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Original Articles

Intramolecular Glycosylation to Form 4-Methoxy-2,6-Dioxopyrimidine Nucleosides via O6,5′-Cyclonucleosides

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Pages 2415-2423 | Received 10 Jan 1999, Accepted 01 Apr 1999, Published online: 04 Oct 2006

References

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  • Mizuno , Y. , Kaneko , C. and Oikawa , Y. 1974 . J. Org. Chem. , 39 : 1440 – 1444 . For a similar approaches using a thio bridge with a purine or pyrimidine base, see (b) El Subbagh, H. I.; Ping, L.-J.; Abushanab, E. Nucleosides Nucleotides 1992, 11, 603–613.
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  • Acidic conditions (anhydrous HC1, 0.05M H2SO4) to remove the pyrimidyl methoxy group and/or cleave the tether cleaved the bond to the anomeric center.
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