Rh(III) Extraction by Phosphinic Acids from Nitrate Media

REFERENCES

• Shelef, M.; Graham, G. W. Why rhodium in automotive three-way catalysts? Catalysis Reviews 1994, 36(3), 433–457.
   Web of Science ®Google Scholar
• Roth, J. F. The production of acetic acid. Platinum Metals Review 1975, 19(1), 12–14.
   Google Scholar
• Wilburn, D. R.; Bleiwas, D. I. Platinum-group metals: World supply and demand; U.S. Geological Survey, 2004.
   Google Scholar
• Loferski, P. J. Platinum-group metals; U.S. Geological Survey, 2012.
   Google Scholar
• International Atomic Energy Agency. Feasibility of separation and utilization of ruthenium, rhodium and palladium from high level wastes; IAEA: Vienna, 1989; pp 18–19.
   Google Scholar
• Naito, K.; Matsui, T.; Tanaka, Y. Recovery of noble metals from insoluble residue of spent fuel. J Nucl Sci Technol. 1986, 23(6), 540–549.
   Web of Science ®Google Scholar
• Philip Horwitz, E.; Diamond, H.; Martin, K. A. The extraction of selected actinides in the (III) (IV) and (VI) oxidation states from hydrochloric acid by o-phi-d(IB)CMPO: The TRUEX-Chloride process. Solvent Extr Ion Exch. 1987, 5(3), 447–470.
   Web of Science ®Google Scholar
• Mathur, J. N.; Murali, M. S.; Nash, K. L. Actinide partition: A review. Solvent Extr. Ion Exch. 2001, 19(3), 357–390.
   Web of Science ®Google Scholar
• Nash, K. L.; Jensen, M. P. Analytical -scale separation of the lanthanides: A review of techniques and fundamentals. Sep. Sci. Technol. 2001, 36(5–6), 1257–1282.
   Web of Science ®Google Scholar
• Nilsson, M.; Nash, K. L. Review Article: A Review of the Development and operational characteristics of the TALSPEAK process. Solvent Extr Ion Exch. 2007, 25(6), 665–701.
   Web of Science ®Google Scholar
• Weaver, B.; Kappelmann, F. A. TALSPEAK: A new method of separating americium and curium from the lanthanides by extraction from an aqueous solution of an aminopolyacetic acid complex with a monoacidic organophosphate or phosphonate; Oak Ridge National Lab. Tenn., 1964.
   Google Scholar
• Chamberlain, D. B.; Leonard, R. A.; Hoh, J. C.; Gay, E. C.; Kalina, D. G.; Vandegrift, G. F. TRUEX hot demonstration; Argonne National Lab, Argonne, IL, 1990.
   Google Scholar
• Kolarik, Z.; Renard, E. V. Recovery of value fission platinoids from spent nuclear fuel. Platinum Metals Review 2003, 47(2), 74–87.
   Web of Science ®Google Scholar
• Shafiqul Alam, M.; Inoue, K. Extraction of rhodium from other platinum group metals with Kelex 100 from chloride media containing tin. Hydrometallurgy 1997, 46(3), 373–382.
   Web of Science ®Google Scholar
• Levitin, G.; Schmuckler, G. Solvent extraction of rhodium chloride from aqueous solutions and its separation from palladium and platinum. Reactive Funct. Poly. 2003, 54(1), 149–154.
   Web of Science ®Google Scholar
• Charlesworth, P. Separating the platinum group metals by liquid-liquid extraction. Platinum Met Rev 1981, 25(3), 106–112.
   Google Scholar
• Lee, J.-Y.; Rajesh Kumar, J.; Kim, J.-S.; Park, H.-K.; Yoon, H.-S. Liquid-liquid extraction/separation of platinum (IV) and rhodium (III) from acidic chloride solutions using tri-iso-octylamine. J. Hazard. Mat. 2009, 168(1), 424–429.
   PubMed Web of Science ®Google Scholar
• Zou, L.; Chen, J.; Pan, X. Solvent extraction of rhodium from aqueous solution of Rh(III)-Sn(II)-Cl- system by TBP. Hydrometallurgy 1998, 50(3), 193–203.
   Web of Science ®Google Scholar
• Tertipis, G. G.; Beamish, F. E. Solvent extraction separation and spectrophotometric determination of rhodium and iridium. Analytical Chem. 1962, 34(6), 623–625.
   Web of Science ®Google Scholar
• Mhaske, A. A.; Dhadke, P. M. Extraction separation studies of Rh, Pt and Pd using Cyanex 921 in toluene: A possible application to recovery from spent catalysts. Hydrometallurgy 2001, 61(2), 143–150.
   Web of Science ®Google Scholar
• Patel, N. M.; Thornback, J. R. The extraction of rhodium from aqueous nitric acid by dinonylnaphthalene sulphonic acid. Solvent Extr Ion Exch. 1987, 5(4), 633–647.
   Web of Science ®Google Scholar
• Freiderich, M. E.; Peterman, D. R.; Klaehn, J. R.; Marc, P. L. J.; Delmau, L. H. Chemical degradation studies on a series of dithiophosphinic acids (DPAHs). Ind. Eng. Chem. Research 2014, 53(9), 3606–3611.
   Web of Science ®Google Scholar
• Alimarin, I. P.; Rodionova, T. y. V.; Ivanov, V. M. Extraction with thio and dithio phosphorus acids. Russian Chem. Reviews 1989, 58(9), 863–878.
   Google Scholar
• Modolo, G.; Wilden, A.; Geist, A.; Magnusson, D.; Malmbeck, R. A review of the demonstration of innovative solvent extraction processes for the recovery of trivalent minor actinides from PUREX raffinate. Radiochimica Acta 2012, 100(8–9), 715–725.
   Web of Science ®Google Scholar
• Xu, Q.; Wu, J.; Chang, Y.; Zhang, L.; Yang, Y. Extraction of Am(III) and lanthanides(III) with organo dithiophosphinic acids. Radiochimica Acta 2008, 96(12), 771–779.
   Web of Science ®Google Scholar
• Li, K.-A.; Freiser, H. Extraction of lanthanide metals with Bis(2,4,4-trimethylpentyl) phosphonic acid. Solvent Extr Ion Exch. 1986, 4(4), 739–755.
   Web of Science ®Google Scholar
• Hill, C.; Madic, C.; Baron, P.; Ozawa, M.; Tanaka, Y. Trivalent minor actinides/lanthanides separation, using organophosphinic acids. J. Alloys Comp. 1998, 271, 159–162.
   Web of Science ®Google Scholar
• Jensen, M. P.; Bond, A. H. Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301, and Cyanex 302. Radiochimica Acta 2002, 90(4), 205–209.
   Web of Science ®Google Scholar
• Samuels, A. C.; Boele, C.; Benette, K.; Wall, N. A.; Clark, A. E. An integrated computational and experimental protocol for understanding Rh(III) speciation in hydrochloric and nitric acid solutions. Inorg. Chem. 2014, DOI:10.1021/ic501408r.
   PubMed Web of Science ®Google Scholar
• Aleksenko, S. S.; Gumenyuk, A. P.; Mushtakova, S. P.; Timerbaev, A. R. Speciation studies by capillary electrophoresis-distribution of rhodium(III) complexed forms in acidic media. Fresenius’ J. Anal. Chem. 2001, 370(7), 865–871.
   PubMedGoogle Scholar
• Cramer, C. J.; Truhlar, D. G. Density functional theory for transition metals and transition metal chemistry. Phy. Chem. Chem. Phy. 2009, 11(46), 10757–10816.
   PubMed Web of Science ®Google Scholar
• Niu, S.; Hall, M. B. Theoretical studies on reactions of transition-metal complexes. Chemical Reviews 2000, 100(2), 353–406.
   PubMed Web of Science ®Google Scholar
• Valiev, M.; Bylaska, E. J.; Govind, N.; Kowalski, K.; Straatsma, T. P.; Van Dam, H. J. J.; Wang, D.; Nieplocha, J.; Apra, E.; Windus, T. L. NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations. Comp. Phy. Comm. 2010, 181(9), 1477–1489.
   Web of Science ®Google Scholar
• Braun-Sand, S. B.; Wiest, O. Theoretical studies of mixed-valence transition metal complexes for molecular computing. J. Phy. Chem. A 2003, 107(2), 285–291.
   Web of Science ®Google Scholar
• Peterson, K. A.; Figgen, D.; Dolg, M.; Stoll, H. Energy-consistent relativistic pseudopotentials and correlation consistent basis sets for the 4 defilements. Y-Pd. J. Chem. Phy. 2007, 126(12), 124101/1–124101/12.
   Google Scholar
• Dunning Jr, T. H. Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen. J. Chem. Phy. 1989, 90(2), 1007–1023.
   Google Scholar
• Woon, D. E.; Dunning Jr, T. H. Calculation of the electron affinities of the second row atoms: aluminum through chlorine. J. Chem. Phy. 1993, 99(5), 3730–3737.
   Web of Science ®Google Scholar
• Buckingham, J. Dictionary of Organic Compounds, 5th ed.; Chapman Hall: London, 1982.
   Google Scholar
• Modolo, G.; Odoj, R. The separation of trivalent actinides from lanthanides by dithiophosphinic acids from HNO3 acid medium. J. Alloys Comp. 1998, 271–273(0), 248–251.
   Web of Science ®Google Scholar
• Pearson, R. G. Hard and soft acids and bases. J. Am. Chem. Soc. 1963, 85(22), 3533–3539.
   Web of Science ®Google Scholar