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Original Articles

Extraction of lanthanides(III) from Perchlorate Solutions with Carbamoyl- and Phosphorylmethoxymethylphosphine Oxides and Tetrabutyldiglycolamide

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References

  • Nash, K. L.; Jensen, M. P. Analytical Separations of Lanthanides: Basic Chemistry and Methods. In Handbook on the Physics and Chemistry of Rare Earths, Gschneidner, K. A., Eyring, L., Eds.; North-Holland: Elsevier Scince B.V., 2000; Vol. 28, pp 311–371.
  • Rozen, A. M.; Nikolotova, Z. I.; Kartasheva, N. A. Diphosphine Dioxides as Extractants for Actinides. Radiokhimiya (In Russian). 1998, 28, 407–423.
  • Medved, T. Y.; Chmutova, M. K.; Nesterova, N. P.; Koiro, O. E.; Kochetkova, N. E.; Myasoedov, B. F.; Kabachnik, M. I. Oxides of Diaryl(Dialkyl)[Dialkylcarbamoylmethyl]Phosphine Oxides. Bull. Acad. Sci. USSR. Div. Chem. Sci. 1981, 30, 1743–1747. DOI: 10.1007/BF00949488.
  • Horwitz, E. P.; Kalina, D. G.; Kaplan, L.; Mason, G. W.; Diamond, H. Selected alkyl(phenyl)-N,N-dialkylcarbamoylmethylphosphine Oxides as Extractants for Am(III) from Nitric Acid Media. Sep. Sci. Technol. 1982, 17, 1261–1279. DOI: 10.1080/01496398208060649.
  • Siddall, T. H.;. Bidentate Organophosphorus Compound as Extractants - I. Extraction of Cerium, Promethium, and Americium Nitrates. J. Inorg. Nucl. Chem. 1963, 25, 883–892. DOI: 10.1016/0022-1902(63)80376-0.
  • Mrochek, J. E.;. Banks V.C. bis-(Disubstitutedphosphinyl)-alkanes - III. Extraction of Mineral Acids, uranium(VI) and Some Lanthanides. J. Inorg. Nucl. Chem. 1965, 27, 589–601. DOI: 10.1016/0022-1902(65)80265-2.
  • Rozen, A. M.; Nikolotova, Z. I.; Kartasheva, N. A.; Yudina, K. S. Complexation of Am, Cm, and Lanthanides with Organics Dioxides and Problem of Anomalous Aryl Strengthening of Complexes. Radiokhimiya (In Russian). 1977, 19, 709–719.
  • Myasoedov, B. F.; Chmutova, M. K.; Kochetkova, N. E.; Koiro, O. E.; Pribilova, G. A.; Nesterova, N. P.; Medved, T. Y. Kabachnik, M.I. Effect of the Structure of Dialkyl(Aryl)[Dialkylcarbamoylmethyl]Phosphine Oxides on Their Extraction Capacity and Selectivity. Solvent Extr. Ion Exch. 1986, 4, 61–81. DOI: 10.1080/07366298608917853.
  • Rozen, A. M.; Nikolotova, Z. I.; Kartasheva, N. A.; Yudina, K. S. Anomalous Dependency of Stability of Am(III) and Other metals(III) Complexes with Diphosphine Dioxides from Their Structure. Dokl. AN SSSR (In Russian). 1975, 222, 1151–1154.
  • Rozen, A. M.; Krupnov, B. V. Dependence of Extraction Ability of Organic Compounds on Their Structure. Russ. Chem. Rev. 1996, 65, 973–1000. DOI: 10.1070/RC1996v065n11ABEH000241.
  • Kabachnik, M. I.; Myasoedov, B. F.; Mastryukova, T. A.; Polikarpov, Y. M.; Chmutova, M. K.; Nesterova, N. P. Correlation Analysis of “Aryl Strengthening” of the Extraction Capacity of Bidentate Organophosphorus Extractants. Russ. Chem. Bull. 1996, 45, 2484–2490. DOI: 10.1007/BF01431100.
  • Evreinov, V. I.; Safronova, Z. V.; Yarkevich, A. N.; Kharitonov, A. V.; Bondarenko, N. A.; Tsvetkov, E. N. Complex Formation of Some Carbamoylmethylphosphine Oxides and Methylenediphosphine Dioxides with Alkali Metal Cations. The “Anomalous Aryl Enhancement” Effect. Russ. J. Gen. Chem. 1999, 69, 1047–1051.
  • Chiarizia, R.; Horwitz, E. P. Diluent Effects in the Extraction of Am(III) from Nitric Acid Solutions by Selected Carbamoylphosphoryl Extractants and Related Monofunctional Compounds. Solvent Extr. Ion Exch. 1992, 10, 101–118. DOI: 10.1080/07366299208918094.
  • Smirnov, I. V.; Babain, V. A.; Shadrin, A. Y. Efremova, T.I.; Bondarenko, N.A.; Herbst, R.S.; Peterman; D.R.; Todd, T.A. Extraction of Americium and Europium by Diphosphine Dioxides and Their Mixtures with Chlorinated Cobalt Dicarbollide. Solvent Extr. Ion Exch. 2005, 23, 1–21. DOI: 10.1081/SEI-200044381.
  • Sasaki, Y.; Choppin, G. R. Solvent Extraction of EU, Th, U, Np and Am with N,N’-dimethyl-N,N’-dihexyl-3-oxapentanediamide and Its Analogous Compounds. Anal. Sci. 1996, 12, 225–230. DOI: 10.2116/analsci.12.225.
  • Narita, H.; Yaita, T.; Tamura, K.; Tachimiti, S. Solvent Extraction of Trivalent Lanthanoid Ions with N,N’-dimethyl-N,N’-diphenyl-3-oxapentanediamide. Radiochim. Acta. 1998, 81, 223–226. DOI: 10.1524/ract.1998.81.4.223.
  • Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori, S. The Novel Extractants, Diglycolamides, for the Extraction of Lanthanides and Actinides in HNO3 - N-Dodecane System. Solvent Extr. Ion Exch. 2001, 19, 91–103. DOI: 10.1081/SEI-100001376.
  • Tachimori, S.; Sasaki, Y.; Suzuki, S. Modification of TODGA – N-Dodecane Solvent with Monoamide for High Loading of lanthanides(III) and actinides(III). Solvent Extr. Ion Exch. 2002, 20, 687–699. DOI: 10.1081/SEI-120016073.
  • Zhu, Z.-X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T. Cumulative Study on Solvent Extraction of Elements by N,N,N’,N’-tetraoctyl-3-oxapentanediamide (TODGA) from Nitric Acid into N-Dodecane. Anal. Chim. Acta. 2004, 527, 163–168. DOI: 10.1016/j.aca.2004.09.023.
  • Ansari, S. A.; Pathak, P. N.; Manchanda, V. K.; Husain, M.; Prasad, A. K.; Parmar, V. S. N,N,N’,N’-tetraoctyldiglycolamide (TODGA): A Promising Extractant for Actinide-Partitioning from High-Level Waste (HLW). Solvent Extr. Ion Exch. 2005, 23, 463–479. DOI: 10.1081/SEI-200066296.
  • Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; Hill, C.; Cote, G. An Additional Insight into the Correlation between the Distribution Ratios and the Aqueous Acidity of the TODGA System. Solvent Extr. Ion Exch. 2007, 25, 187–204. DOI: 10.1080/07366290601169345.
  • Sasaki, Y.; Tsubata, Y.; Kitatsuji, Y.; Sugo, N.; Shirrasu, N.; Morita, Y.; Kimura, T. Extraction Behavior of Metal Ions by TODGA, DOODA, MIDOA, and NTAmide Extractants from HNO3 to N-Dodecane. Solvent Extr. Ion Exch. 2013, 31, 401–415. DOI: 10.1080/07366299.2013.800431.
  • Sasaki, Y.; Sugo, N.; Morita, Y.; Nash, K. L. The Effect of Alkyl Substituents on Actinide and Lanthanide Extraction by Diglycolamide Compounds. Solvent Extr. Ion Exch. 2015, 33, 625–641. DOI: 10.1080/07366299.2015.1087209.
  • Mowafy, E. A.; Mohamed, D. Extraction Behavior of Trivalent Lanthanides from Nitric Acid Medium by Selected Structurally Related Diglycolamides as Novel Extractants. Sep. Purif. Technol. 2014, 128, 18–24. DOI: 10.1016/j.seppur.2014.03.005.
  • Ansari, S. A.; Pathak, P. N.; Mohapatra, P. K.; Manchanda, V. K. Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning. Chem. Rev. 2012, 112, 1751–1772. DOI: 10.1021/cr200002f.
  • Murakami, S.; Matsumiya, M.; Sasaki, Y.; Suzuki, S.; Hisamatsu, S.; Takao, K. Investigation into Coordination States of Diglycolamide and Dioxaoctanediamide Complexes with Lanthanide Elements Using Spectroscopic Methods. Solvent Extr. Ion Exch. 2017, 35, 233–250. DOI: 10.1080/07366299.2017.1336049.
  • Antonio, M. R.; McAlister, D. R.; Horwitz, E. P. An europium(III) Diglycolamide Complex: Insights into the Coordination Chemistry of Lanthanides in Solvent Extraction. Dalton Trans. 2015, 44, 515–521. DOI: 10.1039/c4dt01775g.
  • Ellis, R. J.; Brigham, D. M.; Delmau, L.; Ivanov, A. S.; Williams, N. J.; Vo, M. N.; Reinhart, B.; Moyer, B. A.; Bryantsev, V. S. “Straining” to Separate the Rare Earth: How the Lanthanide Contraction Impacts Chelation by Diglycolamide Ligands. Inorg. Chem. 2017, 56, 1152–1160. DOI: 10.1021/acs.inorgchem.6b02156.
  • Sasaki, Y.; Kitatsuji, Y.; Sugo, Y.; Tsubata, Y.; Kimura, T.; Morita, Y. Actinides Extractability Trends for Multidentate Diamides and Phosphine Oxides. Solvent Extr. Res. Develop. Japan. 2012, 19, 51–61. DOI: 10.15261/serdj.19.51.
  • Shvetsov, I. K.; Trukhlyaev, P. S.; Kalistratov, V. A.; Kulazhko, V. G.; Kharitonov, A. V.; Antoshin, A. E.; Tsvetkov, E. N. Extraction of uranium(VI), plutonium(IV), Transplutonium and Rare Earth Elements with Tetraphenylethylenediphosphine Dioxides with Alkyl Substituents in Ethylene Chain. Radiokhimiya (In Russian). 1989, 31, 63–66.
  • Turanov, A. N.; Karandashev, V. K.; Kharlamov, A. V.; Bondarenko, N. A. Synergistic Solvent Extraction of lanthanides(III) with Mixtures of 4-Benzoyl-3-Methyl-1-Phenylpyrazol-5-One and Some Novel Carbamoyl- and Phosphorylmethoxymethylphosphine Oxides. Solvent Extr. Ion Exch. 2014, 32, 492–507. DOI: 10.1080/07366299.2014.908584.
  • Turanov, A. N.; Karandashev, V. K.; Kharitonov, A. V.; Lezhnev, A. N.; Safronova, Z. V.; Yarkevich, A. N.; Tsvetkov, E. N. Extraction with N,N- Dialkylcarbamoylmethyl(Diphenyl)Phosphine Oxides from Hydrochloric Acid Solutions. Russ. J. Gen. Chem. 1999, 69, 1068–1074.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E. Extraction of Metal Chloride Complexes by Phosphoryl-Containing Podands. Solvent Extr. Ion Exch. 1996, 14, 227–245. DOI: 10.1080/07366299608918337.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Yarkevich, A. N.; Safronova, Z. V. Extraction of lanthanides(III) from Aqueous Nitrate Media with Tetra-(P-Tolyl) [(O-Phenylene)Oxymethylene] Diphosphine Dioxide. Solvent Extr. Ion Exch. 2009, 27, 551–578. DOI: 10.1080/07366290903044683.
  • Turanov, A. N.; Karandashev, V. K.; Bondarenko, N. A. Extraction Properties of Tetrasubstituted Methylenediphosphine Dioxides in Nitric Acid Medium. Radiochemistry. 2007, 49, 55–63. DOI: 10.1134/S1066362207010092.
  • Pearson, R. G.;. Hard and Soft Acids and Base. J. Am. Chem. Soc. 1963, 85, 3533–3539. DOI: 10.1021/ja00905a001.
  • Case, M. E.; Fox, R. V.; Baek, D. L.; Mincher, B. J.; Wai, C. M. Extraction Behavior of Selected Rare Earth Metals from Acidic Chloride Media Using Tetrabutyl Diglycolamide. Solvent Extr. Ion Exch. 2017, 35, 496–506. DOI: 10.1080/07366299.2017.1373984.
  • Horwitz, E. P.; Martin, K. A.; Diamond, H.; Kaplan, L. Extraction of Am from Nitric Acid by Carbamoyl–Phosphoryl Extractants: The Influence of Substituents on the Selectivity of Am over Fe and Selected Fission Products. Solvent Extr. Ion Exch. 1986, 4, 449–494. DOI: 10.1080/07366298608917877.
  • Turanov, A. N.; Karandashev, V. K.; Yarkevich, A. N.; Safronova, Z. V. Extraction of U(VI), Th(IV), Sc(III), and Rare Earth Elements from Nitric Acid Solutions by Selected Bifunctional Neutral Organophosphorus Compounds. Solvent Extr. Ion Exch. 2004, 22, 1–23.

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