Inferential Conversion and Composition Monitoring via Microcalorimetric Measurements in Emulsion Terpolymerization

REFERENCES

• Barandiaran , M.J. ; Lopez de Arbina , L. ; de la Cal , J.C. ; Gugliotta , L.M. ; Asua , J.M. Parameter estimation in emulsion copolymerization using reaction calorimeter data . J. Appl. Polym. Sci. 1995 , 55 ( 8 ), 1231 – 1239
   Google Scholar
• Brandrup , J. ; Immergut , E.H. Polymer Handbook, , 3rd Ed. , Wiley : New York , 1989.
   Google Scholar
• Canegallo , S. ; Canu , P. ; Morbidelli , M. ; Storti , G. Composition control in emulsion copolymerization . II. Application to binary and ternary systems. J. of Appl. Polym. Sci. 1994 , 54 ( 12 ), 1919 – 1935 .
   Google Scholar
• Canegallo , S. ; Storti , G. ; Morbidelli , M. ; Carra , S. Densimetry for on-line conversion monitoring in emulsion homo- and copolymerization . J. of Appl. Polym. Sci. 1993 , 47 ( 6 ), 961 – 979 .
   Google Scholar
• deBuruaga , I.S. ; Echevarria , A. ; Armitage , P.D. ; delaCal , J.C. ; Leiza , J.R. ; Asua , J.M. On-line control of a semibatch emulsion polymerization reactor based on calorimetry . Aiche J. 1997 , 43 ( 4 ), 1069 – 1081 .
   Google Scholar
• Gugliotta , L.M. ; Vega , J.R. ; Antonione , C.E. ; Meira , G.R. Emulsion copolymerization of acrylonitrile and butadiene in an industrial batch reactor . Estimation of conversion and polymer quality from on-line energy measurements. Polym. React. Eng. 1999 , 7 ( 4 ), 531 – 552 .
   Google Scholar
• Guinot , P. ; Othman , N. ; Fevotte , G. ; McKenna , T.F. On-line monitoring of emulsion copolymerisations using hardware sensors and calorimetry . Polym. React. Eng. 2000 , 8 ( 2 ), 115 – 134 .
   Web of Science ®Google Scholar
• Guyot , A. ; Guillot , J. ; Graillat , C. ; Llauro , M.F. Controlled composition in emulsion copolymerization application to butadiene-acrylonitrile copolymers . J. of Macromol. Sci. Chem. 1984 , A21 ( 6–7 ), 683 – 699 .
   Google Scholar
• Kiparissides , C. ; Morris , J. Intelligent manufacturing of polymers . Comput. Chem. Eng. 1996 , 20 , S1113 – S1118 .
   Web of Science ®Google Scholar
• Leiza , J.R. ; Cal , J.R.d.l. ; Montes , M. ; Asua , J.M. On-line monitoring of conversion and polymer composition in emulsion polymerization systems . Process Contr. and Qual. 1993 , 4 ( 3 ), 197 – 210 .
   Google Scholar
• Othman , N. ; Fevotte , G. ; McKenna , T.F. On-line monitoring of emulsion terpolymerization processes . Polym. React. Eng. 2001 , 9 ( 4 ), 271 – 296 .
   Web of Science ®Google Scholar
• Santos , A.M. ; Fevotte , G. ; Othman , N. ; Othman , S. ; McKenna , T.F. On-line monitoring of methyl methacrylate-vinyl acetate emulsion copolymerization . J. of Appl. Polym. Sci. 2000 , 75 ( 13 ), 1667 – 1683 .
   Google Scholar
• Schoonbrood , H.A.S. ; Thijssen , H.A. ; Brouns , H.M.G. ; Peters , M. ; German , A.L. Semicontinuous emulsion copolymerization to obtain styrene-methyl acrylate copolymers with predetermined chemical composition distributions . J. of Appl. Polym. Sci. 1993 , 49 ( 11 ), 2029 – 2040 .
   Google Scholar
• Urretabizkaia , A. ; Arzamendi , G. ; Asua , J.M. Modeling semicontinuous emulsion terpolymerization . Chem. Eng. Sci. 1992 , 47 ( 9–11 ), 2579 – 2584 .
   Google Scholar
• Urretabizkaia , A. ; Leiza , J.R. ; Asua , J.M. Online terpolymer composition control in semicontinuous emulsion polymerization . Aiche J. 1994 , 40 ( 11 ), 1850 – 1864 .
   Web of Science ®Google Scholar
• Urretabizkaia , A. ; Sudol , E.D. ; El-Aasser , M.S. ; Asua , J.M. Calorimetric monitoring of emulsion copolymerization reactions . J. Polym. Sci. Pol. Chem. 1993 , 31 ( 12 ), 2907 – 2913 .
   Google Scholar
• Vandoremaele , G.H.J. ; Schoonbrood , H.A.S. ; Kurja , J. ; German , A.L. Copolymer composition control by means of semicontinuous emulsion copolymerization . J. Appl. Polym. Sci. 1992 , 45 ( 6 ), 957 – 966 .
   Google Scholar
• Vega , J.R. ; Gugliotta , L.M. ; Meira , G.R. Emulsion copolymerization of acrylonitrile and butadiene. Semibatch strategies for controlling molecular structure on the basis of calorimetric measurements . Polym. React. Eng. 2002 , 10 ( 1–2 ), 59 – 82 .
   Web of Science ®Google Scholar
• Zeaiter , J. ; Gomes , V.G. ; Barton , G.W. ; Romagnoli , J.A. ; Gilbert , R.G. Strategies for optimisation and control of molecular weight and particle size distributions in emulsion polymerisation . Comput. Chem. Eng. 2001 , 9 , 823 – 828 .
   Google Scholar