of smoldering combustion applied to flexible polyurethane foams . Comb. Flame 1979 , 36 ( 2 ), 197 – 215 . [CSA] [CROSSREF]
  • Dosanjh , S.S. ; Pagni , P.J. ; Fernandez-Pello , A.C. Forced concurrent smoldering combustion . Comb. Flame 1987 , 68 ( 2 ), 131 – 142 . [CSA] [CROSSREF]
  • Font , R. ; Fullana , A. ; Caballero , J.A. ; Candela , J. ; Gercia , A. Pyrolysis study of polyurethane . J. Anal. Appl. Pyrolysis 2001 , 63 , 58 – 59 . [CSA]
  • Esperanza , M.M. ; García , A.N. ; Font , R. ; Conesa , J.A. Pyrolysis of varnish wastes based on a polyurethane . J. Anal. Appl. Pyrolysis 1999 , 52 ( 2 ), 151 – 166 . [CSA] [CROSSREF]
  • Mequanint , K. ; Sanderson , R. ; Pasch , H. Thermogravimetric study of phosphated polyurethane ionomers. Polym. Deg. Stab. 2002, 77 (1), 121–128. [CSA] [CROSSREF]
  • Zhang , T.L. ; Hu , R.Z. ; Li , F.P. A method to determine the nonisothermal kinetic-parameters and select the most probable mechanism function using a single nonisothermal DSC curve . Thermo. Acta 1994 , 244 , 177 – 184 . [CSA] [CROSSREF]
  • Hu , R.Z. ; Zhengquan , Y. ; Yanjun , L. The determination of the most probable mechanism function and three kinetic parameters of exothermic decomposition reaction of energetic materials by a single non-isothermal DSC curve . Thermo. Acta 1988 , 123 , 135 – 151 . [CSA] [CROSSREF]
  • Coats , A.W. ; Redfern , J.P. Kinetic parameters from thermogravimetrc data . Nature 1964 , 201 , 68 – 69 . [CSA]
  • Sharp , J.H. ; Wendworth , S.A. Kinetic analysis of thermogravimetric data . Analy. Chem. 1969 , 41 , 2060 – 2062 . [CSA] [CROSSREF]
  • Bourbigot , S. ; LeBras , M. ; Delobel , R. ; Decressain , R. ; Amoureux , J.P. Synergistic effect of zeolitein in intumescence process: study of the carbonaceous structures using solid state NMR . J. Chem. Soc.—Faraday. Trans. 1996 , 92 ( 1 ), 149 – 158 . [CSA] [CROSSREF]
  • Delobel , R. ; Lebras , M. ; Ouassou , N. ; Alistiqsa , F. Thermal behaviors of ammonium polyphosphate-pentaerythritol and ammonium pyrophosphate-pentaerythritol intumescent additives in polypropylent formulations . J. Fire Sci. 1990 , 8 ( 2 ), 85 – 108 . [CSA]
  • Duquesne , S. ; Delobel , R. ; Lebras , M. ; Camino , G. A comparative study of the mechanism of action of ammonium polyphosphate and expandable graphite in polyurethane . Polym. Deg. Stab. 2002 , 77 ( 2 ), 333 – 344 . [CSA] [CROSSREF]
  • Gajewski , V. Chemical decomposition of polyurethane . Rubb. World 1990 , 202 ( 6 ), 15 . [CSA]
  • Liu , L.B. Heat resistant property of polyurethane elastomer . Elastomer 1999 , 9 , 41 – 47 (Chinese) . [CSA]
  • Singh , A. Effect of chemical structure on the thermal stability of crosslinked urethane elastomers . Adv. Urethane. Sci. Tech. 1971 , 1 , 95 . [CSA]
  • Duchacek , V. Recent developments for thermoplastic elastomers . J. Macromol. Sci.—Phys. B 1998 , 37 ( 2 ), 275 – 282 . [CSA]
  • Fang , Y.S. ; Zhu , L.M. Polyurethane Foams , Chemical Industry Press : Beijing , 1994 .
  • Syrop , H. An improved method for the flame retardance of urethane foams with low smoke generation . Adv. Urethane. Sci. Tech. 1976 , 4 , 176 – 197 . [CSA]
  • Schell , S.H. ; Gibbons , C. ; Petrella , R.V. The effect of neopentyl alcohols on the flame and smoke resistance of flexible urethane foams . Adv. Urethane. Sci. Tech. 1976 , 4 , 198 – 211 . [CSA]
  • Pielichowski , K. ; Slotwinska , D. Morphological features and flammability of MDI/HMDI-based segmented polyurethanes containing 3-chloro-1,2-propanediol in the main chain . Polym. Deg. Stab. 2003 , 80 ( 2 ), 327 – 331 . [CSA] [CROSSREF]
  • Horrocks , A.R. ; Price , D. Fire Retardant Materials , Woodhead Publishing : Cambridge , 2001 .
  • Pinto , U.A. ; Visconte , L.L.Y. ; Nunes , R.C.R. Mechanical properties of thermoplastic polyurethane elastomers with mica and aluminum trihydrate . Euro. Polym. J. 2001 , 37 ( 9 ), 1935 – 1937 . [CSA] [CROSSREF]
  • Richard , E.L. Pyrolysis kinetics of char forming polymers . Polym. Deg. Stab. 1998 , 61 ( 2 ), 201 – 210 . [CSA] [CROSSREF]
  • Modestio , M. ; Lorenzattio , A. ; Simionio , F. ; Checcino , M. Influence of different flame retardants on fire behaviour of modified PIR/PUR polymers . Polym. Deg. Stab. 2001 , 74 , 475 – 479 . [CSA] [CROSSREF]
  • Matuschek , G. Thermal decomposition of different fire retardant polyurethane foams . Thermo. Acta 1995 , 263 , 59 – 71 . [CSA] [CROSSREF]
  • Wang , P.S. ; Chiu , W.Y. ; Chen , L.W. ; Deng , B.L. ; Don , T.M. ; Chiu , Y.S. Thermal degradation behavior and flammability of polyurethanes blended with poly(bispropoxyphosphazene) . Polym. Deg. Stab. 1999 , 66 ( 3 ), 307 – 315 . [CSA] [CROSSREF]
  • Horacek , H. ; Grabner , R. Advantages of flame retardants based on nitrogen compounds, Polym . Deg. Stab. 1996 , 54 , 205 – 215 . [CSA] [CROSSREF]

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