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Nucleosides and Nucleotides Volume 17, 1998 - Issue 12
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Original Articles

2-Bromoadenosine-Substituted 2′,5′-Oligoadenylates Modulate Binding and Activation Abilities of Human Recombinant RNase L

Yukio Kitade Laboratory of Molecular Biochemistry, Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1–1, Gifu, 501-1193, Japan
,
Masaharu Wakana Laboratory of Molecular Biochemistry, Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1–1, Gifu, 501-1193, Japan
,
Shin-ichi Terai Laboratory of Molecular Biochemistry, Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1–1, Gifu, 501-1193, Japan
,
Takayuki Tsuboi Laboratory of Molecular Biochemistry, Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1–1, Gifu, 501-1193, Japan
,
Masayuki Nakanishi Laboratory of Molecular Biochemistry, Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1–1, Gifu, 501-1193, Japan
,
Chizuko Yatome Laboratory of Molecular Biochemistry, Department of Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1–1, Gifu, 501-1193, Japan
,
Beihua Dong Department of Cancer Biology, The Lemer Research Institute, The Cleveland Clinic Foundation, Cleveland, OH, 44195, USA
,
Robert H. Silverman Department of Cancer Biology, The Lemer Research Institute, The Cleveland Clinic Foundation, Cleveland, OH, 44195, USA
&
Paul F. Torrence Section on Biomedical Chemistry, Laboratory of Medicinal Chemistry, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, Bethesda, MD, 20892, USA
 show all
Pages 2323-2333 | Received 23 Mar 1998, Accepted 29 May 1998, Published online: 16 Aug 2006

References

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  • Kitade , Y. , Wakana , M. and Yatome , C. unpublished results: In fact, the chemical shift of the H2′-proton on 2-bromoadenosine (4.50 ppm) supports an and-orientation the same as that of adenosine (4.60 ppm). On the other hand, the down field shift of H2′-proton of 8-bromoadenosine (5.08 ppm) and 8-methyladenosine (4.86 ppm) imply a syn-orientation as a result of the deshielding effect of purine ring
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