Publication Cover
Australian Journal of Earth Sciences
An International Geoscience Journal of the Geological Society of Australia
Volume 54, 2007 - Issue 1
565
Views
40
CrossRef citations to date
0
Altmetric
Original Articles

Antimony and arsenic dispersion in the Macleay River catchment, New South Wales: a study of the environmental geochemical consequences

, , &
Pages 83-103 | Received 10 Aug 2005, Accepted 09 Aug 2006, Published online: 15 Jan 2007

References

  • Allan , R. 1997 . Introduction: mining and metals in the environment . Journal of Geochemical Exploration , 58 : 95 – 100 .
  • Ashley , P. M. and Craw , D. 2004 . Structural controls on hydrothermal alteration and gold – antimony mineralization in the Hillgrove area, NSW, Australia . Mineralium Deposita , 39 : 223 – 239 .
  • Ashley , P. M. , Craw , D. , Graham , B. P. and Chappell , D. A. 2003 . Environmental mobility of antimony around mesothermal stibnite deposits, New South Wales, Australia and southern New Zealand . Journal of Geochemical Exploration , 77 : 1 – 14 .
  • Ashley , P. M. and Graham , B. P. 2001 . Heavy metal loadings of streams in the Macleay River catchment . Geological Survey of New South Wales Open File Report , GS2001/303
  • Ashley , P. M. and Lottermoser , B. G. 1999a . Arsenic contamination at the Mole River mine, northern New South Wales, Australia . Australian Journal of Earth Sciences , 46 : 861 – 874 .
  • Ashley , P. M. and Lottermoser , B. G. 1999b . “ Geochemical, mineralogical and biogeochemical characterisation of abandoned metalliferous mine sites, Southern New England Orogen ” . In New England Orogen , Edited by: Flood , P. G. 409 – 417 . Armidale : Earth Sciences, University of New England .
  • Ashley , P. M. , Lottermoser , B. G. , Collins , A. J. and Grant , C. D. 2004 . Environmental geochemistry of the derelict Webbs Consols mine, New South Wales, Australia . Environmental Geology , 46 : 591 – 604 .
  • Atkinson , G. 1999 . Soil Landscapes of the Kempsey – Korogoro Point 1:100 000 Sheet , Sydney : New South Wales Department of Land and Water Conservation .
  • Baroni , F. , Boscagli , A. , Protano , G. and Riccobono , F. 2000 . Antimony accumulation in Achillea ageratum, Plantago lanceoata, and Silene vulgaris growing in an old Sb-mining area . Environmental Pollution , 109 : 347 – 352 .
  • Bhumbla , D. K. and Keefer , R. F. 1994 . “ Arsenic mobilization and bioavailability in soils ” . In Arsenic in the Environment, Part 1: Cycling and Characterization , Edited by: Nriagu , J. O. 51 – 82 . New York : Wiley .
  • Blowes , D. W. , Ptacek , C. J. , Jambor , J. L. and Weisener , C. G. 2005 . “ The geochemistry of acid mine drainage ” . In Environmental Geochemistry (Treatise on Geochemistry Volume 9) , Edited by: Lollar , B. S. 149 – 204 . Oxford : Elsevier .
  • Boyle , G. O. 1990 . “ Hillgrove antimony – gold deposits ” . In Geology of the Mineral Deposits of Australia and New Guinea Edited by: Hughes , F. E. Vol. 14 , 1425 – 1427 . Australasian Institute of Mining and Metallurgy Monograph
  • Bryant , C. J. , Chappell , B. W. and Blevin , P. L. 2003 . Granites of the southern New England Orogen . Geoscience Australia Record , 2003/14 : 9 – 11 .
  • Bureau of Meteorology . 2004 . Climate averages . Online <http://www.bom.gov.au/climate/averages>
  • Cohen , D. , Rutherford , N. , Garnett , D. and Waldron , H. 1995 . A geochemical survey of the Upper North east Region, New South Wales, NRAC-funded report for the Geological Survey of New South Wales . Geological Survey of New South Wales Open File Report , GS1995/199
  • Cook , M. 2000 . High arsenic granites in the New England Batholith . Geological Society of Australia Abstracts , 59 : 94
  • Craw , D. , Falconer , D. and Youngson , J. H. 2003 . Environmental arsenopyrite stability and dissolution: theory, experiment, and field observations . Chemical Geology , 199 : 71 – 82 .
  • Dietrich , W. E. and Dunne , T. 1978 . Sediment budget for a small catchment in mountainous terrain . Zeitschrift für Geomorphologie , 29 : 191 – 206 .
  • Duck , L. J. 2000 . “ Geomorphological and geochemical interpretation of the southern Macleay River floodplain, central coast of New South Wales. BSc (Hons) thesis ” . Armidale : University of New England . (unpubl.)
  • Ferguson , R. , Lampert , G. and Brierley , G. 1999 . “ River styles in the Macleay catchment, North Coast, NSW ” . Sydney : Department of Physical Geography, Macquarie University . Report to New South Wales Department of Land and Water Conservation
  • Filella , M. , Belzile , N. and Chen , Y-W. 2002 . Antimony in the environment: a review focused on natural waters. I. Occurrence . Earth-Science Reviews , 57 : 125 – 176 .
  • Finkelman , R. B. , Belkin , H. E. and Zheng , B. 1999 . Health impacts of domestic coal use in China . Proceedings of the National Academy of Science USA , 96 : 3427 – 3431 .
  • Flood , P. G. and Aitchison , J. C. 1988 . “ Tectonostratigraphic terranes of the southern part of the New England Orogen ” . In New England Orogen—Tectonics and Metallogenesis , Edited by: Kleeman , J. D. 7 – 10 . Armidale : Department of Geology and Geophysics, University of New England .
  • Flood , P. G. and Aitchison , J. C. 1993 . “ Recent advances in understanding the geological development of the New England Province of the New England Orogen ” . In New England Orogen—Eastern Australia , Edited by: Flood , P. G. and Aitchison , J. C. 61 – 68 . Armidale : Department of Geology and Geophysics, University of New England .
  • Gebel , T. 1997 . Arsenic and antimony: comparative approach on mechanistic toxicology . Chemical – Biological Interactions , 107 : 131 – 144 .
  • Gilligan , L. B. and Brownlow , J. W. 1987 . Tamworth – Hastings 1:250 000 Metallogenic Map SH56 – 13, SH56 – 13. Mineral Deposit Data Sheets and Metallogenic Study , Sydney : Geological Survey of New South Wales .
  • Gilligan , L. B. , Brownlow , J. W. , Cameron , R. G. and Henley , H. F. 1992 . Dorrigo-Coffs Harbour 1:250 000 Metallogenic Map. SH/56 – 10, SH/56/-11. Metallogenic Study and Mineral Deposit Data Sheets , Sydney : Geological Survey of New South Wales .
  • Grimm , N. B. and Fisher , S. G. 1984 . Exchange between interstitial and surface water: implications for stream metabolism and nutrient cycling . Hydrobiologia , 111 : 219 – 228 .
  • Gurnani , N. , Sharma , A. and Tulukder , G. 1994 . Effects of antimony on cellular systems in animals: a review . Nucleus , 37 : 71 – 96 .
  • Hammel , W. , Debus , R. and Steubing , L. 2000 . Mobility of antimony in soil and its availability to plants . Chemosphere , 41 : 1791 – 1798 .
  • Hudson-Edwards , K. A. , Schell , C. and Macklin , M. G. 1999 . Mineralogy and geochemistry of alluvium contaminated by metal mining in the Rio Tinto area, southwest Spain . Applied Geochemistry , 14 : 55 – 70 .
  • Jones , B. G. , Chenhall , B. E. , Debretsion , F. and Hutton , A. C. 2003 . Geochemical comparisons between estuaries with non-industrialised and industrialised catchments: the Huon and Derwent River estuaries, Tasmania . Australian Journal of Earth Sciences , 50 : 653 – 667 .
  • Juracic , M. , Vitturi , L. M. , Rabitti , S. and Rampazzo , G. 1986 . Suspended matter properties and its role in pollutant transfer from river to the sea. Case study: Adige River – Adriatic Sea . Science of the Total Environment , 55 : 243 – 249 .
  • Korsch , R. J. 1984 . Sandstone compositions from the New England Orogen, eastern Australia: implications for tectonic setting . Journal of Sedimentary Petrology , 54 : 192 – 211 .
  • Krause , E. and Ettel , V. A. 1988 . Solubility and stability of scorodite FeAsO4.2H2O: new data and further discussion . American Mineralogist , 73 : 850 – 854 .
  • Krupka , K. M. and Serne , R. J. 2002 . Geochemical factors affecting the behavior of antimony, cobalt, europium, technetium, and uranium in vadose sediments . Online <www.hanford.gov/docs/gpp/library/programdocs/pnnl-14126.pdf>
  • Lottermoser , B. G. 2003 . Mine Wastes: Characterization, Treatment and Environmental Impacts , Berlin : Springer .
  • Lottermoser , B. G. , Ashley , P. M. and Lawie , D. C. 1999 . Environmental geochemistry of the Gulf Creek copper mine area, northeastern New South Wales, Australia . Environmental Geology , 39 : 61 – 74 .
  • Lottermoser , B. G. , Ashley , P. M. , Muller , M. and Whistler , B. D. 1997 . “ Metal contamination due to mining activities at the Halls Peak massive sulphide deposits, New South Wales ” . In Tectonics and Metallogenesis of the New England Orogen Edited by: Ashley , P. M. and Flood , P. G. Vol. 19 , 290 – 299 . Geological Society of Australia Special Publication
  • Miller , J. R. 1997 . The role of fluvial geomorphic processes in the dispersal of heavy metals from mine sites . Journal of Geochemical Exploration , 58 : 101 – 118 .
  • Mok , W. M. and Wai , C. M. 1994 . “ Mobilization of arsenic in contaminated river waters ” . In Arsenic in the Environment, Part 1: Cycling and Characterization , Edited by: Nriagu , J. O. 99 – 117 . New York : Wiley .
  • Moody , T. C. , Ashley , P. M. and Flood , P. G. 1993 . “ The early Permian Halls Peak Volcanics and associated massive sulphide deposits: implications for the southern New England Orogen ” . In New England Orogen—Eastern Australia , Edited by: Flood , P. G. and Aitchison , J. C. 331 – 336 . Armidale : Department of Geology and Geophysics, University of New England .
  • Mundell , A. H. D. 2000 . “ Sedimentary and geochemical processes of the lower Macleay floodplain and estuary. BSc (Hons) thesis ” . Armidale : University of New England . (unpubl.)
  • Naylor , S. D. , Chapman , G. A. , Atkinson , G. , Murphy , C. L. , Tulau , M. J. , Flewin , T. C. , Milford , H. B. and Morand , D. T. 1998 . Guidelines for the Use of Acid Sulphate Soil Risk Maps , (2nd edition) , Sydney : New South Wales Department of Land and Water Conservation .
  • NEPC (National Environment Protection Council) . 1999 . Assessment of Site Contamination. Schedule B (1) Guideline on the Investigation Levels for Soil and Groundwater Online <http://www.ephc.gov.au/pdf/cs/cs_01_inv_levels.pdf>
  • Nordstrom , D. K. and Alpers , C. N. 1999 . “ Geochemistry of acid mine waters ” . In The Environmental Geochemistry of Mineral Deposits. Part A: Processes, Techniques, and Health Issue Edited by: Plumlee , G. S. and Logsdon , M. J. Vol. 6A , 133 – 160 . Reviews in Economic Geology
  • NWQMS (National Water Quality Management Strategy) . 1996 . Australian Drinking Water Guidelines—Summary Online <http://www.health.gov.au:80/nhmrc/publications/pdf/eh20.pdf>
  • NWQMS (National Water Quality Management Strategy) . 2000 . Australian and New Zealand Guidelines for Fresh and Marine Waters. Section 3.5 Sediment Quality Guidelines Online <http://www.ea.gov.au/water/quality/nwqms/pubs/wqg-ch3.pdf>
  • Ollier , C. D. 1982 . Geomorphology and tectonics of the Dorrigo plateau . Journal of the Geological Society of Australia , 29 : 431 – 435 .
  • Plumlee , G. S. 1999 . “ The environmental geology of mineral deposits ” . In The Environmental Geochemistry of Mineral Deposits. Part A: Processes, Techniques, and Health Issues Edited by: Plumlee , G. S. and Logsdon , M. J. Vol. 6A , 71 – 116 . Reviews in Economic Geology
  • Plumlee , G. S. , Smith , K. S. , Montour , M. R. , Ficklin , W. H. and Mosier , E. L. 1999 . “ Geologic controls on the composition of natural waters and mine waters draining diverse mineral-deposit types ” . In The Environmental Geochemistry of Mineral Deposits. Part B: Case Studies and Research Topics Edited by: Filipek , L. H. and Plumlee , G. S. Vol. 6B , 373 – 432 . Reviews in Economic Geology
  • Quinby-Hunt , M. S. , Wilde , P. , Orth , C. J. and Berry , W. B. H. 1989 . Elemental geochemistry of black shales: statistical comparison of low-calcic shales with other shales . US Geological Survey Circular , 1037 : 8 – 15 .
  • Roberts , J. , Leitch , E. C. , Lennox , P. G. and Offler , R. 1995 . Devonian – Carboniferous stratigraphy of the southern Hastings Block, New England Orogen, eastern Australia . Australian Journal of Earth Sciences , 42 : 609 – 634 .
  • Salomons , W. 1995 . Environmental impact of metals derived from miming activities: processes, predictions, prevention . Journal of Geochemical Exploration , 52 : 5 – 23 .
  • Salomons , W. and Förstner , U. 1984 . Metals in the Hydrocycle , Berlin : Springer .
  • Schultz , R. B. 1991 . “ Metalliferous black shales: accumulation of carbon and metals in cratonic basins ” . In Sedimentary and Diagenetic Mineral Deposits: a Basin Analysis Approach to Exploration Edited by: Force , E. R. , Eidel , J. J. and Maynard , J. B. Vol. 5 , 171 – 176 . Reviews in Economic Geology
  • Shotyk , W. , Krachler , M. and Chen , B. 2005 . “ Anthropogenic impacts on the biogeochemistry and cycling of antimony ” . In Biogeochemistry, Availability, and Transport of Metals in the Environment (Metal Ions in Biological Systems Volume 44) , Edited by: Sigel , A. , Sigel , H. and Sigel , R. K. O. 177 – 203 . New York : M. Dekker .
  • Siegel , F. R. 2002 . Environmental Geochemistry of Potentially Toxic Metals , Berlin : Springer .
  • Smith , K. S. and Huyck , H. L. O. 1999 . “ An overview of the abundance, relative mobility, bioavailability, and human toxicity of metals ” . In The Environmental Geochemistry of Mineral Deposits. Part A: Processes, Techniques, and Health Issues Edited by: Plumlee , G. S. and Logsdon , M. J. Vol. 6A , 29 – 70 . Reviews in Economic Geology
  • Smolders , K. 2002 . “ The effects of heavy metal contamination on benthic macroinvertebrates inhabiting streams in the upper Macleay catchment. BEnvSc (Hons) thesis ” . Armidale : University of New England . (unpubl.)
  • Swaine , D. J. 1990 . Trace Elements in Coal , Toronto : Butterworths .
  • Taylor , G. F. 2001 . “ Acid drainage at minesites ” . In Gondwana to Greenhouse: Australian Environmental Geoscience Edited by: Gostin , V. A. Vol. 21 , 77 – 94 . Geological Society of Australia Special Publication
  • Tessier , A. , Campbell , P. G. C. and Bisson , M. 1979 . Sequential extraction procedure for the speciation of particulate trace metals . Analytical Chemistry , 51 : 844 – 851 .
  • Tighe , M. K. 2005 . “ The fate and behaviour of antimony in a coastal floodplain system, with comparisons to arsenic. PhD thesis ” . Armidale : University of New England . (unpubl.)
  • Tighe , M. , Ashley , P. M. , Lockwood , P. and Wilson , S. 2005 . Soil, water and pasture enrichment of antimony and arsenic within a coastal floodplain system . Science of the Total Environment , 347 : 175 – 186 .
  • Van Loon , J. C. and Barefoot , R. R. 1989 . Analytical Methods for Geochemical Exploration , San Diego : Academic Press .
  • Vink , B. W. 1996 . Stability relations of antimony and arsenic compounds in the light of revised and extended Eh – pH diagrams . Chemical Geology , 130 : 21 – 30 .
  • Walker , P. H. 1970 . Depositional and soil history along the lower Macleay River, New South Wales . Journal of the Geological Society of Australia , 16 : 683 – 696 .
  • Weir , W. E. 1998 . “ Management of tailings at New England Antimony Mines NL. BEng thesis ” . Armidale : University of New England . (unpubl.)
  • Wilson , N. J. , Craw , D. and Hunter , K. 2004 . Antimony distribution and environmental mobility at an historic antimony smelter site, New Zealand . Environmental Pollution , 129 : 257 – 266 .
  • Wolfenden , B. J. 2002 . “ Geochemical behaviour of metalliferous contaminants in the upper Macleay gorges, northern NSW. BSc (Hons) thesis ” . Armidale : University of New England . (unpubl.)
  • Zhu , Y. and Merkel , B. J. 2001 . The dissolution and solubility of scorodite, FeAsO4.2H2O: evaluation and simulation with PHREEQC2 . Online <http://www.geo.tu-freiberg.de/∼merkel/Zhu-Merkel-2001.pdf>

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.