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Experimental Heat Transfer
A Journal of Thermal Energy Generation, Transport, Storage, and Conversion
Volume 22, 2009 - Issue 1
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Original Articles

Magnetic Resonance Imaging of a Polymer Electrolyte Membrane under Water Permeation

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Pages 1-11 | Received 15 Feb 2008, Accepted 14 Aug 2008, Published online: 08 Jan 2009

REFERENCES

  • Springer , T. E. , Zawodzinski , T. A. and Gottesfeld , S. 1991 . Polymer Electrolyte Fuel-Cell Model . J. Electrochem. Soc. , vol. 138 : 2334 – 2342 .
  • Fuller , T. F. and Newman , J. 1992 . Experimental-Determination of the Transport Number of Water in Nafion-117 Membrane . J. Electrochem. Soc. , vol. 139 : 1332 – 1337 .
  • Nguyen , T. V. and White , R. E. 1993 . A Water and Heat Management Model for Proton-Exchange-Membrane Fuel-Cells . J. Electrochem. Soc. , vol. 140 : 2178 – 2186 .
  • Weber , A. Z. and Newman , J. 2004 . Modeling Transport in Polymer-Electrolyte Fuel Cells . Chem. Rev. , vol. 104 : 4679 – 4726 .
  • Wang , C. Y. 2004 . Fundamental Models for Fuel Cell Engineering . Chem. Rev. , vol. 104 : 4727 – 4766 .
  • Majsztrik , P. W. , Satterfield , M. B. , Bocarsly , A. B. and Benziger , J. B. 2007 . Water Sorption, Desorption and Transport in Nafion Membranes . J. Memb. Sci. , vol. 301 : 93 – 106 .
  • Ge , S. H. , Li , X. G. , Yi , B. L. and Hsing , I. M. 2005 . Absorption, Desorption, and Transport of Water in Polymer Electrolyte Membranes for Fuel Cells . J. Electrochem. Soc. , vol. 152 : A1149 – A1157 .
  • Berg , P. , Promislow , K. , St Pierre , J. , Stumper , J. and Wetton , B. 2004 . Water Management in PEM Fuel Cells . J. Electrochem. Soc. , vol. 151 : A341 – A353 .
  • Dong , Q. , Mench , M. M. , Cleghorn , S. and Beuscher , U. 2005 . Distributed Performance of Polymer Electrolyte Fuel Cells under Low-Humidity Conditions . J. Electrochem. Soc. , vol. 152 : A2114 – A2122 .
  • Legras , M. , Hirata , Y. , Nguyen , Q. T. , Langevin , D. and Metayer , M. 2002 . Sorption and Diffusion Behaviors of Water in Nafion 117 Membranes with Different Counter Ions . Desalination , vol. 147 : 351 – 357 .
  • Motupally , S. , Becker , A. J. and Weidner , J. W. 2000 . Diffusion of Water in Nafion 115 Membranes . J. Electrochem. Soc. , vol. 147 : 3171 – 3177 .
  • Zawodzinski , T. A. , Neeman , M. , Sillerud , L. O. and Gottesfeld , S. 1991 . Determination of Water Diffusion—Coefficients in Perfluorosulfonate Ionomeric Membranes . J. Phys. Chem. , vol. 95 : 6040 – 6044 .
  • Rivin , D. , Kendrick , C. E. , Gibson , P. W. and Schneider , A. 2001 . Solubility and Transport Behavior of Water and Alcohols in Nafion . Polymer , vol. 42 : 623 – 635 .
  • Krtil , P. , Trojanek , A. and Samec , Z. 2001 . Kinetics of Water Sorption in Nafion thin Films—Quartz Crystal Microbalance Study . J. Phys. Chem. B , vol. 105 : 7979 – 7983 .
  • Gong , X. , Bandis , A. , Tao , A. , Meresi , G. , Wang , Y. , Inglefield , P. T. , Jones , A. A. and Wen , W. Y. 2001 . Self-Diffusion of Water, Ethanol and Decafluoropentane in Perfluorosulfonate Ionomer by Pulse Field Gradient NMR . Polymer , vol. 42 : 6485 – 6492 .
  • Damay , F. and Klein , L. C. 2003 . Transport Properties of Nafion (Tm) Composite Membranes for Proton-Exchange Membranes Fuel Cells . Solid State Ionics , vol. 162 : 261 – 267 .
  • Kotaka , T. , Tsushima , S. and Hirai , S. 2007 . Visualization of Membrane Hydration Path in an Operating PEMFC by Nuclei-Labeling MRI . ECS Trans. , vol. 11 : 445 – 450 .
  • Tsushima , S. , Teranishi , K. and Hirai , S. 2004 . Magnetic Resonance Imaging of the Water Distribution within a Polymer Electrolyte Membrane in Fuel Cells . Electrochem. Solid State Lett. , vol. 7 : A269 – A272 .
  • Teranishi , K. , Tsushima , S. and Hirai , S. 2005 . Study of the Effect of Membrane Thickness on the Performance of Polymer Electrolyte Fuel Cells by Water Distribution in a Membrane . Electrochem. Solid State Lett. , vol. 8 : A281 – A284 .
  • Tsushima , S. , Teranishi , K. , Nishida , K. and Hirai , S. 2005 . Water Content Distribution in a Polymer Electrolyte Membrane for Advanced Fuel Cell System with Liquid Water Supply . Magn. Reson. Imag. , vol. 23 : 255 – 258 .
  • Teranishi , K. , Tsushima , S. and Hirai , S. 2006 . Analysis of Water Transport in PEFCs by Magnetic Resonance Imaging Measurement . J. Electrochem. Soc. , vol. 153 : A664 – A668 .
  • Tsushima , S. , Nanjo , T. , Nishida , K. and Hirai , S. 2005 . Investigation of the Lateral Water Distribution in a Proton Exchange Membrane in Fuel Cell Operation by 3D-MRI . ECS Trans. , vol. 1 : 199 – 205 .
  • Tsushima , S. , Hirai , S. , Kitamura , K. , Yamashita , M. and Takase , S. 2007 . MRI Application for Clarifying Fuel Cell Performance with Variation of Polymer Electrolyte Membranes: Comparison of Water Content of a Hydrocarbon Membrane and a Perfluorinated Membrane . Appl. Magn. Reson. , vol. 32 : 233 – 241 .
  • Howe , D. T. , Seymour , J. D. , Busse , S. L. C. C. , Peterson , E. S. , Were , E. H. and Taylor , B. F. . MRM Measurement of Material Heterogeneity in Polymer Electrolyte Membranes . Eighth International Conference on Magnetic Resonance Microscopy . pp. O-34
  • Feindel , K. W. , Bergens , S. H. and Wasylishen , R. E. 2007 . The Influence of Membrane Electrode Assembly Water Content on the Performance of a Polymer Electrolyte Membrane Fuel Cell as Investigated by 1H NMR Microscopy . Phys. Chem. Chem. Phys. , vol. 9 : 1850 – 1857 .
  • Feindel , K. W. , Bergens , S. H. and Wasylishen , R. E. 2006 . The Use of 1H NMR Microscopy to Study Proton-Exchange Membrane Fuel Cells . ChemPhysChem. , vol. 7 : 67 – 75 .
  • Minard , K. R. , Viswanathan , V. V. , Majors , P. D. , Wang , L. Q. and Rieke , P. C. 2006 . Magnetic Resonance Imaging (MRI) of PEM Dehydration and Gas Manifold Flooding During Continuous Fuel Cell Operation . J. Power Sources , vol. 161 : 856 – 863 .
  • Zhang , Z. , Martin , J. , Wang , H. , Promislow , K. and Balcom , B. J. . Magnetic Resonance Imaging of Water Content across the Nafion Membrane in OperationalPEM Fuel Cells . Ninth International Conference on Magnetic Resonance Microscopy . pp. 43
  • Callaghan , P. T. 1991 . Principles of Nuclear Magnetic Resonance Microscopy , Oxford, , UK : Clarendon Press .
  • Hinatsu , J. T. , Mizuhata , M. and Takenaka , H. 1994 . Water-Uptake of Perfluorosulfonic Acid Membranes from Liquid Water and Water-Vapor . J. Electrochem. Soc. , vol. 141 : 1493 – 1498 .

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