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Original Articles

Studies on the Selective Separation of Ir(IV), Ru(III) and Rh(III) from Chloride Solutions using Alamine 336 in Kerosene

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Pages 65-77 | Received 11 Apr 2006, Accepted 24 Sep 2006, Published online: 09 Mar 2007

References

  • Hartley , F. R. 1991 . Chemistry of Platinum Group Metals Amsterdam : Elsevier .
  • Hagelüken , C. 2002 . Securing the supply for tomorrow: precious metals recycling from automotive catalysts . Metall , 55 ( 3 ) : 104 – 111 .
  • Grumett , P. 2003 . Precious metal recovery from spent catalysts . Platinum Met. Rev. , 47 : 163 – 166 .
  • Hagelüken , C. 1999 . Recycling of spent noble metal catalyst with emphasis on pyrometallurgical processing . Oil Gas , 25 ( 3 ) : 36 – 39 .
  • Lo , T. C. , Baird , M. H. and Hanson , C. 1983 . Handbook of Solvent Extraction New York : Wiley Interscience .
  • Knothe Von , M. 1980 . Untersuchungen zur extraktion der pt‐metalle mit tributylphosphat aus salzsauern lösungen . Z. Anorg. Allg. Chem. , 470 : 216 – 226 .
  • Hudson , M. J. and Thorns , J. F. 1983 . The concentration of rhodium and iridium during the final stages of the platinum group metals refining process using the co‐polymer poly[(N‐dithiocarboxylato)‐iminoethenehydrogenoiminioethene] . Hydrometallurgy , 11 : 289 – 295 .
  • Zou , L. H. , Chen , J. and Huang , Y. 2004 . An alternative way to separating Ir(IV) and Rh(III) ions from a mixed chloride solution with added stannous chloride . Hydrometallurgy , 72 : 31 – 37 .
  • Kanert , G. A. and Chow , A. 1974 . Solvent extraction separation of rhodium from iridium with tri‐n‐octylamine as a liquid anion‐exchanger . Anal. Chim. Acta , 69 ( 2 ) : 355 – 361 .
  • Lokhande , T. N. , Kolekar , G. B. , Anuse , M. A. and Chavan , M. B. 2000 . Extraction of ruthenium(IV) form hydrochloric acid medium with n‐octylaniline and its determination spectrophotometrically with pyrimidine‐2‐thiol . Sep. Sci. Technol. , 35 ( 1 ) : 153 – 168 .
  • Chavan , D. V. and Dhadke , P. M. 2002 . Extraction separation of Ir(III) and Rh(III) with Cyanex 923 from chloride media: a possible recovery from spent autocatalysts . J. Chem. Technol. Biotechnol. , 77 : 925 – 932 .
  • Alam , M. S. and Inoue , K. 1997 . Extraction of rhodium from other platinum group metals with Kelex 100 from chloride media containing tin . Hydrometallurgy , 46 : 373 – 382 .
  • Mhaske , P. Dhadke. 2002 . Extraction separation studies of Os, Ru, and Ir using Cyanex 921 in toluene . Hydrometallurgy , 63 : 207 – 214 .
  • Kolekar , S. S. and Anuse , M. A. 2002 . Solvent extraction separation of iridium(III) from Rh(III) by N‐n‐octylaniline . J. Anal. Chem. , 57 ( 12 ) : 1071 – 1075 .
  • Kedari , C. S. , Coll , T. , Fortuny , A. , Goralska , E. and Sastre , A. 2005 . Liquid–liquid extraction of Ir, Ru, and Rh from chloride solutions and their separation using different commercially available solvent extraction reagents . Sep. Sci. Technol. , 9 ( 40 ) : 1927 – 1946 .
  • Alguacil , F. J. , Cobo , A. , Coedo , A. G. , Dorado , M. T. and Sastre , A. 1997 . Extraction of platinum(IV) from hydrochloric acid solutions by amine Alamine 304 in xylene. Estimation of the interaction coefficient between PtCl6 2‐ and H+ . Hydrometallurgy , 44 : 203 – 212 .
  • du Preez , J. G.H. , Shillington , D. P. , Herselman , E. , Rohwer , H. E. , van Brecht , B. J.A.M. and Wilke , H. 1995 . Secondary effects associated with the functioning of bulky substituted ammonium cations–revised interpretations . Solv. Extr. And Ion Exch. , 13 ( 2 ) : 189 – 214 .
  • du Preez , J. G.H. , Viviers , C. , Louw , T. , Hosten , E. and Jonck , H. 2004 . The separation of rhodium and iridium. II. chloridation and chlorination of iridium(III) and (IV) . Solv. Extr. And Ion Exch. , 22 ( 2 ) : 175 – 188 .
  • Alam , M. S. , Inoue , K. and Yoshizuka , K. 1998 . Ion exchange/adsorption of rhodium(III) from chloride media on some anion exchanger . Hydrometallurgy , 49 : 213 – 227 .
  • Kertes , A. S. 1965 . “ The chemistry of the formation and elimination of a third phase in organophosphorus and amine extraction systems ” . In Solvent Extraction Chemistry of Metals 377 – 399 . London : McMillan .
  • Fine , D. A. 1969 . On the spontaneous reduction of hexachloiridiate (IV) in aqueous solution . Inorg. Chem. , 8 : 1014 – 1016 .

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