Synergism and Aggregation in Multi-Extractant Solvent Extraction Systems

References

• Blue Ribbon Commission on America’s Nuclear Future. Report to the Secretary of Energy; US Department of Energy: Washington DC, 2012.
   Google Scholar
• Barrett, L.; Chang, Y.; Chu, M.; Corradini, M.; Fentiman, A.; Hughey, W. K.; Jacobs, D.; McCarthy, K.; Piercy, C.; Powers, D.; et al. Report of the American Nuclear Society President’s Special Committee on Used Nuclear Fuel Management Options; American Nuclear Society: USA, 2011.
   Google Scholar
• Spent Fuel Reprocessing Options. IAEA-TECDOC-1587; IAEA: Vienna, Austria, 2008.
   Google Scholar
• Braley, J. C.; Lumetta, G. J.; Carter, J. C. Combining CMPO and HEH[EHP] for Separating Trivalent Lanthanides from the Transuranic Elements. Solvent Extr. Ion Exch. 2013, 31(6), 567–577. DOI: 10.1080/07366299.2013.785912.
   Web of Science ®Google Scholar
• Lumetta, G. J.; Gelis, A. V.; Braley, J. C.; Carter, J. C.; Pittman, J. W.; Warner, M. G.; Vandegrift, G. F. The TRUSPEAK Concept: Combining CMPO and HDEHP for Separating Trivalent Lanthanides from the Transuranic Elements. Solvent Extr. Ion Exch. 2013, 31(3), 223–236. DOI: 10.1080/07366299.2012.670595.
   Web of Science ®Google Scholar
• Hagström, I.; Spjuth, L.; Enarsson, Ȧ.; Liljenzin, J.-O.; Skȧlberg, M.; Hudson, M. J.; Iveson, P. B.; Madic, C.; Cordier, P. Y.; Hill, C.; et al. Synergistc Solvent Extraction of Trivalent Americium and Europium by 2-bromodecanoic Acid and Neutral Nitrogen-Containing Reagents. Solvent Extr. Ion Exch. 1999, 17(2), 221–242. DOI: 10.1080/07366299908934610.
   Web of Science ®Google Scholar
• Healy, T. V. Synergism in the Solvent Extraction of Alkali Metal Ions by Thenoyl Trifluoracetone. J. Inorg. Nucl. Chem. 1968, 30(4), 1025–1036. DOI: 10.1016/0022-1902(68)80322-7.
   Web of Science ®Google Scholar
• Caceci, M.; Choppin, G. R.; Liu, Q. Calorimetric Studies of the Synergistic Effect. The Reaction of UO2 2+, Th 4+ and Nd 3+ TTA Complexes with TBP and TOPO in Benzene. Solvent Extr. Ion Exch. 1985, 3(5), 605–621. DOI: 10.1080/07366298508918530.
   Web of Science ®Google Scholar
• Cordier, P. Y.; Hill, C.; Baron, P.; Madic, C.; Hudson, M. J.; Liljenzin, J.-O. Am (III)/eu (III) Separation at Low pH Using Synergistic Mixtures Composed of Carboxylic Acids and Neutral Nitrogen Polydendate Ligands. J. Alloys Compd. 1998, 271–273, 738–741. DOI: 10.1016/S0925-8388(98)00197-2.
   Web of Science ®Google Scholar
• Ferraro, J. R.; Healy, T. V. Synergism in the Solvent Extraction of Di-, Tri- and Tetravalent Metal ions—V: Infra-red Studies of the Isolated Complexes. J. Inorg. Nucl. Chem. 1962, 24(11), 1463–1474. DOI: 10.1016/0022-1902(62)80153-5.
   Web of Science ®Google Scholar
• Irving, H. Synergism in the Extraction of Metal Chelates. In Proceedings from the International Conference on Solvent Extraction Chemistry, Dryssen, D., Liljenzin, J.-O., Rydberg, J., Eds.; North-Holland Pub. Co.: Gothenburg, Sweden, 1966; pp 91–110.
   Google Scholar
• Osseo-Asare, K.; Keeney, M. E. Sulfonic Acids: Catalysts for the Liquid-Liquid Extraction of Metals. Sep. Sci. Technol. 1980, 15(4), 999–1011. DOI: 10.1080/01496398008076283.
   Web of Science ®Google Scholar
• Antonio, M. R.; Chiarizia, R.; Gannaz, B.; Berthon, L.; Zorz, N.; Hill, C.; Cote, G. Aggregation in Solvent Extraction Systems Containing a Malonamide, a Dialkylphosphoric Acid and Their Mixtures. Sep. Sci. Technol. 2008, 43(9–10), 2572–2605. DOI: 10.1080/01496390802121537.
   Web of Science ®Google Scholar
• Ellis, R. J.; Anderson, T. L.; Antonio, M. R.; Braatz, A. D.; Nilsson, M. A SAXS Study of Aggregation in the Synergistic TBP-HDBP Solvent Extraction System. J. Phys. Chem. B. 2013, 117(19), 5916–5924. DOI: 10.1021/jp401025e.
   PubMed Web of Science ®Google Scholar
• Anderson, T. L.; Braatz, A. D.; Ellis, R. J.; Antonio, M. R.; Nilsson, M. Synergistic Extraction of Dysprosium and Aggregate Formation in Solvent Extraction Systems Combining TBP and HDBP. Solvent Extr. Ion Exch. 2013, 31(6), 617–633. DOI: 10.1080/07366299.2013.787023.
   Web of Science ®Google Scholar
• Tkac, P.; Vandegrift, G. F.; Lumetta, G. J.; Gelis, A. V. Study of the Interaction between HDEHP and CMPO and Its Effect on the Extraction of Selected Lanthanides. Ind. Eng. Chem. Res. 2012, 51(31), 10433–10444. DOI: 10.1021/ie300326d.
   Web of Science ®Google Scholar
• Braatz, A. D.; Antonio, M. R.; Nilsson, M. Structural Study of Complexes Formed by Acidic and Neutral Organophosphorus Reagents. Dalton Trans. 2017, 46(4), 1194–1206. DOI: 10.1039/c6dt04305d.
   PubMed Web of Science ®Google Scholar
• Gelis, A. V.; Lumetta, G. J. Actinide Lanthanide Separation Process□ALSEP. Ind. Eng. Chem. Res. 2014, 53(4), 1624–1631. DOI: 10.1021/ie403569e.
   Web of Science ®Google Scholar
• Whittaker, D. M.; Griffiths, T. L.; Helliwell, M.; Swinburne, A. N.; Natrajan, L. S.; Lewis, F. W.; Harwood, L. M.; Parry, S. A.; Sharrad, C. A. Lanthanide Speciation in Potential SANEX and GANEX Actinide/Lanthanide Separations Using Tetra-N-Donor Extractants. Inorg. Chem. 2013, 52(7), 3429–3444. DOI: 10.1021/ic301599y.
   PubMed Web of Science ®Google Scholar
• Aneheim, E.; Ekberg, C.; Fermvik, A.; Foreman, M. R. S. J.; Retegan, T.; Skarnemark, G. A TBP/BTBP-based GANEX Separation Process. Part 1: Feasibility. Solvent Extr. Ion Exch. 2010, 28(4), 437–458. DOI: 10.1080/07366299.2010.480930.
   Web of Science ®Google Scholar
• Carrott, M.; Bell, K.; Brown, J.; Geist, A.; Gregson, C.; Heres, X.; Maher, C.; Malmbeck, R.; Mason, C.; Modolo, G.; et al. Development of a New Flowsheet for co-Separating the Transuranic Actinides: The EURO-GANEX Process. Solvent Extr. Ion Exch. 2014, 32(5), 447–467. DOI: 10.1080/07366299.2014.896580.
   Web of Science ®Google Scholar
• Miguirditchian, M.; Roussel, H.; Chareyre, L.; Baron, P.; Espinoux, D.; Calor, J.-N.; Viallesoubranne, C.; Lorrain, B.; Masson, M. HA Demonstration in the Atalante Facility of the Ganex 2nd Cycle for the Grouped TRU Extraction. Proceedings of Global 2009, Paris, France, September 6–11, 2009, Paper 9378.
   Google Scholar
• Partridge, J. A.; Jensen, R. C. Purification of Di-(2-ethylhexyl) Phosphoric Acid by Precipitation of Copper(ii) Di-(ethylhexyl) Phosphate. J. Inorg. Nucl. Chem. 1969, 31(8), 2587–2589. DOI: 10.1016/0022-1902(69)80591-9.
   Web of Science ®Google Scholar
• Huh, C.; Mason, S. G. A Rigorous Theory of Ring Tensiometry. Colloid Polym. Sci. 1975, 253(7), 566–580. DOI: 10.1007/BF01753960.
   Web of Science ®Google Scholar
• Drew, M. G.; Iveson, P. B.; Hudson, M. J.; Liljenzin, J.-O.; Spjuth, L.; Cordier, P.-Y.; Enarsson, Å.; Hill, C.; Madic, C. Separation of Americium (III) from Europium (III) with Tridentate Heterocyclic Nitrogen Ligands and Crystallographic Studies of Complexes Formed by 2, 2′: 6′, 2ʺ-terpyridine with the Lanthanides. J. Chem. Soc. Dalton Trans. 2000, 821–830. doi:10.1039/a907077j.
   Google Scholar
• Chiarizia, R.; Briand, A.; Jensen, M. P.; Thiyagarajan, P. Sans Study of Reverse Micelles Formed upon the Extraction of Inorganic Acids by TBP in n‐Octane. Solvent Extr. Ion Exch. 2008, 26(4), 333–359. DOI: 10.1080/07366290802182394.
   Web of Science ®Google Scholar
• Osseo-Asare, K.; Zheng, Y. The Solubilization of an Aliphatic Hydroxyoxime by Dinonylnaphthalene Sulfonic Acid Reversed Micelles. Colloids Surf. 1987, 28, 9–17. DOI: 10.1016/0166-6622(87)80162-2.
   Google Scholar
• Osseo-Asare, K.; Keeney, M. Aspects of the Interfacial Chemistry of Nickel Extraction with LIX63-HDNNS Mixtures. Metall. Trans. B. 1980, 11(1), 63–67. DOI: 10.1007/BF02657172.
   Web of Science ®Google Scholar
• Osseo-Asare, K.; Renninger, D. Synergic Extraction of Nickel and Cobalt by LIX63-dinonylnaphthalene Sulfonic Acid Mixtures. Hydrometallurgy. 1984, 13(1), 45–62. DOI: 10.1016/0304-386X(84)90016-1.
   Web of Science ®Google Scholar
• Osseo-Asare, K. Enhanced Solvent Extraction with Water-in-Oil Microemulsions. Sep. Sci. Technol. 1988, 23(12–13), 1269–1284. DOI: 10.1080/01496398808075629.
   Web of Science ®Google Scholar
• Nilsson, M.; Studies of a Synergistic Extraction System for Minor Actinides and the Chemical Properties of 2-bromodecanoic acid. Chalmers University of Technology, Göteborg, Sweden, 2003. ( Licenciate Thesis).
   Google Scholar
• Meinrath, G.; Ekberg, C.; Landgren, A.; Liljenzin, J.-O. Assessment of Uncertainty in Parameter Evaluation and Prediction. Talanta. 2000, 51(2), 231–246. DOI: 10.1016/S0039-9140(99)00259-3.
   PubMed Web of Science ®Google Scholar
• Rydberg, J. Hydrophilic Actinide Complexation Studied by Solvent Extraction Radiotracer Technique. Rev. Inorg. Chem. 1999, 19(4), 245–301. DOI: 10.1515/REVIC.1999.19.4.245.
   Web of Science ®Google Scholar
• Peppard, D.; Mason, G.; Hucher, I. Stability Constants of Certain Lanthanide (III) and Actinide (III) Chloride and Nitrate Complexes. J. Inorg. Nucl. Chem. 1962, 24(7), 881–888. DOI: 10.1016/0022-1902(62)80109-2.
   Web of Science ®Google Scholar
• Tournier, R.; Davis, M., Jr. Distribution, Rate of Extraction, and Complexing Action of ThenoyItrifluoroacetone in the Synergistic System Kerosine/ThenoyItrifluoroacetone/Tributylphosphate/Dilute HNO3. Sep Sci. 1972, 7(2), 159–186.
   Google Scholar
• Pai, S. A.; Subramanian, M. S. Synergistic Extraction of Uranyl Ion with 1-phenyl-3-methyl-4-benzoylpyrazolone-5 (HPMBP) and Diphenyl Sulfoxide (DPSO), Tri-n-butyl Phosphate (TBP) or Tri-n-octylphosphine Oxide (TOPO). J. Radioanal. Nucl. Chem. 1985, 89(2), 423–433. DOI: 10.1007/BF02040606.
   Web of Science ®Google Scholar
• Mathur, J.; Pai, S.; Khopkar, P.; Subramanian, M. Thermodynamics of Synergistic Extraction of Europium (III) by Mixtures of Thenoyltrifluoroacetone and Some Neutral Oxo-donors. J. Inorg. Nucl. Chem. 1977, 39(4), 653–657. DOI: 10.1016/0022-1902(77)80582-4.
   Web of Science ®Google Scholar
• Vo, Q. N.; Unangst, J. L.; Nguyen, H. D.; Nilsson, M. Quantifying Dimer and Trimer Formation of Tri-N-Butyl Phosphates in Different Alkane Diluents: FTIR Study. J. Phys. Chem. B. 2016, 120(28), 6976–6984. DOI: 10.1021/acs.jpcb.6b02923.
   PubMed Web of Science ®Google Scholar