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Review Article

Review of Ion Exchange Technologies for Cesium Removal from Caustic Tank Waste

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References

  • Poirier, M. R.; Peters, T. B.; Brass, E. A.; Brown, S. J.; Geeting, M. W.; Johnson, L. C.; Coleman, C. J.; Crump, S. L.; Barnes, M. J.; Fink, S. D. Full-Scale Testing of a Caustic Side Solvent Extraction System to Remove Cesium from Savannah River Site Radioactive Waste. Sep. Sci. Technol. 2008, 43, 2797–2813. DOI: 10.1080/01496390802148720.
  • King, W. D.; Hamm, L. L.; Nash, C. A. Tank Closure Cesium Removal Project CST Simulant Cesium Batch Contact Kinetics Test Results and Column Performance Predictions; Technical Report SRNL-STI-2019-00088, Rev. 0; Savannah River National Laboratory: Aiken, SC, 2019.
  • Pease, L. F.; Fiskum, S. K.; Colburn, H. A.; Schonewill, P. P. Cesium Ion Exchange with Crystalline Silicotitanate Literature Review; Technical Report PNNL-28343; Pacific Northwest National Laboratory: Richland, WA, 2019.
  • Gephart, R. E. A Short History of Hanford Waste Generation, Storage, and Release; Technical Report PNNL-13605, Rev. 4; Pacific Northwest National Laboratory: Richland, WA, 2003.
  • Carlton, W. H.; Bauer, L. R.; Evans, A. G.; Geary, L. A.; Murphy, C. E., Jr.; Pinder, J. E.; Strom, R. N. Cesium in the Savannah River Site Environment; Technical Report WSRC-RP-92-250; Westinghouse Savannah River Co.: Aiken, SC, 1992.
  • Kimmel, R. Idaho High-Level Waste and Facilities Disposition, Final Environmental Impact Statement; Technical Report DOE/EIS-0287; U.S. Department of Energy: Washington, D.C., 2002. https://www.energy.gov/sites/prod/files/nepapub/nepa_documents/RedDont/EIS-0287-FEIS-01-2002.pdf
  • Kelly, S., Jr.; Meess, D. C. THOREX Processing and Zeolite Transfer for High-Level Waste Stream Processing Blending; Technical Report DOE/NE/44139-82; West Valley Nuclear Services Company, Inc.: West Valley, NY, 1997.
  • Agnew, S. F. Hanford Tank Chemical and Radionuclide Inventories: HDW Model Rev. 4; Technical Report LA-UR-96-3860; Los Alamos National Laboratory: Los Alamos, NM, 1996; p 664.
  • Cleveland, J. The Chemistry of Plutonium; American Chemical Society: La Grange Park, IL, 1979.
  • Wilmarth, W. R.; Johnson, M. E.; Lumetta, G. J.; Poirier, M. R.; Thompson, M. C.; Machara, N. The Role of Liquid Waste Pretreatment Technologies in Solving the DOE Cleanup Mission; Technical Report SRNL-STI-2008-00426; Savannah River National Laboratory: Aiken, SC, 2008.
  • Dalton, W. J. Qualification Testing and Full-Scale Demonstration of Titanium-Treated Zeolite for Sludge Wash Processing; Technical Report DOE/NE/44139-72; West Valley Nuclear Services Company: West Valley, NY, 1997.
  • Billingsley, K.; Mims, C.; Robinson, S. The Integrated Tank Waste Management Plan at Oak Ridge National Laboratory; Technical Report ORNL/CP-98216; Oak Ridge National Laboratory: Oak Ridge, TN, 1998.
  • Brooks, K. P.; Kim, A. Y.; Kurath, D. E. Assessment of Commercially Available Ion Exchange Materials for Cesium Removal from Highly Alkaline Wastes; Technical Report PNNL-11121; Pacific Northwest National Laboratory: Richland, WA, 1996.
  • Brown, G. N. Literature Review of Spherical Resorcinol-Formaldehyde for Cesium Ion Exchange; Technical Report PNNL-23410; Pacific Northwest National Laboratory: Richland, WA, 2014.
  • King, W. D. Literature Reviews to Support Ion Exchange Technology Selection for Modular Salt Processing; Technical Report WSRC-STI-2007-00609; Washington Savannah River Company, Aiken, SC, 2007.
  • Pillay, K. A. Review of the Radiation Stability of Ion Exchange Materials. J. Radioanal. Nucl. Chem. 1986, 102, 247–268. DOI: 10.1007/BF02037966.
  • Wilmarth, W. R.; Lumetta, G. J.; Johnson, M. E.; Poirier, M. R.; Thompson, M. C.; Suggs, P. C.; Machara, N. P. Review: Waste-Pretreatment Technologies for Remediation of Legacy Defense Nuclear Wastes. Solvent Extr. Ion Exch. 2011, 29, 1–48. DOI: 10.1080/07366299.2011.539134.
  • Eager, K. M.; Penwell, D. L.; Knutson, B. Preliminary Flowsheet: Ion Exchange Process for the Separation of Cesium from Hanford Tank Waste Using DuoliteTM CS-100 Resin; Technical Report WHC-SD-WM-TI-667; Westinghouse Hanford Company: Richland, WA, 1994.
  • Bray, L. A. Recovery of Cesium from PUREX Alkaline Waste with a Synthetic Zeolite; Technical Report BNWL-288; Battelle-Pacific Northwest Laboratory: Richland, WA, 1967.
  • Lewis, R. E.; Butler, T. A.; Lamb, E. An Aluminosilicate Ion Exchanger for Recovery and Transport of 137Cs from Fission-Product Wastes. Nucl. Sci. Eng. 1966, 24, 118–122. DOI: 10.13182/NSE66-A18296.
  • Buckingham, J. S. Laboratory Evaluation of an Ion Exchange Process for Removing Cesium from PUREX Acid Waste Solutions. Technical Report RHO-CD-739, Rockwell International Corporation, Richland, WA, 1979.
  • Barton, W.; Gale, L.; Johnson, M. Sixteen Years of Cesium Recovery Processing at Hanford’s B Plant; Technical Report RHO-RE-SA-169; Rockwell Hanford Operations: Niagara Falls, NY, 1986.
  • Harjula, R.; Lehto, J. Effect of Sodium and Potassium Ions on Cesium Absorption from Nuclear Power Plant Waste Solutions on Synthetic Zeolites. Nucl. Chem. Waste Manage. 1986, 6, 133–137. DOI: 10.1016/0191-815X(86)90051-3.
  • Wiley, J. R.; Wallace, R. M. Removal of Cesium from Savannah River Plant Waste Supernate; Technical Report DP-1388; E. I. du Pont de Nemours & Co.: Aiken, SC, 1975.
  • Carlstrom, R. Ion Exchange Flowsheet for Recovery of Cesium from PUREX Sludge Supernatant at B Plant; Technical Report ARH-F-106; Atlantic Richfield Hanford Company: Richland, WA, 1977.
  • Landon, L. F. Preliminary Technical Data Summary No. 3 For the Defense Waste Processing Facility; Technical Report DPSTD-77-13-3; E. I. du Pont de Nemours and Co.: Aiken, SC, 1980.
  • Chilton, J. M. Evaluation of the Low-Level Waste Treatment Plant at Oak Ridge National Laboratory and Suggested Changes in the Design and Operation; Technical Report ORNL-5618; Oak Ridge National Laboratory: Oak Ridge, TN, 1980.
  • Kurath, D. E.; Bray, L. A.; Brooks, K. P.; Brown, G. N.; Bryan, S. A.; Carlson, C. D.; Carson, K. J.; DesChane, J. R.; Elovich, R. J.; Kim, A. Y. Experimental Data and Analysis to Support the Design of an Ion-Exchange Process for the Treatment of Hanford Tank Waste Supernatant Liquids; Technical Report PNL-10187; Pacific Northwest Laboratory: Richland, WA, 1994.
  • Kent, T. E.; Villiers-Fisher, J. F.; Harrington, F. E. Selection of an Interim Upgrade Strategy for the Process Waste Treatment Plant at Oak Ridge National Laboratory; Technical Report ORNL/TM-11384; Oak Ridge National Laboratory: Oak Ridge, TN, 1991.
  • Bray, L. A.; Carson, K. J.; Elovich, R. J. Initial Evaluation of Sandia National Laboratory-Prepared Crystalline Silicotitanate for Cesium Recovery; Technical Report PNL-8847; Pacific Northwest Laboratory: Richland, WA, 1993.
  • Bray, L. A.; Carson, K. J.; Elovich, R. J.; Kurath, D. E. Equilibrium Data for Cesium Ion Exchange of Hanford CC and NCAW Tank Waste; Technical Report PNNL-11123; Pacific Northwest National Laboratory: Richland, WA, 1996.
  • Kurath, D. E.; Bray, L. A.; Ross, W. A.; Ploetz, D. K. Correlation of Laboratory Testing and Actual Operations for the West Valley Supernatant Treatment System. Nuclear Waste Management III: 4th International Symposium of Ceramics in Nuclear Waste Management, American Ceramic Society, Westerville, OH, 1989.
  • Collins, E. D.; Campbell, D. O.; King, L. J.; Knauer, J. B.; Wallace, R. M. Evaluation of Zeolite Mixtures for Decontaminating High-Activity-Level Water at the Three Mile Island Unit 2 Nuclear Power Station. Conference: IAEA Technical Committee meeting on inorganic ion exchangers and absorbents for chemical processing in the nuclear fuel cycle, Vienna, Austria, June 12-15, 1984, Oak Ridge National Laboratory: Oak Ridge, TN, 1984.
  • Sanchez, H. F.; Quinn, G. Submerged Demineralizer System Processing of TMI-2 Accident Waste Water; Technical Report GEND-031; EG and G Idaho, Inc.: Idaho Falls, ID, 1983.
  • Abe, H.; Susa, S.; Sugimori, T.; Tajima, N.; Yamamoto, S.; Oomura, H.; Ikeda, A.; Saso, M.; Ishikawa, K. Radioactive Waste Water Treatment for Fukushima Daiichi Nuclear Power Plant–16081. Waste Management 2016 Conference, Phoenix, AZ, March 6–10, 2016.
  • Lehto, J.; Koivula, R.; Leinonen, H.; Tusa, E.; Harjula, R. Removal of Radionuclides from Fukushima Daiichi Waste Effluents. Sep. Purif. Rev. 2019, 48, 122–142. DOI: 10.1080/15422119.2018.1549567.
  • Bibler, J. P.; Wallace, R. M. Cesium-specific Phenolic Ion Exchange Resin. U.S. Patent 5,441,991, August 15, 1995.
  • Brooks, K. P.; Augspurger, B. S.; Blanchard, D. L., Jr.; Cuta, J. M.; Fiskum, S. K.; Thorson, M. R. Hydraulic Testing of Ion Exchange Resins for Cesium Removal from Hanford Tank Waste. Sep. Sci. Technol. 2006, 41, 2391–2408. DOI: 10.1080/01496390600742724.
  • Hamm, L. L.; Aleman, S. E.; Hardy, B. J.; King, W. D.; Duffey, C. E. Ion Exchange Modeling for Removal of Cesium from Hanford Waste Using SuperLig® 644 Resin; Technical Report WSRC-TR-2003-00555; Westinghouse Savannah River Company: Aiken, SC, 2004.
  • Rapko, B. M.; Blanchard, D. L., Jr.; Carson, K. J.; DesChane, J. R.; Sell, R. L.; Swoboda, R. G. Batch Contact Testing of SuperLig® 644; Technical Report PNWD-3265; Battelle-Pacific Northwest Division: Richland, WA, 2003.
  • Bray, L. A. Efficient Separations and Processing Crosscutting Program: Develop and Test Sorbents; Technical Report PNL-10750; Pacific Northwest Laboratory: Richland, WA, 1995.
  • Fiskum, S. K.; Blanchard, D. L., Jr.; Steele, M. J.; Wagner, J. J. Analysis of SuperLig® 644 Resin Used in Hanford Tank Waste Processing; Technical Report PNWD-3353, Rev. 1; Battelle-Pacific Northwest Division: Richland, WA, 2004.
  • Arm, S. T.; Blanchard, D. L., Jr.; Fiskum, S. K.; Weier, D. R. Chemical Degradation of SuperLig®644 Ion Exchange Resin; Technical Report PNWD-3315; Battelle-Pacific Northwest Division: Richland, WA, 2003.
  • Fiskum, S. K.; Blanchard, D. L., Jr.; Arm, S. T.; Peterson, R. A. Cesium Removal from Simulated and Actual Hanford Tank Waste Using Ion Exchange. Sep. Sci. Technol. 2005, 40, 51–67. DOI: 10.1081/SS-200041760.
  • Hassan, N. M.; Adu-Wusu, K.; Nash, C. A. Multiple Ion Exchange Column Runs for Cesium and Technetium Removal from AW-101 Waste Sample; Technical Report WSRC-TR-2003-00098, SRT-RPP-2003-00026; Westinghouse Savannah River Company: Aiken, SC, 2003.
  • Steimke, J. L.; Norato, M. A.; Steeper, T. J.; McCabe, D. J. Summary of Initial Testing of SuperLig® 644 at the TFL Ion Exchange Facility; Technical Report WSRC-TR-2000-00505; Westinghouse Savannah River Company: Aiken, SC, 2001.
  • Arm, S. T.; Blanchard, D. L., Jr.; Brooks, K. P.; Buchmiller, W. C.; Cook, B. J.; Cuta, J. M.; Fiskum, S. K.; Hontz, Z.; Isackson, C.; Schepmoes, A. A.; et al. Laboratory Scale Hydraulic Testing of Spherical Resorcinol-Formaldehyde Ion Exchange Resins; Technical Report PNWD-3763; Battelle-Pacific Northwest Division: Richland, WA, 2006.
  • Brown, G. N.; Adami, S. R.; Bray, L. A.; Bryan, S. A.; Carlson, C. D.; Carson, K. J.; DesChane, J. R.; Elovich, R. J.; Forbes, S. J.; Franz, J. A.; et al. Chemical and Radiation Stability of SuperLig®644, Resorcinol-Formaldehyde, and CS-100 Cesium Ion Exchange Materials; PNL-10772; Pacific Northwest Laboratory: Richland, WA, 1995.
  • Berg, A.; Nilsen, T.; Bjørgum, J.; Ugelstad, J. Process for Preparing a Dispersion and for Preparing Polymer Particles. U.S. Patent 5,677,373, October 14, 1997. Trondheim, Norway, Sinvent A/S.
  • Nyman, M.; Nenoff, T. M.; Headley, T. J. Characterization of UOP IONSIV IE-911; Technical Report SAND2001-0999; Sandia National Laboratories: Albuquerque, NM, 2001.
  • Celestian, A.; Kubicki, J.; Hanson, J.; Clearfield, A.; Parise, J. The Mechanism Responsible for Extraordinary Cs Ion Selectivity in Crystalline Silicotitanate. J. Amer. Chem. Soc. 2008, 130, 11689–11694. DOI: 10.1021/ja801134a.
  • Chitra, S.; Sudha, R.; Kalavathi, S.; Mani, A. G. S.; Rao, S. V. S.; Sinha, P. K. Optimization of Nb-substitution and Cs+/Sr+2 Ion Exchange in Crystalline Silicotitanates (CST). J. Radioanal. Nucl. Chem. 2013, 295, 607–613. DOI: 10.1007/s10967-012-1812-0.
  • Walker, J. F., Jr.; Taylor, P. A.; Cummins, R. L. Cesium Removal Demonstration Utilizing Crystalline Silicotitanate Sorbent for Processing Melton Valley Storage Tank Supernate: Final Report; Technical Report ORNL/TM-13503; Oak Ridge National Laboratory: Oak Ridge, TN, 1998.
  • Walker, J. F., Jr.; Kent, T. E. Wastewater Triad Project: Final Summary Report; Technical Report ORNL/TM-2001/129; Oak Ridge National Laboratory; Oak Ridge, TN, 2001.
  • Fiskum, S. K.; Arm, S. T.; Buchmiller, W. C.; Trang-Le, T. T.; Martinez, J. E.; Matyas, J.; Steele, M. J.; Thomas, K. K.; Blanchard, D. L., Jr. Comparison Testing of Multiple Spherical Resorcinol-Formaldehyde Resins for the River Protection Project—Waste Treatment Plant; Technical Report PNWD-3785; Battelle-Pacific Northwest Division: Richland, WA, 2006.
  • Fiskum, S. K.; Augspurger, B. S.; Brooks, K. P.; Buchmiller, W. C.; Russell, R. L.; Schweiger, M. J.; Snow, L. A.; Steele, M. J.; Thomas, K. K.; Wallace, D. E.; et al. Comparison Testing of Multiple Resorcinol-Formaldehyde Resins for the River Protection Project—Waste Treatment Plant; Technical Report PNWD-3387; Battelle-Pacific Northwest Division: Richland, WA, 2004.
  • Adamson, D. J. Pilot-Scale Hydraulic Testing of Resorcinol Formaldehyde Ion Exchange Resin. Proceedings of ASME 2009 Fluids Engineering Division Summer Meeting, Vail, CO, Paper FEDSM2009-78040, 2009.
  • Fiskum, S. K.; Peterson, R. A.; Colburn, H. A.; Smoot, M. R.; Landon, M. R.; Colosi, K. A.; Wilson, R. A. Small- to Large-Scale Comparisons of Cesium Ion Exchange Performance with Spherical Resorcinol-Formaldehyde Resin. Sep. Sci. Technol. 2019, 54, 1922–1931. DOI: 10.1080/01496395.2019.1570262.
  • Rovira, A. M.; Fiskum, S. K.; Allred, J. R.; Geeting, J. G. H.; Colburn, H. A.; Carney, A. M.; Trang-Le, T. T.; Peterson, R. A. Dead-End Filtration and Crystalline Silicotitanate Cesium Ion Exchange with Hanford Tank Waste AW-102; Technical Report PNNL-28783, Rev. 0; Pacific Northwest National Laboratory: Richland, WA, 2019.
  • Fiskum, S. K.; Smoot, M. R.; Peterson, R. A.; Colburn, H. A.; Allred, J. R. Cesium Ion Exchange Using Spherical Resorcinol-Formaldehyde Resin in Support of Waste Qualification Testing for LAWPS; Technical Report PNNL-26837; Pacific Northwest National Laboratory: Richland, WA, 2017.
  • King, W. D.; Duffey, C. E.; Malene, S. H. Determination of Cesium (Cs+) Adsorption Kinetics and Equilibrium Isotherms from Hanford Waste Simulants Using Resorcinol-Formaldehyde Resins (U); Technical Report WSRC-TR-2003-00574; Westinghouse Savannah River Company: Aiken, SC, 2004.
  • Fiskum, S. K.; Rovira, A. M.; Colburn, H. A.; Carney, A. M.; Peterson, R. A. Cesium Ion Exchange Testing Using a Three-Column System with Crystalline Silicotitanate and Hanford Tank Waste 241-AP-107; Technical Report PNNL-28958, Rev. 0; Pacific Northwest National Laboratory: Richland, WA, 2019.
  • Nash, C. A.; Duignan, M. R.; Duffey, C. E. Batch, Kinetics, and Column Data from Spherical Resorcinol-Formaldehyde Resin; Technical Report WSRC-STI-2006-00071, Rev. 0; Washington Savannah River Company: Aiken, SC, 2006.
  • Russell, R. L.; Fiskum, S. K.; Smoot, M. R.; Rinehart, D. E. Cesium Isotherm Testing with Spherical Resorcinol-Formaldehyde Resin at High Sodium Concentrations; Technical Report PNNL-25277; Pacific Northwest National Laboratory: Richland, WA, 2016.
  • Russell, R. L.; Rinehart, D. E.; Brown, G. N.; Schonewill, P. P.; Peterson, R. A. Ion Exchange Kinetics Testing with sRF Resin; Technical Report PNNL-21109; Pacific Northwest National Laboratory: Richland, WA, 2012.
  • Nash, C. A.; Duignan, M. R. Real Waste Testing of Spherical Resorcinol-Formaldehyde Ion Exchange Resin; Technical Report SRNL-STI-2009-00594;, Savannah River National Laboratory: Aiken, SC, 2009.
  • Miller, J. E.; Brown, N. E. Development and Properties of Crystalline Silicotitanate (CST) Ion Exchangers for Radioactive Waste Applications; Technical Report SAND97-0771; Sandia National Laboratories: Albuquerque, NM, 1997.
  • Brown, G. N.; Bray, L. A.; Carlson, C. D.; Carson, K. J.; DesChane, J. R.; Elovich, R. J.; Hoopes, F. V.; Kurath, D. E.; Nenninger, L. L.; Tanaka, P. K. Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241-AW-101 DSSF Tank Waste; Technical Report PNNL-11120; Pacific Northwest National Laboratory: Richland, WA, 1996.
  • Zheng, Z.; Philip, C. V.; Anthony, R. G.; Krumhans, J. L.; Trudell, D. E.; Miller, J. E. Ion Exchange of Group I Metals by Hydrous Crystalline Silicotitanates. Ind. Eng. Chem. Res. 1996, 35, 4246–4256. DOI: 10.1021/ie960073k.
  • Aleman, S. E.; Hamm, L. L.; Smith, F. G. Ion Exchange Modeling of Cesium Removal from Hanford Waste Using Spherical Resorcinol-Formaldehyde Resin; Technical Report WSRC-STI-2007-00030; Savannah River Site: Aiken, SC, 2007.
  • Hamm, L. L.; Hang, T.; McCabe, D. J.; King, W. D. Preliminary Ion Exchange Modeling for Removal of Cesium from Hanford Waste Using Hydrous Crystalline Silicotitanate Material; Technical Report WSRC-TR-2001-00400; Westinghouse Savannah River Company: Aiken, SC, 2002.
  • Fiskum, S. K.; Bredt, P. R.; Campbell, J. A.; Greenwood, L. R.; Farmer, O. T.; Lumetta, G. J.; Mong, G. M.; Ratner, R. T.; Soderquist, C. Z.; Swoboda, R. G.; et al. Inorganic, Radioisotopic and Organic Analysis of 241-AP-101 Tank Waste; Technical Report PNWD-3046; Battelle-Pacific Northwest Division: Richland, WA, 2000.
  • Urie, M. W.; Campbell, J. A.; Farmer, O. T.; Fiskum, S. K.; Greenwood, L. R.; Hoppe, E. W.; Mong, G. M.; Soderquist, C. Z.; Swoboda, R. G.; Thomas, M. P.; et al. Chemical Analysis and Physical Property Testing of 24-AN-102 Tank Waste—Supernatant and Centrifuged Solids; Technical Report PNWD-3229; Battelle-Pacific Northwest Division: Richland, WA, 2002.
  • Fiskum, S. K.; Arm, S. T.; Steele, M. J.; Thorson, M. R. Spherical Resorcinol-Formaldehyde Performance Testing with Hanford Tank Waste. Solvent Extr. Ion Exch. 2008, 26, 435–452. DOI: 10.1080/07366290802182691.
  • King, W. D.; Hamm, L. L.; Coleman, C. J.; Fondeur, F. F.; Reboul, S. H. Crystalline Silicotitanate (CST) Ion Exchange Media Performance Evaluations in SRS Average Supernate Simulant and Tank 10H Waste Solution to Support TCCR; Technical Report SRNL-STI-2018-0027; Savannah River National Laboratory: Aiken, SC, 2018.
  • Kutus, B.; Gácsi, A.; Pallagi, A.; Pálinkó, I.; Peintler, G.; Sipos, P. A Comprehensive Study on the Dominant Formation of the Dissolved Ca(OH)2(aq) in Strongly Alkaline Solutions Saturated by Ca(II). RSC Adv. 2016, 6, 45231–45240. DOI: 10.1039/C6RA05337H.
  • Rovira, A. M.; Fiskum, S. K.; Colburn, H. A.; Allred, J. R.; Smoot, M. R.; Peterson, R. A. Cesium Ion Exchange Testing Using Crystalline Silicotitanate with Hanford Tank Waste 241-AP-107; Technical Report PNNL-27706; Pacific Northwest National Laboratory: Richland, WA, 2018.
  • Wilmarth, W. R.; Dukes, V. H.; Mills, J. T. Reactivity of Crystalline Silicotitanate (CST) and Hazardous Metal/Actinide Loading during Low Curie Salt Use; Technical Report WSRC-TR-2004-00588; Westinghouse Savannah River Company: Aiken, SC, 2004.
  • Campbell, E. L.; Rovira, A. M.; Colon-Cintron, F.; Boglaienko, D.; Levitskaia, T. G.; Peterson, R. A. Characterization of Cs-Loaded CST Used for Treatment of Hanford Tank Waste in Support of Tank-Side Cesium Removal; Technical Report PNNL-28945, Rev. 0; Pacific Northwest National Laboratory: Richland, WA, 2019.
  • Fiskum, S. K.; Arm, S. T.; Fountain, M. S.; Steele, M. J.; Blanchard, D. L., Jr. Spherical Resorcinol-Formaldehyde Resin Testing for 137Cs Removal from Simulated and Actual Hanford Waste Tank 241-AP-101 Diluted Feed (Envelope A) Using Small-Column Ion Exchange; Technical Report PNWD-3697; Battelle-Pacific Northwest Division: Richland, WA, 2006.
  • Fiskum, S. K.; Colburn, H. A.; Rovira, A. M.; Allred, J. R.; Smoot, M. R.; Peterson, R. A.; Landon, M. R.; Colosi, K. A. Cesium Removal from AP-105 Hanford Tank Waste Using Spherical Resorcinol-Formaldehyde Resin. Sep. Sci. Technol. 2019, 54, 1932–1941. DOI: 10.1080/01496395.2019.1577273.
  • Nash, C. A.; Duignan, M. R. Characterization of Cycled Spherical Resorcinol-Formaldehyde Ion Exchange Resin; Technical Report SRNL-STI-2009-00605; Savannah River National Laboratory: Aiken, SC, 2010.
  • Nelson, J. L.; Mercer, B. W. Ion Exchange Separation of Cesium from Alkaline Waste Supernatant Solutions; Technical Report HW-76449; General Electric Company: Richland, WA, 1963.
  • Fiskum, S. K.; Rovira, A. M.; Allred, J. R.; Colburn, H. A.; Smoot, M. R.; Carney, A. M.; Trang-Le, T. T.; Cantaloub, M. G.; Buck, E. C.; Peterson, R. A. Cesium Removal from Tank Waste Simulants Using Crystalline Silicotitanate at 12% and 100% TSCR Bed Heights; Technical Report PNNL-28527, Rev. 0; Pacific Northwest National Laboratory: Richland, WA, 2019.
  • Taylor, P. A.; Mattus, C. H. Thermal and Chemical Stability of Baseline and Improved Crystalline Silicotitanate; Technical Report ORNL/TM-2001/165; Oak Ridge National Laboratory: Oak Ridge, TN, 2001.
  • Harland, C.;. Ion Exchange: Theory and Practice, 2nd Edition; The Royal Society of Chemistry: Cambridge, United Kingdom, 1994.
  • Nguyen, L. T.; A Kinetic Model for Ion Exchange between Cesium and Sodium Using Silico-Titanates. Ph.D. Dissertation, Texas A&M University, College Station, 1994.
  • Treybal, R. E.;. Mass-Transfer Operations, First ed.; McGraw-Hill: New York, NY, 1955.
  • King, W. D.; Hamm, L. L.; McCabe, D. J.; Nash, C. A.; Fondeur, F. F. Crystalline Silicotitanate Ion Exchange Media Long-Term Storage Evaluation; Technical Report SRNL-STI-2018-00567, Rev. 0; Savannah River National Laboratory: Aiken, SC, 2018.
  • Bibler, N. E.; Crawford, C. L. An Investigation of the Radiolytic Stability of a Resorcinol-Formaldehyde Ion Exchange Resin; Technical Report WSRC-RP-94-148; Westinghouse Savannah River Company: Aiken, SC, 1994.
  • Carlson, C. D.; Bray, L. A.; Bryan, S. A. Radiation Testing of Organic Ion Exchange Resins; Technical Report PNL-10767; Pacific Northwest Laboratory: Richland, WA, 1995.
  • Mattus, A. J.; Kent, T. E.; Taylor, P. A. Study of the Potential Impact of Gamma-Induced Radiolytic Gases on Loading of Cesium onto Crystalline Silicotitanate Sorbent at ORNL’s High Flux Isotope Reactor; Technical Report ORNL/TM-2000/362; Oak Ridge National Laboratory: Oak Ridge, TN, 2001.
  • Colburn, H. A.; Bryan, S. A.; Camaioni, D. M.; Mahoney, L. A.; Adami, S. R. Gas Generation Testing of Spherical Resorcinol-Formaldehyde (sRF) Resin; Technical Report PNNL-26869, Rev. 0; Pacific Northwest National Laboratory: Richland, WA, 2018.
  • Bibler, N. E.; Crawford, C. L.; Biddle, C. R. Results of Scoping Studies for Determining Radiolytic Hydrogen Production from Moist CST and CST Slurries; Technical Report WSRC-RP-98-01143; Westinghouse Savannah River Company: Aiken, SC, 1998.
  • Colburn, H. A.; Rovira, A. M.; Adami, S. R.; Camaioni, D. M.; Bryan, S. A.; Schonewill, P. P. Gas Generation Testing of Crystalline Silicotitanate Ion Exchange Media; Technical Report PNNL-28842, Rev. 1; Pacific Northwest National Laboratory: Richland, WA, 2019.
  • Walker, D. D.; Radiolytic Gas Generation in Crystalline Silicotitanate Slurries; Technical Report WSRC-TR-99-00285, Rev. 1; Westinghouse Savannah River Company: Aiken, SC, 2003.
  • King, W. D.; Fondeur, F. F.; Wilmarth, W. R.; Pettis, M. E.; McCollum, S. W. Reactivity of Resorcinol-Formaldehyde Resin with Nitric Acid. Sep. Sci. Technol. 2006, 41, 2475–2486. DOI: 10.1080/01496390600743151.
  • Adamson, D. J.; Fowley, M. D.; Steimke, J. L.; Steeper, T. J.; Williams, M. R.; Duffey, C. E.; Fondeur, F. F. Pilot-Scale Hydraulic Testing of Resorcinol-Formaldehyde Ion Exchange Resin; Technical Report SRNL-RPP-2006-00013; Savannah River National Laboratory: Aiken, SC, 2006.
  • Walker, J. F., Jr.; Taylor, P. A.; Spence, R. D.; Slater, C. O.; Walker, D. D.; Bickford, D. F.; Lee, S. Y.; Aleman, S. E.; Hamm, L. L. Small-Column Ion-Exchange Alternative to Remove 137Cs from Low Curie Salt Waste: Summary of Phase 1; Technical Report ORNL/TM-2003/287; Oak Ridge National Laboratory: Oak Ridge, TN, 2004.
  • Fiskum, S. K.; Burgeson, I. E.; Farmer, O. T.; Greenwood, L. R.; Soderquist, C. Z.; Steele, M. J.; Thomas, M. P. Spherical Resorcinol-Formaldehyde Resin Analysis Following Actual Hanford Tank Waste Processing; Technical Report PNWD-3752; Battelle-Pacific Northwest Division: Richland, WA, 2006.
  • Nash, C. A.; Fowley, M. D. Characterization of Spent Spherical Resorcinol-Formaldehyde Resin; Technical Report WSRC-STI-2007-00213, Rev. 0; Washington Savannah River Company: Aiken, SC, 2007.
  • IAEA. International Peer Review Mission on Mid-And-Long-Term Roadmap toward the Decommissioning of TEPCO’s Fukushima Daiichi Nuclear Power Station (Fourth Mission). 2018. https://www.iaea.org/sites/default/files/19/01/missionreport-310119.pdf.
  • Andrews, M. K.; Fellinger, T. L.; Ferrara, D. M.; Harbour, J. R.; Herman, D. T. Vitrification of Cesium-Loaded Crystalline Silicotitanate (CST) in the Shielded Cells Melter; Technical Report WSRC-TR-97-00314; Westinghouse Savannah River Company: Aiken, SC, 1997.
  • Russell, R. L.; Kim, D. S.; Vienna, J. D.; Gervasio, V.; Skidmore, C. H.; Riley, B. J.; Peterson, R. A. Cold Crucible Vitrification of Non-Radioactive CST and Simulated Hanford Tank Waste; Technical Report PNNL-28895, Rev. 0; Pacific Northwest National Laboratory: Richland, WA, 2019.

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