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Original Articles

Recovery of U and Pu from Nitric Acid using N,N-di(2-ethylhexyl)butanamide (DEHBA) in Mixer-Settler Extractors

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Pages 590-603 | Published online: 05 Sep 2013

REFERENCES

  • Siddall III , T.H. 1960 . Effects of structure of N,N-disubstituted amides on their extraction of actinide and zirconium nitrates and of nitric acid . J. Phys. Chem. , 64 : 1863 – 1866 .
  • Musikas , C. and Hubert , H. 1987 . Solvent extraction for the chemical separation of the 5f elements . Inorg. Chim. Acta , 140 : 197 – 206 .
  • Gasparini , G. M. and Grossi , G. 1980 . Application of N,N-dialkyl aliphatic amides in the separation of some actinides . Sep. Sci. Technol. , 15 : 825 – 844 .
  • Musikas , C. 1988 . Potentiality of nonorganophosphorus extractants in chemical separations of actinides . Sep. Sci. Technol. , 23 : 1211 – 1266 .
  • Musikas , C. , Condamines , N. and Cuillerdier , C. 1991 . Separation chemistry for the nuclear industry . Anal. Sci. Suppl. , 7 : 11 – 16 .
  • Ruikar , P.B. , Nagar , M.S. and Subramanian , M.S. 1993 . Extraction of uranium, plutonium and some fission products with γ-irradiated unsymmetrical and branched chain dialkylamides . J. Radioanal. Nucl. Chem. , 176 : 103 – 111 .
  • Ruikar , P.B. , Nagar , M.S. , Subramanian , M.S. , Gupta , K.K. , Varadarajan , N. and Singh , P.K. 1995 . Extraction behavior of uranium(VI), plutonium(IV) and some fission products with gamma pre-irradiated n-dodecane solutions of N,N’-dihexyl substituted amides . J. Radioanal. Nucl. Chem. , 196 : 171 – 178 .
  • Pathak , P.N. , Veeraraghavan , R. , Prabhu , D.R. , Mahajan , G.R. and Manchanda , V.K. 1999 . Separation studies of uranium and thorium using di-2-ethylhexyl isobutyramide . Sep. Sci. Technol. , 34 : 2601 – 2614 .
  • Gupta , K.K. , Manchanda , V.K. , Subramanian , M.S. and Singh , R.K. 2000 . Solvent extraction studies on U(VI), Pu(IV), and fission products using N,N-dihexyloctanamide . Solvent Extr. Ion Exch. , 18 : 273 – 292 .
  • Gupta , K.K. , Manchanda , V.K. , Subramanian , M.S. and Singh , R.K. 2000 . N,N-dihexyl hexanamide: A promising extractant for nuclear fuel reprocessing . Sep. Sci. Technol. , 35 : 1603 – 1617 .
  • Pathak , P.N. , Kumbhare , L.B. and Manchanda , V.K. 2001 . Structual effects in N,N-dialkyl amides on their extraction behavior toward uranium and thorium . Solvent Extr. Ion Exch. , 19 : 105 – 126 .
  • Manchanda , V.K. , Ruikar , P.B. , Sriram , S. , Nagar , M.S. , Pathak , P.N. , Gupta , K.K. , Singh , R.K. , Chitnis , R.R. , Dhami , P.S. and Ramanujam , A. 2001 . Distribution behavior of U(VI), Pu(IV), Am(III), and Zr(IV) with N,N-dihexyl octanamide under uranium-loading conditions . Nucl. Technol. , 134 : 231 – 239 .
  • Mowafy , E.A. and Aly , H.F. 2001 . Extraction of actinides and selected fission products from nitric acid medium using long chain monoamides . Solvent Extr. Ion Exch. , 19 : 629 – 641 .
  • Yu , C. , Zhenwei , Z. , Runtian , J. and Xin , S.G. 2003 . Structual effect of N,N-dialkylamide on the extraction of thorium(IV) ion from nitric acid solution . J. Radioanal. Nucl. Chem. , 258 : 171 – 173 .
  • Suzuki , S. , Sasaki , Y. , Yaita , T. and Kimura , T. June 21–24 2004 . Study on selective separation of uranium by N,N-dialkylamide in ARTIST process. ATALANTE 2004 , June 21–24 , 1 – 63 . France : Nimes .
  • Manchanda , V.K. and Pathak , P.N. 2004 . Amides and diamides as promising extractants in the back end of the nuclear fuel cycle: An overview . Sep. Sci. Technol. , 35 : 85 – 103 .
  • Manchanda , V.K. , Pathak , P.N. and Rao , A.K. 2004 . Di(2-Ethylhexyl) pivalamide (D2EHPVA): A promising extractant for selective removal of uranium from high level nuclear waste solutions . Solvent Extra. Ion Exch. , 22 : 353 – 375 .
  • Suzuki , S. , Yaita , T. , Sugo , Y. and Kimura , T. September 9–13 2007 . Study on selective separation of uranium(VI) by new N,N-dialkyl carboxyamides. GLOBAL 2007 , September 9–13 , 1137 – 1141 . Idaho : Boise .
  • Pathak , P.N. , Kumbhare , L.B. and Manchanda , V.K. 2001 . Effect of structure of N,N dialkyl amides on the extraction of U(VI) and Th(IV): A thermodynamic study . Radiochim. Acta , 89 : 447 – 452 .
  • Vasudevan , T. , Murali , M. S. , Nagar , M. S. and Mathur , J. N. 2002 . Extraction of U(VI) from nitrate and thiocyanate media with monoamides . Solvent Extr. Ion Exch. , 20 : 665 – 686 .
  • Yu , C. , Guoxin , S. , Zhenwei , Z. , Yexin , L. and Sixiu , S. 2005 . Extraction of U(VI) with unsymmetrical N-methyl-N-decylalkylamide in toluene . Radiochim. Acta , 93 : 287 – 290 .
  • Prabhu , D.R. , Mahajan , G.R. , Nair , G.M. and Subramanian , M.S. 1993 . Extraction of uranium(VI) and plutonium(IV) with unsymmetrical monoamides . Radiochim. Acta , 60 : 109 – 113 .
  • Prabhu , D.R. , Mahajan , G.R. and Nair , G.M. 1997 . Di(2-ethylhexyl) butyramide and di(2-ethylhexyl)isobutyramide as extractants for uranium(VI) and plutonium(IV) . J. Radioanal. Nucl. Chem. , 224 : 113 – 117 .
  • Sun , G.X. , Han , J.T. , Bao , B.R. and Sun , S.X. 1998 . Structual effect of N,N-dialykyamide in toluene on the extraction of uranium(VI) . J. Radioanal. Nucl. Chem. , 232 : 245 – 247 .
  • Pathak , P.N. , Prabhu , D.R. , Kanekar , A.S. and Machanda , V.K. 2006 . Distribution studies on Th(IV), U(VI) and Pu(IV) using tri-N-butylphosphate and N,N-dialkyl amides . Radiochim. Acta , 94 : 193 – 198 .
  • Carlini , D. , Casarci , M. , Gasparini , G.M. , Grossi , G. and Moccia , A. August 26–29 1984 . “ Bench scale demonstration of a coprocessing operation with an amidic solvent ” . In International meeting on fuel reprocessing and waste management , August 26–29 , 1–485 – 4–492 . Wyoming : Jackson .
  • Miguirditchian , M. , Sorel , C. , Cames , B. , Bisel , I. , Baron , P. , Espinoux , D. , Calor , J-N. , Viallesoubranne , C. , Lorrain , B. and Masson , M. 2009 . HA demonstration in the Atalante facility of the Ganex 1st cycle for the selective extraction uranium from HLW , 1032 – 1035 . Paris , , France, September 6–11 : GLOBAL 2009 .
  • Ban , Y. , Hotoku , S. and Morita , Y. 2011 . Selective extraction of U(VI) by counter-current liquid-liquid extraction with N,N-di(2-ethylhexyl)-2,2-dimethylpropanamide . Solvent Extr. Ion Exch. , 29 : 519 – 533 .
  • Ban , Y. , Hotoku , S. and Morita , Y. 2012 . Distribution of U(VI) and Pu(IV) by N,N-di(2-ethylhexyl)butanamide in continuous counter-current extraction with mixer-settler extractor . Solvent Extr. Ion Exch. , 30 : 142 – 155 .
  • Ban , Y. , Hotoku , S. and Morita , Y. 2012 . Application of N,N-di(2-ethylhexyl)butanamide for mutual separation of U(VI) and Pu(IV) by continuous counter-current extraction with mixer-settler extractors . J. Nucl. Sci. Technol. , 49 : 588 – 594 .
  • Gasparini , G.M. and Grossi , G. 1986 . Long chain disubstituted aliphatic amides as extracting agents in industrial applications of sovent extraction . Solvent Extr. Ion Exch. , 4 : 1233 – 1271 .
  • Thiollet , G. and Musikas , C. 1989 . Synthesis and uses of the amides extractants . Solvent Extr. Ion Exch. , 7 : 813 – 827 .
  • Ruikar , P.B. , Nagar , M.S. and Subramanian , M.S. 1992 . Extraction behavior of uranium, plutonium and some fission products with gamma-irradiated N,N’-dialkylamides . J. Radioanal. Nucl. Chem. , 159 : 167 – 173 .
  • Mowafy , E. A. 2004 . The effect of prefious gamma-irradiation on the extraction of U(VI), Th(IV), Zr(IV), Eu(III) and Am(III) by various amides . J. Radioanal. Nucl. Chem. , 260 : 179 – 187 .
  • Parikh , K.J. , Pathak , P.N. , Misra , S.K. , Tripathi , S.C. , Dakshinamoorthy , A. and Manchanda , V.K. 2009 . Radiolytic degradation studies on N,N-dihexyloctanamide (DHOA) under PUREX process Conditions . Solvent Extr. Ion Exch. , 27 : 244 – 257 .
  • Ban , Y. , Burdet , F. , Cames , B. , Caniffi , B. , Hill , C. and Morita , Y. September 6–11 2009 . Radiolysis and extraction properties of branched N,N-dialkylamides in n-dodecane for U(VI) separation. GLOBAL 2009 September 6–11 , 266 – 271 . Paris , , France
  • Nair , G.M. , Mahajan , G.R. and Prabhu , D.R. 1996 . Dioctyl butyramide and dioctyl isobutyramide as extractants for uranium(VI) and plutonium(IV) . J. Radioanal. Nucl. Chem. , 204 : 103 – 111 .
  • Miguirditchian , M. , Chareyre , L. , Sorel , C. , Bisel , I. , Baron , P. and Masson , M. May 19–23 2008 . Development of the GANEX process for the reprocessing of Gen IV spent nuclear fuels. ATALANTE 2008 , May 19–23 , O1 – 14 . France : Montpellier .
  • Tsubata , Y. , Asakura , T. and Morita , Y. 2009 . Development of a computer code, PARC, for simulation of solvent extraction process in reprocessing . Trans.Atomic Energy Soc. Japan , 8 : 211 – 220 . [In Japanese]
  • Tsubata , Y. , Asakura , T. and Morita , Y. 2008-2010 . Development of a Computer Code, PARC, for Simulation of Liquid-Liquid extraction Process in Reprocessing . JAEA-DATA/Code 2008 , [in Japanese]

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