Benefits and limitations of using isotope-derived groundwater travel times and major ion chemistry to validate a regional groundwater flow model: example from the Centre-du-Québec region, Canada

References

• Aravena, R., W. Leonard, and P. Niel. 1995. Estimating 14C groundwater ages in a methanogenic aquifer. Water Resources Research 31 (9): 2307–2317.
   Web of Science ®Google Scholar
• Arnold, J. G., and P. M. Allen. 1995. Automated methods for estimating baseflow and ground water recharge from streamflow records. Journal of the American Water Resources Association 35 (2): 411–424.
   Google Scholar
• Beckers, J., and E. O. Frind. 2001. Simulating groundwater flow and runoff for the Oro Moraine aquifer system. Part II. Automated calibration and mass balance calculations. Journal of hydrology 243: 73–90.
   Web of Science ®Google Scholar
• Benoit, N., D. Blanchette, M. Nastev, V. Cloutier, D. Marcotte, M. Brun Kone, and J. Molson. 2011. Groundwater geochemistry of the lower Chaudière River watershed, Québec. In: GeoHydro2011, Joint IAH-CNC, CANQUA and AHQ Conference, Québec City, Canada, August 28-31, 2011, Paper DOC-2209, 8 pp.
   Google Scholar
• Blanchette, D., R. Lefebvre, M. Nastev, and V. Cloutier. 2013. Groundwater quality, geochemical processes and groundwater evolution in the Chateauguay River watershed, Quebec, Canada. Canadian Water Resources Journal 35 (4): 503–526.
   Google Scholar
• Bolduc, A. M., and M. Ross. 2001. Surficial geology, Lachute-Oka, Québec. Geological Survey Canada. Open File 3520. https://doi.org/10.4095/212599.
   Google Scholar
• Brunner, P., C. T. Simmons, P. G. Cook, and R. Therrien. 2010. Modeling surface water-groundwater interaction with MODFLOW: Some considerations. Ground Water 48 (2): 174–180.
   PubMedGoogle Scholar
• Castro, M. C., and P. Goblet. 2003. Calibration of regional flow models: Working toward a better understanding of site-specific systems. Water Resources Research 39 (6): 1–25. doi:10.1029/2002WR001653.
   Web of Science ®Google Scholar
• Chapman, T. G. 1991. Comment on «Evaluation of automated techniques for baseflow and recession analysis» by RJ Nathan and TA McMahon. Water Resources Research 27: 1783–1784.
   Web of Science ®Google Scholar
• Cloutier, V., R. Lefebvre, M. M. Savard, É. Bourque, and R. Therrien. 2006. Hydrogeochemistry and groundwater origin of the Basses-Laurentides sedimentary rock aquifer system, St. Lawrence Lowlands, Québec, Canada. Hydrogeology Journal 14: 573–590.
   Web of Science ®Google Scholar
• Collin, M. L., and A. J. Melloul. 2003. Assessing groundwater quality to pollution to promote sustainable urban and rural development. Journal of Cleaner Production 11: 727–736.
   Web of Science ®Google Scholar
• Croteau, A., M. Nastev, and R. Lefebvre. 2010. Groundwater recharge assessment in the Châteauguay River watershed. Canadian Water Resources Journal 35: 451–468.
   Web of Science ®Google Scholar
• Doherty, J. 2016. PEST. Model-Independent Parameter Estimation. User manual Part 1 and 2. Watermark Numerical Computing. 6th Edition, 390. Brisbane: Watermark Numerical Computing.
   Google Scholar
• Eckhardt, K. 2005. How to construct recursive digital filters for baseflow separation. Hydrological Processes 19 (2): 507–515.
   Web of Science ®Google Scholar
• El-Kadi, A. I., L. N. Plummer, and P. Aggarwal. 2011. NETPATH-WIN: An interactive user version of the mass-balance model, NETPATH. Ground Water 49: 593–599.
   PubMedGoogle Scholar
• Environment Canada. 2016. 1981-2010 historical means for stations number 7028441, 7020305, 7022160 and 7025440. http://climate.weather.gc.ca/climate_normals/index_e.html.
   Google Scholar
• ESRI (Environmental System Research Institute), 2016. ArcGIS Desktop. Release 10.3.1. Analysis Tools.
   Google Scholar
• Fontes, C. H. 1992. Chemical and isotopic constraints on 14C dating of groundwater. In Radiocarbon dating after four decades: An interdisciplinary perspective, eds. R. E. Taylor, A. Long, and R. S. Kra, 242–326. New York, NY: Springer.
   Google Scholar
• Fortin, V., and R. Turcotte. 2007. Le modèle hydrologique MOHYSE. Research report. Environnement Canada. Montréal.
   Google Scholar
• Gleeson, T., W. M. Alley, D. M. Allen, M. A. Sophocleous, Y. Zhou, M. Taniguchi, and J. VanderSteen. 2012. Towards sustainable groundwater use: Setting long-term goals, backcasting, and managing adaptively. Ground Water 50 (1): 19–26.
   PubMedGoogle Scholar
• Gleeson, T., L. Marklund, L. Smith, and A. H. Manning. 2011. Classifying the water table at regional to continental scales. Geophysical Research Letters 38: L05401.
   Web of Science ®Google Scholar
• Gleeson, T., J. VanderSteen, M. A. Sophocleous, M. Taniguchi, W. M. Alley, D. M. Allen, and Y. Zhou. 2010. Ground water sustainability strategies. Nature Geoscience 3: 378–379.
   Web of Science ®Google Scholar
• Globensky, Y. 1987. Géologie des basses-terres du Saint-Laurent. Ministère des Richesses naturelles du Québec 63 (v. MM 85-02) (in French).
   Google Scholar
• Godbout, P. M., M. Lamothe, V. Horoi, and O. Caron. 2011. Synthèse stratigraphique, cartographie des dépôts quaternaires et modèle hydrostratigraphique régional, secteur de Bécancour, Québec. Rapport final. Université du Québec à Montréal, à l’intention du ministère des Ressources naturelles et de la Faune (MRNF), 37 pp ( in French).
   Google Scholar
• Gusyev, M. A., M. Toews, U. Morgenstern, M. Stewart, P. White, C. Daughney, and J. Hadfield. 2013. Calibration of a transient transport model to tritium data in streams and simulation of groundwater ages in the western Lake Taupo catchment, New Zealand. Hydrology and Earth System Sciences 17 (3): 1217–1227.
   Web of Science ®Google Scholar
• Haitjema, H., V. Kelson, and W. de Lange. 2001. Selecting MODFlOW cell sizes for accurate flow fields. Ground Water 39 (6): 931–938.
   PubMedGoogle Scholar
• Harbaugh, A. W. 2005. MODFLOW-2005, the U.S. Geological Survey modular ground-water model – The ground-water flow process: U.S. Geological Survey techniques and methods 6-A16. Various pp. http://pubs.usgs.gov/tm/2005/tm6A16/.
   Google Scholar
• Huntley, D., R. Nommensen, and D. Steffey. 1992. The use of specific capacity to assess transmissivity in fractured-rock aquifers. Ground Water 30 (3): 396–402.
   Google Scholar
• Izbicki, J. A., C. L. Stamos, T. Nishikawa, and P. Martin. 2004. Comparison of ground-water flow model particle-tracking results and isotopic data in the Mojave River ground-water basin, southern California, USA. Journal of Hydrology 292 (1–4): 30–47.
   Web of Science ®Google Scholar
• Juckem, P. F., R. J. Hunt, and M. P. Anderson. 2006. Scale effects of hydrostratigraphy and recharge zonation on base flow. Ground Water 44 (3): 362–370.
   PubMedGoogle Scholar
• Lamothe, M. 1989. A new framework for the Pleistocene stratigraphy of the Central St. Lawrence Lowland. Géographie physique et Quaternaire 43 (2): 119–129.
   Google Scholar
• Lamothe, M., and G. St-Jacques. 2014. Géologie du Quaternaire des bassins versants des rivières Nicolet et Saint-François, Québec. Rapport présenté au ministère des Ressources Naturelles et de la Faune, Montréal, 31 pp. (in French).
   Google Scholar
• Larocque, M., P. G. Cook, K. Haaken, and C. T. Simmons. 2009. Estimating flow using tracers and hydraulics in synthetic heterogenous aquifers. Ground Water 47 (6): 786–796.
   PubMedGoogle Scholar
• Larocque, M., S. Gagné, D. Barnetche, G. Meyzonnat, M. H. Graveline, and M. A. Ouellet. 2015. Projet de connaissance des eaux souterraines du bassin versant de la zone Nicolet et de la partie basse de la zone Saint-François - Rapport final. Rapport déposé au Ministère du Développement durable, de l’Environnement et de la Lutte contre les changements climatiques, 258 pp. (in French)
   Google Scholar
• Larocque, M., S. Gagné, L. Tremblay, and G. Meyzonnat. 2013. Projet de connaissance des eaux souterraines du bassin versant de la rivière Bécancour et de la MRC de Bécancour - Rapport final. Rapport déposé au Ministère du Développement durable, de l’Environnement, de la Faune et des Parcs, 219 pp. (in French)
   Google Scholar
• Lavigne, M. A., M. Nastev, and R. Lefebvre. 2010. Regional sustainability of the Châteauguay River aquifers. Canadian Water Resources Journal 35 (4): 487–502.
   Web of Science ®Google Scholar
• Levison, J. K., M. Larocque, V. Fournier, S. Gagné, S. Pellerin, and M. A. Ouellet. 2014a. Dynamics of a headwater system and peatland under current condition and with climate change. Hydrological Processes 28: 4808–4822.
   Web of Science ®Google Scholar
• Levison, J. K., M. Larocque, and M. A. Ouellet. 2014b. Modeling low-flow bedrock springs providing ecological habitats with climate change scenarios. Journal of Hydrology 515: 16–28.
   Web of Science ®Google Scholar
• Malgrange, J., and T. Gleeson. 2014. Shallow, old, and hydrologically insignificant fault zones in the Appalachian orogen. Journal of Geophysical Research – Solid Earth 119: 346–359. doi:10.1002/2013JB010351.
   Web of Science ®Google Scholar
• de Marsily, G., F. Delay, J. Gonçalvès, Ph. Renard, V. Teles, and S. Violette. 2005. Dealing with spatial heterogeneity. Hydrogeology Journal 13: 161–183.
   Web of Science ®Google Scholar
• MDDELCC (Ministère du Développement durable, de l’Environnement et de la Lutte contre les changements climatiques). 2013. www.mddelcc.gouv.qc.ca/eau/souterraines/sih/index.htm.
   Google Scholar
• Méjean, P., D. Pinti, M. Larocque, G. Bassam, G. Meyzonnat, and S. Gagné. 2017. Processes controlling 234U and 238U isotope fractionation and helium in the groundwater of the St. Lawrence Lowlands, Quebec: The potential role of natural rock fracturing. Applied Geochemistry 66: 198–209.
   Web of Science ®Google Scholar
• Meriano, M., and N. Eyles. 2003. Groundwater flow through Pleistocene glacial deposit in the rapidly urbanizing Rouge River-Highland Creek watershed, City of Scarborough, southern Ontario, Canada. Hydrogeology Journal 11: 288–303.
   Web of Science ®Google Scholar
• MERN (Ministry of Energy and Natural Resources). 2013. Digital elevation model. Scale 1:20 000. 10 m resolution. SNRC Sheets: 31I, 21L, 31H, 21E. http://geoboutique.mrnf.gouv.qc.ca.
   Google Scholar
• Meyzonnat, G., M. Larocque, F. Barbecot, D. Pinti, and S. Gagné. 2016. The potential of major ion chemistry to assess groundwater vulnerability of a regional aquifer in southern Quebec (Canada). Environmental Earth Sciences 75 (68): 1–12. doi:10.1007/s12665-015-4793-9.
   Web of Science ®Google Scholar
• Moritz, A., J.-F. Hélie, D. L. Pinti, M. Larocque, D. Barnetche, S. Retailleau, R. Lefebvre, and Y. Gélinas. 2015. Methane baseline concentrations and sources in shallow aquifers from the shale gas-prone region of the St. Lawrence Lowlands (Quebec, Canada). Environmental Science and Technology 49: 4765–4771.
   PubMed Web of Science ®Google Scholar
• Morris, B. L., A. R. L. Lawrence, P. J. C. Chilton, B. Adams, R. C. Calow, and B. A. Klink. 2003. Groundwater and its susceptibility to degradation: A global assessment of the problem and options for management. Early Warning and Assessment Report Series. RS. 03-3. United Nations Environment Programme, Nairobi, Kenya, 126 pp.
   Google Scholar
• Niswonger, R. G., S. Panday, and M. Ibaraki. 2011. MODFLOW-NWT, a Newton formulation for MODFLOW-2005: U.S. Geological Survey Techniques and Methods 6-A37, 44 p.
   Google Scholar
• Occhietti, S., and P. J. H. Richard. 2003. Effet réservoir sur les âges 14C de la Mer de Champlain à la transition Pléistocène-Holocène : révision de la chronologie de la déglaciation au Québec méridional. Géographie Physique et Quaternaire 57: 115–138.
   Google Scholar
• Oudin, L., F. Hervieu, C. Michel, C. Perrin, V. Andreassian, F. Anctil, and C. Loumagne. 2005. Which potential evapotranspiration input for a lumped rainfall–runoff model? Part 2 – towards a simple and efficient potential evapotranspiration model for rainfall–runoff modelling. Journal of Hydrology 303: 290–306.
   Web of Science ®Google Scholar
• Pandey, V. P., S. Shrestha, S. K. Chapagain, and F. Kazama. 2011. A framework for measuring groundwater sustainability. Environmental Science & Policy 14: 396–407.
   Web of Science ®Google Scholar
• Person, M., J. McIntosh, V. Bense, and V. H. Remenda. 2007. Pleistocene hydrology of North America: The role of ice sheets in reorganizing groundwater flow systems. Reviews of Geophysics 45 (3): RG3007. doi:10.1029/2006RG000206.
   Web of Science ®Google Scholar
• Phillips, F., and M. C. Castro. 2003. Groundwater dating and residence-time measurements. Treatise of Geochemistry 5: 451–497.
   Google Scholar
• Pinti, D. L., Y. Gélinas, M. Larocque, D. Barnetche, S. Retailleau, A. Moritz, J.-F. Hélie, and R. Lefebvre 2013. Concentrations, sources et mécanismes de migration préférentielle des gaz d’origine naturelle (méthane, hélium, radon) dans les eaux souterraines des Basses-Terres du Saint-Laurent. FQRNT ISI n° 171083. Study no. E3-9, 94 pp. (in French).
   Google Scholar
• Plummer, L., and P. Glynn. 2013. Radiocarbon dating in groundwater systems. In Isotope methods for dating old groundwater, 33–90. Vienna: International Atomic Energy Agency.
   Google Scholar
• Poirier, C. 2012. Estimation préliminaire des débits de base à des sites de stations hydrométriques du Centre d’expertise hydrique du Québec (CEHQ). Contribution au Programme d’acquisition des connaissances sur les eaux souterraines (PACES). MDDELCC, Direction de l’expertise hydrique, Québec.
   Google Scholar
• Pollock, D. W. 2016. User Guide for MODPATH Version 7 – A particle tracking model for MODFLOW: U.S. Geological Survey Open-File Report 2016-1086, 35 pp.
   Google Scholar
• Portniaguine, O., and D. K. Solomon. 1998. Parameter estimation using groundwater age and head data, Cape Cod. Massachusetts. Water Resources Research 34 (4): 637–645.
   Web of Science ®Google Scholar
• Przemyslaw, W., A. J. Zurek, C. Stumpp, A. Gemitzi, A. Gargini, M. Filippini, K. Rozanski, J. Meeks, J. Kvaerner, and S. Witczak. 2016. Toward operational methods for the assessment of intrinsic groundwater vulnerability: A review. Critical Reviews in Environmental Science and Technology 46 (9): 827–884.
   Web of Science ®Google Scholar
• Reilly, T. E., K. F. Dennehy, W. M. Alley, and W. L. Cunningham. 2008. Groundwater availability in the United-States: U.S. Geological Survey Circular 1323, 70 pp.
   Google Scholar
• Richard, S. K., R. Chesnaux, A. Rouleau, and R. H. Coupe. 2016. Estimating the reliability of aquifer transmissivity values obtained from specific capacity tests: Example from the Saguenay-Lac-Saint-Jean aquifers, Canada. Hydrological sciences journal 61 (1): 173–185.
   Web of Science ®Google Scholar
• Rivard, C., R. Lefebvre, and D. Paradis. 2014. Regional recharge estimation using multiple methods: An application in the Annapolis Valley, Nova-Scotia (Canada). Environmental Earth Sciences 71 (3): 1389–1408.
   Web of Science ®Google Scholar
• Saby, M., M. Larocque, D. L. Pinti, F. Barbecot, Y. Sano, and M. C. Castro. 2016. Linking groundwater quality to residence times and regional geology in the St. Lawrence Lowlands, southern Quebec, Canada. Applied Geochemistry 65: 1–13.
   Web of Science ®Google Scholar
• Saby, M., M. Larocque, D. L. Pinti, F. Barbecot, S. Gagné, D. Barnetche, and H. Cabana. 2017. Regional assessment of concentrations and sources of pharmaceutically active compounds, pesticides, nitrate, and E. coli in post-glacial aquifer environments (Canada). Science of the Total Environment 579: 557–568.
   PubMed Web of Science ®Google Scholar
• Sanford, W. E. 1997. Correcting for diffusion in Carbon-14 dating of groundwater. Groundwater 35 (2): 357–361.
   Google Scholar
• Sanford, W. E. 2011. Calibration of models using groundwater age. Hydrogeology Journal 19: 13–16.
   Web of Science ®Google Scholar
• Sanford, W. E. 2017. Estimating regional-scale permeability-depth relations in a fractured-rock terrain using groundwater-flow model calibration. Hydrogeology Journal 25: 405–419.
   Web of Science ®Google Scholar
• Sanford, W. E., L. N. Plummer, D. P. McAda, L. M. Bexfield, and S. K. Anderholm. 2004. Hydrochemical tracers in the middle Rio Grande Basin, USA: 2. Calibration of a groundwater-flow model. Hydrogeology Journal 12: 389–407.
   Web of Science ®Google Scholar
• SAS Institute Inc. 2012. JMP® software, Version 12. SAS Institute Inc., Cary, NC., 1997–2016 pp.
   Google Scholar
• Scanlon, B. R., R. W. Healy, and P. G. Cook. 2002. Choosing appropriate techniques for quantifying groundwater recharge. Hydrogeology Journal 10: 18–39.
   Web of Science ®Google Scholar
• Schlosser, P., M. Stute, C. Sonntag, and K. O. Munnich. 1989. Tritiogenic 3He in shallow groundwaters. Earth Planetary Science Letters 94: 245–256.
   Web of Science ®Google Scholar
• Sheets, R. A., E. S. Bair, and G. L. Rowe. 1998. Use of3H/3He Ages to evaluate and improve groundwater flow models in a complex buried-valley aquifer. Water Ressources Research. 34 (5): 1077–1089.
   Web of Science ®Google Scholar
• Slivitzky, A., and P. St-Julien. 1987. Compilation géologique de la région de l’Estrie-Beauce. Rapport géologique MM-85-04. Ministère de l’Énergie et des Ressources, Québec ( in French).
   Google Scholar
• Suckow, A. 2014. The age of groundwater – Definition, models and why we do not need this term. Applied Geochemistry 50: 222–230.
   Web of Science ®Google Scholar
• Sulis, M., C. Paniconi, C. Rivard, R. Harvey, and D. Chaumont. 2011. Assessment of climate change impacts at the catchment scale with a detailed hydrological model of surface-subsurface interactions and comparison with a land surface model. Water Resources Research 47: W01513. doi:10.1029/2010WR009167.
   Web of Science ®Google Scholar
• Szabo, Z., D. H. Rice, L. N. Plummer, E. Busenberg, S. Drenkard, and P. Schlosser. 1996. Ages dating of shallow groundwater with chlorofluorocarbons, tritium/helium3, and flow path analysis, southern New Jersey. Water Resources Research 32 (4): 1023–1038.
   Web of Science ®Google Scholar
• Tamers, M. A. 1975. Validity of radiocarbon dates on groundwater. Geophysical Surveys 2 (2): 217–239.
   Google Scholar
• Tolstikhin, I. N., and I. L. Kamenskiy. 1969. Determination of ground-water ages by T-He-3 method. Geochemistry International 6: 810–811.
   Web of Science ®Google Scholar
• Tran Ngoc, T. D., R. Lefebvre, E. Konstantinovskaya, and M. Malo. 2014. Characterization of deep saline aquifers in the B_ecancour area, St. Lawrence Lowlands, Quebec, Canada: implications for CO2 geological storage. Environmental Earth Sciences 72: 119–146. doi:10.1007/s12665-013-2941-7.
   Web of Science ®Google Scholar
• Troldborg, L., K. H. Jensen, P. Engesgaard, J. C. Refsgaard, and K. Hinsby. 2008. Using environmental tracers in modelling Flow in a complex shallow aquifer system. Journal of Hydrologic Engineering 13 (11): 1037–1048.
   Web of Science ®Google Scholar
• Turnadge, C., and B. D. Smerdon. 2014. A review of methods for modelling environmental tracers in groundwater: Advantages of tracer concentration simulation. Journal of Hydrology 519: 3674–3689.
   Web of Science ®Google Scholar
• United-States Department of Agriculture (USDA), Natural Resources Conservation Service. 2004. National Engineering Handbook. Part 630: Hydrology. Chapter 10: Estimation of Direct Runoff From Rainfall, 79. 210-VI-NEH, July 2004.
   Google Scholar
• Vautour, G., D. L. Pinti, P. Méjean, M. Saby, G. Meyzonnat, M. Larocque, M. C. Castro, C. M. Hall, M. C. Boucher, E. Rouleau, F. Barbecot, N. Takahata, and Y. Sano. 2015. 3H/3He, 14C and (U-Th)/He groundwater ages in the St. Lawrence Lowlands, Quebec, Eastern Canada. Chemical Geology 413: 94–106.
   Web of Science ®Google Scholar
• Voss, C. I. 2011. Editor’s message: Groundwater modelling fantasies – Part 1, adrift in the details. Hydrogeology Journal 19: 1281–1284.
   Web of Science ®Google Scholar
• Wassenaar, L. I., and M. J. Hendry. 2000. Mechanisms controlling the distribution and transport of 14C in a clay-rich till aquitard. Ground Water 38 (3): 343–349.
   Google Scholar
• Weise, S., and H. Moser. 1987. Groundwater dating with helium isotopes. Techniques in water resource development, 105–126. Wien: IAEA.
   Google Scholar
• Wen, T., M. C. Castro, C. M. Hall, D. L. Pinti, and K. C. Lohmann. 2016. Constraining groundwater flow in the glacial drift and Saginaw aquifers in the Michigan basin through helium concentrations and isotopic ratios. Geofluids 16: 3–25.
   Web of Science ®Google Scholar