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Articles

Distribution Behavior of Neptunium by Extraction with N,N-dialkylamides (DEHDMPA and DEHBA) in Mixer-Settler Extractors

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References

  • IAEA Safeguards Glossary 2001 Edition; IAEA, 2001, p 27.
  • Benedict, M.; Pigford, T. H.; Levi, H. W. Nuclear Chemical Engineering; McGraw-Hill: NY. 1981, p 468.
  • McKay, H. A. C. Science and Technology of Tributyl Phosphate, Vol. I. CRC Press: FL, 1982, p 9.
  • Manchanda, V. K.; Ruikar, P. B.; Sriram, S.; Nagar, M. S.; Pathak, P. N.; Gupta, K. K.; Singh, R. K.; Chitnis, R. R.; Dhami, P. S.; Ramanujam, A. Distribution behavior of U(VI), Pu(IV), Am(III), and Zr(IV) with N,N-dihexyl octanamide under uranium-loading conditions. Nucl. Technol. 2001, 134, 231–239.
  • Benay, G.; Wipff, G. Liquid-liquid extraction of uranyl by an amide ligand: interfacial features studied by MD and PMF simulations. Physical Chemistry B 2013, 117, 7399–7415.
  • Pathak, P. N. N,N-Dialkyl amides as extractants for spent fuel reprocessing: An overview. J. Radioanal. Nucl. Chem. 2014, 300, 7–15.
  • Parikh, K. J.; Pathak, P. N.; Misra, S. K.; Tripathi, S. C.; Dakshinamoorthy, A.; Manchanda, V. K. Radiolytic degradation studies on N,N-dihexyloctanamide (DHOA) under PUREX process conditions. Solv. Extra. Ion Exch. 2009, 27, 244–257.
  • Buchheim, B. K.; Bunschi, H.; Hoop, F. J.; Fitzpatrick, J. Methodology for a consequence analysis of a nuclar waste disposal facility. Nucl. Technol. 1983, 61, 444–449.
  • Krause, H.; Randl, R. Treatment and Final Disposal of Radioactive Wastes from Fuel Reprocessing in the Federal Republic of Germany; KfK 1741, 1972, p 20.
  • Gasparini, G. M.; Grossi, G. Long chain disubstituted aliphatic amides as extracting agents in industrial applications of solvent extraction. Solv. Extra. Ion Exch. 1986, 4, 1233–1271.
  • Suzuki, S.; Yaita, T.; Sugo, Y.; Kimura, T. Study on selective separation of uranium(VI) by new N,N-dialkyl carboxyamides. Proc. of Global 2007, Boise, ID, U.S.A, Sep. 9-13, 2007, pp 1137–1141.
  • Nair, G. M.; Mahajan, G. R.; Prabhu, D. R. Extraction of uranium(VI) and plutonium(IV) with some high molecular weight aliphatic monoamides from nitric acid medioum. J. Radioanal. Nucl. Chem., 1995, 191, 323–330.
  • Verma, P. K.; Pathak, P. N.; Kumari, N.; Sadhu, B.; Sundararajan, M.; Aswal, V. K.; Mohapatra, P. K. Effect of successive alkylation of N,N-dialkyl amides on the complexation behavior of uranium and thorium: Solvent extraction, small angle neutron scattering, and computational studies. The Journal of Physical Chemistry B 2014, 118, 14388–14396.
  • Pathak, P. N.; Kanekar, A. S.; Prabhu, D. R.; Machanda, V. K. Comparison of hydrometallurgical parameters of N,N-dialkylamides and of tri-n-butylphosphate. Solv. Extra. Ion Exch. 2009, 27, 683–694.
  • Long, J. T. Engineering for Nuclear Fuel Reprocessing; Gordon and Breach Science Publishers: NY, 1967, pp 14–15.
  • Miguirditchian, M.; Sorel, C.; Cames, B.; Bisel, I.; Baron, P.; Espinoux, D.; Calor, J.-N.; Viallesoubranne, C.; Lorrain, B.; Masson, M. HA demonstration in the Atalante facility of the Ganex 1st cycle for the selective extraction uranium from HLW. Proc. Global 2009, Paris, France, Sep. 6-11, 2009, pp 1032–1035.
  • Manchanda, V. K.; Pathak, P. N.; Rao, A. K. Di(2-Ethylhexyl) pivalamide (D2EHPVA): A promising extractant for selective removal of uranium from high level nuclear waste solutions. Solv. Extra. Ion Exch. 2004, 22, 353–375.
  • Suzuki, S.; Sasaki, Y.; Yaita, T.; Kimura, T. Study on selective separation of uranium by N,N-dialkylamide in ARTIST process. Atalante 2004, Nimes, France, Jun. 21-24, 2004, P1–63.
  • Musikas, C.; Condamines, N.; Cuillerdier, C. Separation chemistry for the nuclear industry. Anal. Sci. Suppl. 1991, 7, 11–16.
  • Ban, Y.; Hotoku, S.; Tsubata, Y.; Morita, Y. Uranium and plutonium extraction from nitric acid by N,N-di(2-ethylexyl)-2,2-dimethylpropanamide (DEHDMPA) and N,N-di(2-ethylhexyl)butanamide (DEHBA) using mixer-settler extractors. Solv. Extra. Ion Exch. 2014, 32, 348–364.
  • Development of high decontamination process for recovered uranium before conversion: Research report entrusted by the Ministry of Economy, Trade and Industry. JAEA, 2008, p 27. [in Japanese]
  • Sun, G.; Bao, B.; Liu, C. Extraction of uranyl(VI) ion with N,N-diethyloctadecanamide from nitric acid solution. J. Radioanal. Nucl. Chem., 1997, 218, 101–102.
  • Gupta, K. K.; Manchanda, V. K.; Subramanian, M. S.; Singh, R. K. Solvent extraction studies on U(VI), Pu(IV), and fission products using N,N-dihexyloctanamide. Solv. Extra. Ion Exch., 2000, 18, 273–292.
  • Ban, Y.; Hakamatsuka, Y.; Tsutsui, N.; Urabe, S.; Hagiya, H.; Matsumura, T. Spectroscopic study of Np(V) oxidation to Np(VI) in 3 mol/dm3 nitric acid at elevated temperatures. Radiochim. Acta 2014, 102, 775–780.
  • Precek, M.; Paulenova, A.; Mincher, B. J. Reduction of Np(VI) in irradiated solutions of nitric acid. Procedia Chemistry 2012, 7, 51–58.

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