555
Views
3
CrossRef citations to date
0
Altmetric
Original Articles

Stable Carbon Isotope Ratios and the Photochemical Age of Atmospheric Volatile Organic Compounds

, , , &
Pages 7-13 | Received 30 Oct 2012, Accepted 28 Apr 2013, Published online: 22 Aug 2013

References

  • Anderson, R., Iannone, R., Thompson, A., Rudolph, J., & Huang, L. (2004a). Carbon kinetic isotope effects in the gas-phase reactions of aromatic hydrocarbons with the OH radical at 296 ± 4 K. Geophysical Research Letters, 31. doi:10.1029/2004GL020089
  • Anderson, R., Iannone, R., Thompson, A., Rudolph, J., & Huang, L. (2004b). Carbon kinetic isotope effects in the gas-phase reactions of light alkanes and ethene with the OH radical at 296 ± 4 K. Journal of Physical Chemistry A, 108(52), 11537–11544.
  • Atkinson, R. (2000). Atmospheric chemistry of VOCs and NOx. Atmospheric Environment, 34, 2063–2101.
  • Atkinson, R., & Arey, J. (2003). Atmospheric degradation of volatile organic compounds. Chemical Reviews, 103, 4605–4638.
  • Bloss, C., Wagner, V., Jenkin, M.E., Volkamer, R., Bloss, W.J., Heard, D.E., Wirtz, K., Martin-Reviejo, M., Rea, G., Wenger, J.C., & Pilling, M.J. (2005). Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons. Atmospheric Chemistry and Physics, 5, 641–644.
  • Chameides, W.L., Fehsenfeld, F., Rodgers, M.O., Cardelino, C., Martinez, J., Parrish, D., Lonneman, W., Greenberg, J., Middleton, P., & Wang, T. (1992). Ozone precursor relationships in the ambient atmosphere. Journal of Geophysical Research, 97, 6037–6055.
  • Craig, H. (1953). The geochemistry of the stable carbon isotopes. Geochimica et Cosmochimica Acta, 3, 53–92.
  • Finlayson-Pitts, B.J., & Pitts, J.N. J. (2000). Chemistry of the upper and lower atmosphere. San Diego: Academic Press.
  • Gelencsér, A., Siszler, K., & Hlavay, J. (1997). Toluene–benzene concentration ratio as a tool for characterizing the distance from vehicular emission sources. Environmental Science and Technology, 31(10), 2869–2872.
  • Jobson, B.T., Berkowitz, C.M., Kuster, W.C., Goldan, P.D., Williams, E.J., Fesenfeld, F.C., Apel, E.C., Karl, T., Lonneman, W.A., & Riemer, D. (2004). Hydrocarbon source signatures in Houston, Texas: Influence of the petrochemical industry. Journal of Geophysical Research, 109, D24305. doi:10.1029/2004JD004887
  • Kaye, J.A. (1987). Mechanisms and observations for isotope fractionation of molecular species in planetary atmospheres. Reviews of Geophysics, 25(8), 1609–1658.
  • Kleinman, L.I., Daum, P.H., Lee, L.-N., Nunnermacker, L.J., Springston, S.R., Weinstein-Lloyd, J., Hyde, P., Doskey, P., Rudolph, J., Fast, J., & Berkowitz, C. (2003). Photochemical age determinations in the Phoenix metropolitan area. Journal of Geophysical Research, 108, 4096. doi:10.1029/2002JD002621
  • Pankow, J.F., Luo, W., Isabelle, L.M., Bender, D.A., & Baker, R.J. (1998). Determination of a wide range of volatile organic compounds in ambient air using multisorbent adsorption/thermal desorption and gas chromatography/mass spectrometry. Analytical Chemistry, 70(24), 5213–5221.
  • Parrish, D.D., Hahn, C.J., Williams, E.J., Norton, R.B., Fehsenfeld, F.C., Singh, H.B., Shetter, J.D., Gandrud, B.W., & Ridley, B.A. (1992). Indications of photochemical histories of Pacific air masses from measurements of atmospheric trace species at Point Arena, California. Journal of Geophysical Research, 97(D14), 15883–15901.
  • Roberts, J.M., Fehsenfeld, F.C., Liu, S.C., Bollinger, M.J., Hahn, C., Albritton, D.L., & Sievers, R.E. (1984). Measurements of aromatic hydrocarbon ratios and NOx concentrations in the rural troposphere: Observation of air mass photochemical aging and NOx removal. Atmospheric Environment, 18(11), 2421–2432.
  • Rudolph, J. (2007). Gas chromatography-isotope ratio mass spectrometry. In R. Koppmann (Eds.), Volatile organic compounds in the atmosphere (pp. 348–466). Oxford: Blackwell Publishing Ltd.
  • Rudolph, J., & Czuba, E. (2000). On the use of isotopic composition measurements of volatile organic compounds to determine the “photochemical age” of an air mass. Geophysical Research Letters, 27(23), 3865–3868.
  • Rudolph, J., Czuba, E., & Huang, L. (2000). The stable carbon isotope fractionation for reactions of selected hydrocarbons with OH-radicals and its relevance for atmospheric chemistry. Journal of Geophysical Research, 105(D24), 29329–29346.
  • Rudolph, J., Czuba, E., Norman, A.L., Huang, L., & Ernst, E. (2002). Stable carbon isotope composition of nonmethane hydrocarbons in emissions from transportation related sources and atmospheric observations in an urban atmosphere. Atmospheric Environment, 36(7), 1173–1181.
  • Rudolph, J., Lowe, D.C., Martin, R.J., & Clarkson, T.S. (1997). A novel method for the compound specific determination of δ13C in volatile organic compounds at ppt levels in ambient air. Geophysical Research Letters, 24(6), 659–662.
  • Saunders, S.M., Jenkin, M.E., Derwent, R.G., & Pilling, M.J. (2003). Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): Tropspheric degradation of non-aromatic volatile organic compounds. Atmospheric Chemistry and Physics, 3, 161–180.
  • Sillman, S. (1999). The relation between ozone, NOx and hydrocarbons in urban and polluted rural environments. Atmospheric Environment, 33, 1821–1845.
  • Simpson, I.J., Blake, N.J., Blake, D.R., Atlas, E., Flocke, F., Crawford, J.H., Fuelberg, H.E., Kiley, C.M., Meinardi, S., & Rowland, F.S. (2003). Photochemical production and evolution of selected C2–C5 alkyl nitrates in tropospheric air influenced by Asian outflow. Journal of Geophysical Research, 108, 8808. doi:10.1029/2002JD002830

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.