142
Views
11
CrossRef citations to date
0
Altmetric
Original Articles

The Recovery of Iron from Zinc Sulphate-Sulphuric Acid Processing Solutions by Solvent Extraction or Ion Exchange

, , &
Pages 105-145 | Received 11 Feb 1997, Accepted 14 May 1997, Published online: 26 Mar 2008

References

  • Kajiwara T. and Iida T. and Hino T. , survey of operating situation of zinc smelters and refineries in the world. In Zinc and Lead '95 (edited by Azakami T. , Masuko N. , Dutrizac J. E. and Ozberk E. ), The Mining and Materials Processing Institute of Japan , Tokyo , 1995 , p. 27 – 53 .
  • Arregui V. and Gordon A.R. and Steintveit G. , The jarosite process - past, present and future . In Lead-Zinc-Tin '80 (edited by Cigan J. M. , Mackey T. S. and O'Keefe T. J. ), The Metallurgical Society of AIME , Warrendale , 1979 , p. 97 – 123 .
  • Dutrizac J.E. , The physical chemistry of iron precipitation in the zinc industry . In Lead-Zinc-Tin '80 (edited by Cigan J. M. , Mackey T. S. and O'Keefe T. J. ), 532 – 564 . The Metallurgical Society of AIME , Warrendale , 1979 .
  • Piret N.L. and Melin A.E. , Impact of environmental issues on iron removal process evolution in the zinc industry , In Hydrometallurgy Fundamentals, Technology and Innovation , 1993 , (edited by J. B. Hiskey and G. W. Warren ), p. 499 – 520 . Society for Mining, Metallurgy and Exploration , Littleton , 1993
  • Pammenter R.V. and Kershaw M.G. and Horsham T.R. , The low-contaminant jarosite process - further developments and the implementation of the process . In Iron Control in Hydrometallurgy (edited by Dutrizac J. E. and Monhemius A. J. ), pp. 603 – 617 . Ellis Horwood , Chichester , England , 1986 .
  • , Ritcey G.M. , Iron - an overview of its control in solvent extraction of metals. In Iron Control in Hydrometallurgy . (edited by Dutrizac J. E. and Monhemius A. J. ), Ellis Horwood , Chichester , England , 1986
  • Piret N.L. and Castle J.F. , Review of secondary zinc treatment process options. In Recycling of Metaliferous Materials , p. 181 – 219 . Inst. Min. Metall. , London , England . 1990 .
  • Flett D.S. and Monhemius A.J. , Solvent extraction for iron control in hydro-metallurgy. In Iron Control and Disposal , (edited by Dutriazac J. E. and Harris G. B. ), p. 331 – 356 . Inst. MIn. Metall. Petrol. , Montreal , Canada , 1996
  • von Ropenack A. , Hematite - the solution to a disposal problem - an example from the zinc industry. In Iron control in Hydrometallurgy (edited by Dutrizac J. E. and Monhemius A. J. ) Ellis Horwood , Chichester , England , 1986 .
  • Pammenter R.V. and Gilmour R. and Salmon P.T. , Production of zinc in the modernized Pasminco Metals EZ plant, Hobart, Tasmania . In World Zinc '93 (edited by Matthew I. G. ), p. 287 – 293 The Australian Institute of Mining and Metallurgy , Parkvillie , Australia , 1993
  • Tchobanoglous G. and Burton F.L. , Wastewater Engineering Treatment, Disposal and Reuse . McGraw-Hill , New York , 1991 , pp. 301 – 314
  • Kuhn A.T. , 1971 , A review of the role of electrolysis in the treatment of iron pickle liquors , Iron and Steel , 44 , pp. 173 – 176
  • Peek M.L. and Goedhart O.F. and Van Weert G. , Process evaluation of steel pickle liquors pyrohydrolysis in a commercial Keramchemie fluid bed reactor, In Iron Control and Disposal , (edited by Dutrizac J. E. and Harris G. B. ), Can. Inst. Min. Metall. Petrol. , Montreal , Canada , 1996 , pp. 483 – 503
  • Riveros P.A. and Dutrizac J.E. , The precipitation of hematite from ferric chloride media. Hydrometallurgy , in press. 1997
  • Shang Y. and Van Weert G. , 1993 , Iron control in nitrate hydrometallurgy by autoclave hydrolysis of iron(III) nitrate , Hydrometallurgy , 33 , pp. 273 – 290
  • Dutrizac J.E. , The hydrothermal conversion of jarosite-type compounds to hematite , In Productivity and Technology in the Metallurgical Industries , (edited by Koch M. and Taylor J. C. ), pp. 587 – 612 . The Minerals, Metals and Materials Society , Warrendale , Pa. , 1989 .
  • Collier D. and Heng R. and Lehman R. and Pietsch H.B. and Rathje G. , The Versatic acid process - a solution to the iron problem in the zinc industry? In Iron Control in Hydrometallurgy (edited by Dutrizac J. E. and Monhemius A. J. ), Ellis Horwood , Chichester , England 1986
  • Monhemius A.J. , Precipitation of metal values from cationic extractants. In MINTEK'50 (edited by Haughton L. F. ) pp. 599 – 609 . Council for Mineral Technology , Randburg , South Africa 1985 .
  • Monhemius A.J. and Teixeira L.A.C. and Thorsen G. , The precipitation of hematite from iron-loaded Versatic acid solutions by hydrolytic stripping. In Hydro-metallurgical Process Fundamentals . (edited by Bautista R. G. ), pp. 647 – 661 Plenum Press , New York , 1984 .
  • Monhemius A.J. and Yu X. and Dougill S.B. , Continuous hydrolytic stripping of iron from Versatic acid using formic acid solutions. In Solvent Extraction in the Process Industries (edited by D. H. Slater Logsdail. and M. J. ), pp. 202 – 209 , Else-vier Applied Science , London , England , 1993
  • Doyle F.M. and Monhemius A.J. , 1994 , Kinetics and mechanisms of precipitation of nickel ferrite by hydrolytic stripping , Hydrometallurgy , 35 , pp. 251 – 265
  • Nogueira E.D. and Regife J.M. and Biythe P.M. , 1980 , Zincex-the development of a secondary zinc process , Chem. Ind , 2 , pp. 63 – 67
  • , Nogueira E.D. and Regife J.M. and Viegas M.P. , Design features and operating experience of the Quimigai Zincex plant. In Chloride Hydrometallurgy (edited by Parker P. D. ) The Metallurgical Society of AIME , Warrendale , 1982, pp. 59–79
  • Heng R. and Lehmann R. and Garcia D.J. , Zinc recovery from hydrometallurgical zinc processing residues by solvent extraction. ISEC 86, International Solvent Extraction Conference , Frankfurt am Main , Germany , DECHEMA , 1986 ,
  • Sanuki S. and Sugiyama A. and Kadomachi K. and Miyata K. and Arai K. , 1995 , Recovery of metal values from Sm-Co magnet scrap , Nippon Kinzoku Gakkaishi , 59 , pp. 169 – 176
  • Watanabe T. and Hoshino M. and Uchino K. and Nakazato Y. and Nishimura S. , In Iron Control in Hydrometallurgy (edited by Dutrizac J. E. and Monhemius A. J. ), Ellis Horwood , Chichester , England , 1986 .
  • Sato T. and Nakamura T. and Ikeno M. , 1985 , The extraction of iron(III) from aqueous acid solutions by di(2-ethylhexyl) phosphoric acid , Hydrometallurgy , 15 , pp. 209 – 217
  • Acharya S. and Nayak A. , 1988 , Separation of D2EHPA and M2EHPA , Hydrometallurgy , 19 , pp. 309 – 320
  • Hirato T. and Wu Z.C. and Yamada Y. and Majima H. , 1992 , Improvements of the stripping characteristics of Fe(III) utilising a mixture of di-2-ethyl hexyl phosphoric acid and tributyl phosphate , Hydrometallurgy , 28 , pp. 81 – 93
  • Chen J. and Yu S. and Liu H. and Meng X. and Wu Z. , 1992 , New mixed solvent systems for the extraction and separation of ferric iron in sulphate solutions , Hydro-metallurgy , 30 , pp. 401 – 416
  • Majima H. and Izaki T. and Sanuki S. , 1985 , Reductive stripping of Fe( I Unloaded D2EHPA with aqueous solutions containing sulfur dioxide , Metall. Trans , 16B , pp. 187 – 194
  • O'Keefe T. J. , 1991 , Solvent extraction of metals and selective redox stripping of cations for separation , Patent WO 91/16465 ,
  • Belew B. and Harlamovs J.R. and O'Keefe;Watson T.J. and Hiskey J.L. , (edited by J. B. and Warren G. W. ), Littleton, Co , 1993 , pp. 817 – 830
  • Moats M.S. and Chang C.M. and O'Keefe T.J. , Warrendalez The Minerals, Metals and Materials Society , 1995 , (edited by P. B. Queneau and R. D. Peterson) , pp. 545 – 562
  • Chang C.M. and Gu H. and O'Keefe T.J. , 1996 , Galvanic stripping of iron from solvent extraction solutions from zinc residue leaching. In Iron Control and Disposal , Can. Inst. Min. Metall. Petrol , pp. 417 – 428
  • Cronberg A.D. and Hartlage J.A. and Cotton J.W. , 1978 , Ion exchange process for the purification of base metal electrolyte solutions , U.S. Patent 4,067,802 ,
  • Demopoulos G.P. and Gefvert D.L. , 1984 , Iron (III) removal from base-metal electrolyte solutions by solvent extraction , Hydrometallurgy , Demopoulos, G. P., Mihaylov I. O. and Pouskouleli, G. (1993). Synergistic extraction of iron (III) from sulphuric acid solutions with mixed Kelex 100-alkyl phosphorus acid extractants. Solvent Extr. Ion Exch. 11, 67-89 , 12 , pp. 299 – 315
  • Leiby R. and Bricke M. and Spitz P. , Warrendale The Minerals. Metals and Materials Society , 1995 , pp. 311 – 319
  • , Demopoulos G.P. and Pouskouleli G. , 1989, Solvent extraction of Fc(Ill) from acid sulphate solutions by mono(2-ethyl hexyl) phosphoric acid, Can. Metall. Quart , 28, pp. 13–18
  • Demopoulos G.P. and Molnar R. and Rosato L.I. , 1996 , Bench scale and mini-pilot plant investigations on the selective removal of iron from zinc process solutions by solvent extraction. In Iron Control and Disposal , Can. Inst. Min. Metall Petrol , (edited by J. E. Dutrizac, and G. B. Harris) , pp. 395 – 416
  • Cupertino D.C. and Tasker P.A. and King M.G. and Jackson J.S. , London Chapman and Hall , 1994 , In Hydrometaliurgy'94 , pp. 591 – 600
  • Delmas F. and Nogueira C.A. and Ehle M. and Oppenlander K. and Koch R.O. and Lemmert F. and Plazanet C. and Weigel V. and Ujma K.H. and Ketels E. , Novel highly efficient selective extractants for iron in zinc electrometallurgy. In: Iron Control and Disposal , Can. Inst. Min. Metall. Petrol , 1996 , pp. 381 – 393
  • Monzyk B. , N-ethyl hydroxamic acid chelants , U.S. Patent 5,328,626 , 1992
  • Monzyk B. , Metal extractant solution comprising N-ethyl hydroxamic acid chelants and kerosene solvent , U.S. Patent 5,428,842 , 1996
  • Lakshmanan V.I. and Rathie N. and Monzyk B. , Evaluation of N-alkyl hydroxamix acids for selective iron separation from zinc process liquors for high purity iron products. In Iron Control and Disposal , Can Inst. Min. Metall. Petrol , 1996 , pp. 357 – 367
  • Tait B.K. and Mdlalose K.E. and Taljaard I. , The extraction of some metal ions by LIX 1104 dissolved in toluene , Hydrometalurgy , 1995 , 38 , pp. 1 – 6
  • Filippou D. and Papangelakis V.G. and Demopoulos G.P. , A new method for the estimation of acid activities through speciation, and its application to process solutions of ZnSO4-FeSO4–Fe2(SO3–H2SO4. In Hydrometaliurgy Fundamentals, Technology and Innovation , Soc. Mining , 1993 , pp. 233 – 240
  • Alguacil F.J. and Arner S. , Extraction equilibrium between primary amine Primene 81R and iron(III) sulphate , Polyhedron , 1986 , 5 , pp. 1747 – 1753
  • Alguacil F.J. and Amer S. , The extraction of iron(III) sulphate from aqueous sulphate solutions by Primene 81R sulphate , Hydrometaliurgy , 1986 , 15 , pp. 337 – 350
  • Yu S. and Wu Z. and Chen J. , 1986 , Iron removal from sulfuric acid solutions by solvent extraction with mixtures of extractants. In Iron Control in Hydrometallurgy ,(edited by Dutrizac J. E. and Monhemius A. J. ) Ellis Horwood Chi-chester , England , , pp. 334 – 352
  • Meng X. and Yu S. and Chen J. , Extraction of iron(III) from sulfate solutions with primary amine and tributyl phosphate. 1989 , In Second International Conference on Separations Science and Technology (edited by Baird M. H. I. and Vijayan S. ), Canadian Society for Chemical Engineering , Ottawa , Canada
  • Wu Z. and Yu S. , Removal of Fe(III) from zinc sulphate solutions by extraction with tertiary amines as solvent. Nonferrous Metall , Chin. Soc. Metall , 1988 , 40 , pp. 66 – 72
  • Juan D. and Perales A. , Ecological treatment of waste products from zinc hydro-metallurgy. 1994 , In Hydrometallurgy '94 Chapman and Hall , London , England , pp. 1123 – 1151
  • Poppe W. and Miiller H. and Krajewski W. and Schugerl K. , Removal of iron(III) from acidic zinc salt solutions by solvent extraction , German Patent DE 3801430 Al , 1989
  • Miiller H. and Poppe W. and Schugerl K. , Solvent extraction of iron from an acid zinc sulphate solution , Erzmetall , 1986 , 39 , pp. 632 – 636
  • Kerney U. , Solvent extraction of iron from sulphuric acid leach liquors of roasted ores , Erzmetall , 1990 , 43 , pp. 195 – 199
  • , Yu S. and Chen J. , Synergistic extraction of ferric iron in sulphate solutions by tertiary amine and 2-ethylhexyl 2-ethylhexylphosphonic acid (HEHEHP) or dialkylphonic acid, Hydrometallurgy , 1989, 22, pp. 183–192
  • Gao Z. and Wang D. and Sun S. and Yang Y. and Shen J. , Extraction kinetics of iron(III) by 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester. In Solvent Extraction in the Process Industries , (edited by Logsdail D. H. and Slater M. J. ), Elsevier Applied Science , London , England , 1993 , 3 , pp. 1436 – 1443
  • Dreisinger D. and West-Sells P. and King J.A. and Patel C. , The solvent extraction-elec-trowin-ning of zinc from Eskay Creek pressure oxidation solutions using Cyanex 302 extractant , Australasian Inst. Min. Metall , 1993 , pp. 357 – 363
  • Rickleton W.A. and Boyle R.J. , The selective recovery of zinc with new thiophosphinic acids , Solvent Extr. Ion Exch , 1990 , 8 , pp. 783 – 797
  • Yadav S.K. and Singh O.V. and Tandon S.N. , Extraction and separation of some 3d transition elements using Cyanex 925: application to zinc ores , Hydro-metallurgy , 1994 , 36 , pp. 53 – 59
  • Dalton R.F. and Tasker P.A. and Cupertino D.C. , Novel zinc processing technology based on new selective solvent extraction reagents. In Zinc and Lead '95 Mining and Materials Processing Institute of Japan , Tokyo , Japan , 1995 , pp. 330 – 339
  • Dalton R.F. and Quan P.M. , Novel solvent extraction reagents for recovery of zinc from sulphate leach solutions. In Hydrometallurgy '94 , pp. 601 – 611 . Chapman and Hall , London , England , 1994
  • Cupertino D.C. and Dalton R.F. and Seward G.W. and Townson B. and Harris G.B. and Tasker P.A. , Iron control in zinc circuits: the role of highly selective zinc extrac-tants. In Iron Control and Disposal , Can. Inst. Min. Metail. Petrol , 1996 , pp. 369 – 379
  • Simek M. , Behavior of calcium, scandium, and iron(III) cations in ion exchange in concentrated mineral acids , Collect. Czech. Chem. Commun , 1974 , 39 , pp. 1693 – 1699
  • Weng B. and Li D. , Stepwise regeneration of cation exchanger column by oxalic and sulfuric acids , Electroplating and Pollution Control , 1987 , 7 , pp. 38 – 39
  • Patel G.C. and Pancholi H.B. and Patel M.M. , Synthesis, characterization and ion exchange properties of 2,4-dihydroxybenzoic acid-urea-formaldehyde copolymers , High Perform. Polym , 1991 , 3 , pp. 99 – 106
  • Patel C.C. and Patel M.M. , Ion-exchange properties of 2,4-dihydroxy-propiophenone-urea-formaldehyde copolvmers , J. Indian Chem. Soc , 1991 , 68 , pp. 149 – 151
  • Chiarizia R. and Horwitz E.P. and Gatrone R.C. and Alexandratos S.D. and Trochimczuk A.Q. and Crick D.W. , Uptake of metal ions by a new chelating ion-exchange resin. Part 2. Acid depedencies of transition and post-transition metal ions , Solvent Extr. Ion Exch , 1993 , II , pp. 967 – 985
  • Horowitz E.P. and Chiarizia R. and Alexandratos S.D. , Uptake of metal ions by a new chelating ion-exchange resin. Part 5: The effects of solution matrix on actinides , Solvent Extr. Ion Exch , 1994 , 12 , pp. 831 – 845
  • Gula M.J. and Dreisinger D.B. and Montijo J.C. and Young S.K. , The ion exchange control of iron in copper electrolyte streams using Eichrom's Diphonix resin. In Iron Control and Disposal , Can. Inst. Min. Metail. Petrol , 1996 , pp. 315 – 327
  • Capaul M. and Sauter H. , Purification of sulfuric acid , German patent DE 2029117 , 1970
  • McAndrew R.T. and Wang S.S. and Brown W.R. , Precipitation of iron compounds from sulphuric acid leach solutions , CIM Bull , 1975 , 68 , pp. 101 – 110

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.