138
Views
5
CrossRef citations to date
0
Altmetric
Original Articles

Redox Processes in the Organic Phase during Cobalt Extraction with the bis(2,4,4-trimethylpentyl)dithiophosphinic Acid and Trioctyl Phosphine Oxide Mixtures

&

REFERENCES

  • Kholkin, A.I.; Belova, V.V.; Voshkin, A.A.; Zhidkova, T.I.; Zhilov, V.I.; Dzhana, R.K. Application of binary extractants based on dialkyl dithiophosphoric acids in hydrometallurgy. Russ. J. Chem. Technol. 2005, 6(8), 34–43.
  • CYANEX® 301 Extractant, 2007, Technical Brochure, CYTEC INDUSTRIES INC., West Paterson, New Jersey; 14 pp.
  • Mihaylov, I.; Krause, E.; Colton, D.F.; Okita, Y.; Duterque, J.-P.; Perraud J.-J. The development of a novel hydrometallurgical process for nickel and cobalt recovery from Goro laterite ore. CIM Bulletin 2000, 93(1041), 124–130.
  • Tsakiridis, P.E.; Agatzini, S.L. Simultaneous solvent extraction of cobalt and nickel in the presence of manganese and magnesium from sulfate solutions by Cyanex 301. Hydrometallurgy 2004, 72 (3–4), 269–278.
  • Mihaylov, I.; Grinbaum, B.; Ilan, Y.; Efraim, A. Opportunities for nickel-cobalt extraction and separation using Cyanex 301. In Proceedings of the 39th Annual Hydrometallurgy Meeting CIM, Hydrometallurgy of nickel and cobalt. Sudbury, Ontario, Canada, Aug. 23–26, 2009; Budac, J.J., Fraser, R., Mihaylov, I., Eds.; Canadian Institute of Mining, Metallurgy and Petroleum: Montreal, 2009; pp 383–391.
  • Vorde, I.V.; Pinoy, L.; Courtijn, E.; Verpoort, F. Influence of acetate ions and the role of the extraction of copper(II), nickel(II), cobalt(II), magnеsium(II), and iron(II, III) with types of extractants. Hydrometallurgy 2005, 78 (1–2), 92–106.
  • Ocana, N.; Alguacil, F.J. Cobalt-manganese separation: The extraction of cobalt(II) from manganese sulphate solutions by Cyanex 301. J. Chem. Technol. Biotechnol. 1999, 73(3), 211–216.
  • Tait, B.K. Cobalt-nickel separation: the extraction of cobalt (II) and nickel (II) by Cyanex 301, Cyanex 302 and Cyanex 272. Hydrometallurgy 1993, 32(3), 365–372.
  • Sole, K.C.; Hiskey, J.B. Solvent extraction characteristics of thiosubstituted organophosphinic acid extractants. Hydrometallurgy 1992, 30 (1–3), 345–365.
  • Gajda, B.; Apostoluk, W. Equilibria of cobalt(II) and nickel(II) extraction from sulphate solutions with Cyanex 301. Ars Separatoria Acta 2002, 1, 55–60.
  • Van de Voorde, I.; Pinoy, L.; Courtijn, E.; Verpoort, F. Equilibrium studies of nickel(II), copper(II), and cobalt(II) extraction with Aloxime 800, D(2)EHPA and Cyanex reagents. Solvent Extr. Ion Exch. 2006, 24(6), 893–914.
  • Menoyo, B.; Elizalde, M.P. Extraction of cobalt(II) by Cyanex 301. Solvent Extr. Ion Exch. 1997, 15(4), 563–576.
  • Facon, S.; Rodriguez, M.A.; Cote, G.; Bauer, D. General properties of bis(2,4,4- trimethylpentyl)dithiophosphinic acid (Cyanex 301) in acidic liquid–liquid extraction systems. In Proceedings of the International Solvent Extraction Conference, ISEC 1993. York, UK, Sept. 9–15, 1993; Logsdail, D.H., Slater, M.J., Eds., Elsevier: London, UK, 1993; Vol. 1, pp 557–564.
  • Fleitlikh, I.Yu.; Grigorieva, N.A.; Kuz’min, V.I.; Pashkov, G.L. Redox processes during cobalt extraction with bis(2,4,4-trimethylpentyl)dithiophosphinic acid. Hydrometallurgy 2012, 129(1), 43–49.
  • Kuz’min, V.I.; Logutenko, O.A.; Kuz’mina, V.N. Co(II) oxidation by oxygen in extraction with di(2-ethylhexyl)dithiophosphoric acid. Russ. J. Inorg. Chem. 1999, 44(7), 1155–1159.
  • Kuz’min, V.I.; Klimkina, T.A., Logutenko, O.A. Oxidation of cobalt(II) with disulphide upon extraction with di(2-ethylhexyl)dithiophosphoric acid. Russ. J. Inorg. Chem. 1998, 43(5), 798–801.
  • Kholkin, A.I.; Chernobrov, A.S.; Gindin, L.M.; Kuznetsova, L.M.; Kalish, N.K., Sinyukova, V.M. Influence of redox reactions on extraction equilibriums in the systems containing acidic extractants. Russ. J. Proc. Siberian Branch Acad. Sci. USSR (Chem. Sci. Ser.) 1976, 5, 67–72.
  • Bourget, C.; Jakovlevic, B.; Nucciarone D. CYANEX® 301 binary extractant systems in cobalt/nickel recovery from acidic sulphate solutions. Hydrometallurgy 2005, 77 (3–4), 203–218.
  • Tait, B.K. The extraction of some base metal ions by Cyanex 301, Cyanex 302 and their binary extractant mixtures with Aliquat 336. Solvent Extr. Ion Exch. 1992, 10(5), 799–809.
  • Zhidkova, T.I.; Belova, V.V.; Brenno, Yu.Yu.; Zhidkov, L.L.; Kholkin, A.I. Metals extraction from chloride and nitrate solutions with binary extractants based on CYANEX 301. Russ. J. Chem. Technol. 2006, 3, 32–36.
  • Cote, G.; Bauer, D. Solvent extraction of cobalt(II) di(2-ethylhexyl)dithiophosphate adduct with oxygen donor ligands. J. Inorg. Nucl. Chem. 1979, 4 (5), 767–774.
  • Kuz’min, V.I.; Klimkina, T.A.; Kuz’mina, V.N. Influence of electron-donor additives on cobalt oxidation in the extraction systems containing di(2-ethylhexyl)dithiophosphoric acid. Russ. J. Applied Chem. 1999, 72(6), 932–935.
  • Kletenik, Yu.B.; Sedova, S.A.; Kholkin, A.I.; Gindin, L.M.; Sergeeva, V.V.; Pashkov, G.L. Extraction purification of sulfate nickel solutions from cobalt with use of dialkyl dithiophosphoric acid. In Proceedings VIth Russian National Conference on Solvent Extraction, Kemerovo, USSR, Sept. 9–11, 1981; Vol. II, 223.
  • Kletenik, Yu.B.; Sedova, S.A. Separation of cobalt and nickel in the extraction systems containing di(2-ethylhexyl)dithiophosphoric acid and donor-active additives on basis of kinetic factors. Russ. J. Appl. Chem. 1983, 56(7), 1510–1514.
  • Grigorieva, N.A.; Fleitlikh, I.Yu. Cobalt extraction from sulfate media with bis (2,4,4-trimethylpentyl)dithiophosphinic acid in the presence of electron donor additives. Hydrometallurgy 2013, 138, 71–78.
  • Zhu, Y.; Chen, J.; Jiao, R. Extraction of Am(III) and Eu(III) from nitrate solution with purified Cyanex 301. Solvent Extr. Ion Exch. 1996, 14(1), 61–68.
  • Grigorieva, N.A.; Pavlenko, N.I.; Pashkov, G.L.; Fleitlikh, I.Yu.; Nikiforova, L.K. Investigation of the state of bis(2,4,4-trimethylpentyl)dithiophosphinic acid in nonane in the presence of electron donor additives. Solvent Extr. Ion Exch. 2010, 28(4), 510–525.
  • Pashkov, G.L.; Grigorieva, N.A.; Pavlenko, N.I.; Fleitlikh, I.Yu.; Nikiforova, L.K.; Pleshkov, M.A. Nickel (II) extraction from sulfate media with bis(2,4,4-trimethylpentyl)dithiophosphinic acid dissolved in nonane. Solvent Extr. Ion Exch. 2008, 26(6), 749–763.
  • Dolenko, G.N.; Kholkin, A.I.; Chernobrov, A.S; Goltsova, E.A.; Gindin, L.M.; Kuznetsova, L.M.; Kalish, N.K. Composition and configuration studies of metal extracted complexes in the bis(2-ethylhexyl)dithiophosphoric acid systems. Russ. J. Proc. Siberian Branch Acad. Sci. USSR (Chem. Sci. Ser.) 1979, 2(1), 32–42.
  • Torgov, V.G.; Bakovets, K.A.; Mardezhova, G.A.; Drozdova, M.K.; Mikhaylov, V.A. Extraction of cobalt chloride with tri-n-octyl amine oxide. Russ. J. Proc. Siberian Branch Acad. Sci. USSR (Chem. Sci. Ser.) 1974, 3, 70–78.
  • Kazitsyna, L.A.; Kupletskaya, N.B. Application of UV, IR, and NMR spectroscopy in organic chemistry; Vysshaya Shkola: Moscow, 1971.
  • Mukherjee, R.N.; Venkateshan, M.S.; Zingde, M.D.; Dhingra, M.M. Spectroscopic, NMR and PMR studies on monoadducts of cobalt(II) and nickel(II) diaryldithiophosphinates with oxygen donor ligands. J. Inorg. Nucl. Chem. 1976, 38(4), 689–693.
  • Larionov, S.V., Arykova, E.I., Podol’skaya, L.A. Investigation of some properties of dialkyl dithiophosphinates of elements of the iron family. Russ. J. Proc. Siberian Branch Acad. Sci. USSR (Chem. Sci. Ser.) 1969, 4(2), 80–86.
  • Kokina, T.E.; Klevtsova, R.F.; Glinskaya, L.D.; Semyannikov, P.P.; Trubin, S.V.; Larionov, S.V. Cobalt(II) complexes containing di-isobutyl dithiophosphinate ions and nitrogenous heterocycles. The structure of [Co2(triethylenediamine) (iso-Bu2PS2)4]. Russ. J. Inorg. Chem. 2004, 49(4), 593–601.
  • Kirichenko, V.N.; Larionov, S.V. Stabilization of cobalt(II) in the presence of dialkyl dithiophosphate ions and heterocyclic nitrous bases. Russ. J. Inorg. Chem. 1979, 24(11), 3064–3069.
  • Ionova, G.; Ionov, S.; Rabbe, C.; Hill, C.; Madic, C.; Guillaumont, R.; Krupa, J. C. Мechanism of trivalent actinide/lanthanide separation using bis(2,4,4-trimethylpentyl)dithiophosphinic acid (Cyanex 301) and neutral O-bearing co-extractant synergistic mixtures. Solvent Extr. Ion Exch. 2001 19(3), 391–414.
  • Reddy, M.L.P.; Bharathi, J.RB.; Peter, S; Ramamohan, T.R. Synergistic extraction of rare earths with bis(2,4,4-trimethylpentyl)dithiophosphinic acid and trialkyl phosphine oxide. Talanta 1999, 50(1), 79–85.
  • Jones, D. L. Process for the extraction of nickel and/or cobalt values from a solution. Australian Patent 755 776, 2002.
  • Borbat, V.F.; Volkov, V.I.; Kazanskiy, L.A. Production of Cobalt from Sulfide Ores;Metallurgia: Moscow, 1983.
  • Nagaphani, K.B.; Chong, H.S.; Man, S.L. Solvent extraction equilibrium and modeling studies of manganese from sulfate solutions by a mixture of Cyanex 301 and TBP. Hydrometallurgy 2014, 144–145, 1–6.
  • Sedova, S.A.; Navrotskaya, V.A.; Kletenik, Yu.B. Separation of cobalt and nickel at the stripping stage in the di(2-ethylhexyl)dithiophosphoric acid–trioctyl phosphine oxide system. Russ. J. Proc. Siberian Branch Acad. Sci. USSR (Chem. Sci. Ser.) 1984, 7(6), 98–101.
  • Fleitlikh, I.Yu.; Pashkov, G.L.; Grigorieva, N.A.; Nikiforova, L.K.; Pleshkov, M.A.; Shneerson, Y.M. Cobalt and nickel recovery from sulfate media containing calcium, manganese, and magnesium with a mixture of Cyanex 301 and a trialkylamine. Solvent Extr. Ion Exch. 2011, 29 (5–6), 782–800.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.