Highly Efficient Pertraction of Tetravalent Neptunium Ions Across a Flat Sheet Supported Liquid Membrane Containing Two Different Aza-Crown Ether-Based Multiple Diglycolamide Ligands

References

• Lange, R. G.; Carroll, W. P. Review of Recent Advances of Radioisotope Power Systems. Energy Convers. Manage. 2008, 49(3), 393–401.
   Web of Science ®Google Scholar
• Verma, P. K.; Mohapatra, P. K. Fate of Neptunium in Nuclear Fuel Cycle Streams: State-of-The Art on Separation Strategies. Radiochim. Acta 2022, 110(6–9), 527–548.
   Web of Science ®Google Scholar
• Edwards, S.; Andrieux, F.; Boxall, C.; Sarsfield, M.; Taylor, R.; Woodhead, D. Neptunium (IV)-Hydroxamate Complexes: Their Speciation, and Kinetics and Mechanism of Hydrolysis. Dalton Trans. 2019, 48(2), 673–687.
   PubMed Web of Science ®Google Scholar
• (a) Krishnamurthy, M.; Sipahimalani, A. Radiolytic Degradation of TBP-HNO3 System: Gas Chromatographic Determination of Radiation Chemical Yields of n-Butanol and Nitrobutane. J. Radioanal. Nucl. Chem. 1995, 199(3), 197–206. (b) Serenko, Y. V.; Belova, E.; Ponomarev, A.; Yudin, N. The Effect of Radiolysis and Thermally Stimulated Acid Hydrolysis on Tributyl Phosphate and its Solutions in ISOPAR-M. Radiat. Phys. Chem. 2022, 195, 110080.
   Web of Science ®Google Scholar
• (a) Liu, Y.; Zhao, C.; Liu, Z.; Liu, S.; Zhou, Y.; Jiao, C.; Zhang, M.; Gao, Y.; He, H.; Zhang, S. Study on the Extraction of Lanthanides by Isomeric Diglycolamide Extractants: An Experimental and Theoretical Study. RSC Adv. 2022, 12(2), 790–797. (b) Rout, A.; Venkatesan, K. A.; Antony, M.; Rao, P. R. V. Comparison in the Extraction Behavior of Uranium (VI) from Nitric Acid Medium Using CHON Based Extractants, Monoamide, Malonamide, and Diglycolamide, Dissolved in Piperidinium Ionic Liquid. Sep. Sci. Technol. 2016, 51(3), 474–484.
   Web of Science ®Google Scholar
• (a) Kimberlin, A.; Saint-Louis, G.; Guillaumont, D.; Camès, B.; Guilbaud, P.; Berthon, L. Effect of Metal Complexation on Diglycolamide Radiolysis: A Comparison Between ex situ Gamma and in situ Alpha Irradiation. Phys. Chem. Chem. Phys. 2022, 24(16), 9213–9228. (b) Sengupta, A.; Mohapatra, P. K.; Patil, A. B.; Kadam, R. M.; Verboom, W. Radiation Stability of Diglycolamide Functionalized Calix[4]Arenes in Ionic Liquid: Solvent Extraction, EPR and GC–MS Studies. Sep. Purif. Technol. 2016, 162, 77-83.
   PubMed Web of Science ®Google Scholar
• Ansari, S. A.; Gujar, R. B.; Prabhu, D. R.; Pathak, P. N.; Mohapatra, P. K. Counter-Current Extraction of Neptunium from Simulated Pressurized Heavy Water Reactor High Level Waste Using N,N,N’,N’-Tetraoctyl Diglycolamide. Solvent Extr. Ion Exch. 2012, 30(5), 457–468.
   Web of Science ®Google Scholar
• Mahanty, B.; Verma, P. K.; Mohapatra, P. K.; Leoncini, A.; Huskens, J.; Verboom, W. Pertraction of Np (IV) and Pu (IV) Across a Flat Sheet Supported Liquid Membrane Containing Two N-Pivoted Tripodal Diglycolamides. Sep. Purif. Technol. 2020, 238, 116418.
   Web of Science ®Google Scholar
• (a) Ansari, S. A.; Mohapatra, P. K.; Manchanda, V. K. Recovery of Actinides and Lanthanides from High-Level Waste Using Hollow-Fiber Supported Liquid Membrane with TODGA as the Carrier. Ind. Eng. Chem. Res. 2009, 48(18), 8605–8612. (b) Gujar, R . B.; Ansari, S. A.; Prabhu, D. R.; Raut, D. R.; Pathak, P. N.; Sengupta, A.; Thulasidas, S.; Mohapatra, P. K.; Manchanda, V. Demonstration of T2EHDGA Based Process for Actinide Partitioning Part II: Counter-Current Extraction Studies. Solvent Extr. Ion Exch. 2010, 28(6), 764-777. (c) Ansari, S. A.; Mohapatra, P. K.; Leoncini, A.; Ali, S. M.; Huskens, J.; Verboom, W. V. Highly Efficient N-Pivot Tripodal Diglycolamide Ligands for Trivalent f-Cations: Synthesis, Extraction, Spectroscopy, and Density Functional Theory Studies. Inorg. Chem. 2019, 58(13), 8633-8644. (d) Bhattacharyya, A.; Egberink, R. J. M.; Mohapatra, P. K.; Verma, P. K.; Kanekar, A. S.; Yadav, A. K.; Jha, S. N.; Bhatacharyya, D.; Huskens, J.; Verboom, W. Remarkable Enhancement in Extraction of Trivalent f-Block Elements Using a Macrocyclic Ligand with Four Diglycolamide Arms: Synthesis, Extraction, and Spectroscopic and Density Functional Theory Studies. Inorg. Chem. 2019, 58(21), 14885-14899.
   Web of Science ®Google Scholar
• (a) Banerjee, P.; Ansari, S. A.; Mohapatra, P. K.; Egberink, R. J. M.; Valsala, T. P.; Sathe, D. B.; Bhatt, R. B.; Huskens, J.; Verboom, W. Highly Efficient Plutonium Scavenging by an Extraction Chromatography Resin Containing a Tetraaza-12-Crown-4 Ligand Tethered with Four Diglycolamide Pendent Arms. J. Chromatogr. A 2021, 1653, 462419. (b) Ansari, S. A.; Bhattacharyya, A.; Mohapatra, P. K.; Egberink, R. J. M.; Huskens, J.; Verboom, W. Evaluation of Two Aza-Crown Ether-Based Multiple Diglycolamide-Containing Ligands for Complexation with the Tetravalent Actinide Ions Np4+ and Pu4+: Extraction and DFT Studies. RSC Adv. 2019, 9(55), 31928-31935.
   PubMed Web of Science ®Google Scholar
• (a) Parhi, P. Supported Liquid Membrane Principle and Its Practices: A Short Review. J. Chem. 2013, 2013. (b) de Gyves, J.; Rodríguez de San Miguel, E. Metal Ion Separations by Supported Liquid Membranes. Ind. Eng. Chem. Res. 1999, 38(6), 2182-2202. (c) Mohapatra, P. K.; Manchanda, V. K. Liquid Membrane Based Separations of Actinides and Fission Products. Ind. J. Chem. 2003, 42A, 2925-2938.
   Web of Science ®Google Scholar
• (a) Ansari, S. A.; Chaudhury, S.; Mohapatra, P. K.; Aggarwal, S. K.; Manchanda, V. K. Recovery of Plutonium from Analytical Laboratory Waste Using Hollow Fiber Supported Liquid Membrane Technique. Sep. Sci. Technol. 2012, 48(2), 208–214. (b) Ansari, S. A.; Chaudhury, S.; Mohapatra, P. K.; Aggarwal, S. K.; Manchanda, V. K. Hollow Fibre Supported Liquid Membranes for Nuclear Fuel Cycle Applications: A Review. Cleaner Eng. Technol. 2021, 4, 100138.
   Web of Science ®Google Scholar
• Bhattacharyya, A.; Leoncini, A.; Egberink, R. J. M.; Mohapatra, P. K.; Verma, P. K.; Kanekar, A. S.; Yadav, A. K.; Jha, S. N.; Bhattacharyya, D.; Huskens, J.; Verboom, W. First Report on the Complexation of Actinides and Lanthanides Using 2, 2′, 2′′-(((1, 4, 7-Triazonane-1,4,7-Triyl) Tris(2-Oxoethane-2,1-Diyl)) Tris(Oxy)) Tris(N,N-Dioctylacetamide): Synthesis, Extraction, Luminescence, EXAFS, and DFT Studies. Inorg. Chem. 2018, 57(20), 12987–12998.
   PubMed Web of Science ®Google Scholar
• Giesche, H. Mercury Porosimetry: A General (Practical) Overview. Part. Part. Syst. Charact. 2006, 23(1), 9–19.
   Web of Science ®Google Scholar
• Mathur, J. N.; Ruikar, P. B.; Krishna, M. V. B.; Murali, M. S.; Nagar, M. S.; Iyer, R. H. Extraction of Np (IV), Np (VI), Pu (IV) and U (VI) with Amides, BEHSO and CMPO from Nitric Acid Medium. Radiochim. Acta 1996, 73(4), 199–206.
   Web of Science ®Google Scholar
• Kaya, A.; Kud, H.; Shirahashi, J.; Suzuki, S. The Purification of Plutonium by Anion Exchange in Nitric Acid. J. Nucl. Sci. Technol. 1967, 4(6), 289–292.
   Web of Science ®Google Scholar
• Sengupta, A.; Mohapatra, P. K.; Iqbal, M.; Huskens, J.; Verboom, W. A Diglycolamide-Functionalized Task Specific Ionic Liquid (TSIL) for Actinide Extraction: Solvent Extraction, Thermodynamics and Radiolytic Stability Studies. Sep. Purif. Technol. 2013, 118, 264–270.
   Web of Science ®Google Scholar
• Sharma, J. N.; Kumar, A.; Kumar, V.; Pahan, S.; Janardanan, C.; Tessi, V.; Wattal, P. Process Development for Separation of Cesium from Acidic Nuclear Waste Solution Using 1,3-Dioctyloxycalix[4]arene-Crown-6 + Isodecyl Alcohol/n-Dodecane Solvent. Sep. Purif. Technol. 2014, 135, 176–182.
   Web of Science ®Google Scholar
• Danesi, P. R. Separation of Metal Species by Supported Liquid Membranes. Sep. Sci. Technol. 1984, 19(11–12), 857–894.
   Web of Science ®Google Scholar
• Reichwein-Buitenhuis, E.; Visser, H.; de Jong, F.; Reinhoudt, D. Kinetic versus Diffusion Control in Carrier-Mediated Cotransport of Alkali Cations Through Supported Liquid Membranes. J. Am. Chem. Soc. 1995, 117(14), 3913–3921.
   Web of Science ®Google Scholar
• Mahanty, B.; Mohapatra, P. K.; Leoncini, A.; Huskens, J.; Verboom, W. Liquid–Liquid Extraction and Supported Liquid Membrane Transport of Neptunium (IV) Across a Flat-Sheet Supported Liquid Membrane Containing a TREN-DGA Derivative. Solvent Extr. Ion Exch. 2022, 40, 693–717.
   Web of Science ®Google Scholar
• Mohapatra, P. K.; Iqbal, M.; Raut, D. R.; Verboom, W.; Huskens, J.; Manchanda, V. K. Evaluation of a Novel Tripodal Diglycolamide for Actinide Extraction: Solvent Extraction and SLM Transport Studies. J. Membr. Sci. 2011, 375(1–2), 141–149.
   Web of Science ®Google Scholar
• Wilke, C.; Chang, P. Correlation of Diffusion Coefficients in Dilute Solutions. AIChE J. 1955, 1(2), 264–270.
   Web of Science ®Google Scholar
• Schotte, W. Prediction of the Molar Volume at the Normal Boiling Point. Chem. Eng. J. 1992, 48(3), 167–172.
   Web of Science ®Google Scholar