Solvent-responsiveness of PS–PEO binary mixed polymer brushes: a coarse-grained molecular dynamics study

References

• Chen T, Ferris R, Zhang J, et al. Stimulus-responsive polymer brushes on surfaces: transduction mechanisms and applications. Prog Polym Sci. 2010;35:94–112.10.1016/j.progpolymsci.2009.11.004
   Web of Science ®Google Scholar
• de Las Heras Alarcon C, Pennadam S, Alexander C. Stimuli responsive polymers for biomedical applications. Chem Soc Rev. 2005;34:276–285.
   PubMed Web of Science ®Google Scholar
• Minko S. Responsive polymer brushes. J Macromol Sci Part C: Polym Rev. 2006;46:397–420.10.1080/15583720600945402
   Web of Science ®Google Scholar
• Xin BW, Hao JC. Reversibly switchable wettability. Chem Soc Rev. 2010;39:769–782.10.1039/B913622C
   PubMed Web of Science ®Google Scholar
• Lee HI, Pietrasik J, Sheiko SS, et al. Stimuli-responsive molecular brushes. Prog Polym Sci. 2010;35:24–44.10.1016/j.progpolymsci.2009.11.002
   Web of Science ®Google Scholar
• Minko S, Luzinov I, Luchnikov V, et al. Bidisperse mixed brushes: synthesis and study of segregation in selective solvent. Macromolecules. 2003;36:7268–7279.10.1021/ma034160h
   Web of Science ®Google Scholar
• Cristobal G, Berret JF, Chevallier C, et al. Phase behavior of polyelectrolyte block copolymers in mixed solvents. Macromolecules. 2008;41:1872–1880.10.1021/ma702249w
   Web of Science ®Google Scholar
• Liu L, Zhang J, Wu CL, et al. Surface-active gold nanoparticles with mixed polymer brushes as surfactants in the preparation of polystyrene colloid particles. Macromol Rapid Commun. 2008;29:45–51.10.1002/(ISSN)1521-3927
   Web of Science ®Google Scholar
• Alexander S. Adsorption of chain molecules with a polar head a scaling description. J Phys (Paris). 1977;38:983–987.10.1051/jphys:01977003808098300
   Web of Science ®Google Scholar
• De Gennes PG. Polymer solutions near an interface. Adsorption and depletion layers. Macromolecules. 1981;14:1637–1644.
   Web of Science ®Google Scholar
• Schaefer DW. A unified model for the structure of polymers in semidilute solution. Polymer. 1984;25:387–394.10.1016/0032-3861(84)90292-1
   Web of Science ®Google Scholar
• Milner ST, Witten TA. Theory of the grafted polymer brush. Macromolecules. 1988;21:2610–2619.10.1021/ma00186a051
   Web of Science ®Google Scholar
• Shim DFK, Cates ME. Finite extensibility and density saturation effects in the polymer brush. J Phys. 1989;50:3535–3551.10.1051/jphys:0198900500240353500
   Web of Science ®Google Scholar
• Grest GS, Murat M. Structure of grafted polymeric brushes in solvents of varying quality: a molecular dynamics study. Macromolecules. 1993;26:3108–3117.10.1021/ma00064a019
   Web of Science ®Google Scholar
• Soga KG, Zuckermann MJ, Guo H. Binary polymer brush in a solvent. Macromolecules. 1996;29:1998–2005.10.1021/ma951102q
   Web of Science ®Google Scholar
• Lemieux M, Usov D, Minko S, et al. Reorganization of binary polymer brushes: reversible switching of surface microstructures and nanomechanical properties. Macromolecules. 2003;36:7244–7255.10.1021/ma034634c
   Web of Science ®Google Scholar
• Xu Y, Chen X, Han X, et al. Lock/unlock mechanism of solvent-responsive binary polymer brushes: density functional theory approach. Langmuir. 2013;29:4988–4997.10.1021/la304984s
   PubMed Web of Science ®Google Scholar
• Marko JF, Witten TA. Phase separation in a grafted polymer layer. Phys Rev Lett. 1991;66:1541–1544.10.1103/PhysRevLett.66.1541
   PubMed Web of Science ®Google Scholar
• Dong H. Phase separation of grafted polymers under strong demixing interaction. J Phys II France. 1993;3:999–1020.10.1051/jp2:1993178
   Google Scholar
• Dong J, Zhou J. Solvent-responsive behavior of polymer-brush-modified amphiphilic gold nanoparticles. Macromol Theory Simul. 2013;22:174–186.10.1002/mats.v22.3
   Web of Science ®Google Scholar
• Quan X, Peng C, Dong J, et al. Structural properties of polymer-brush-grafted gold nanoparticles at the oil-water interface: insights from coarse-grained simulations. Soft Matter. 2016;12:3352–3359.10.1039/C5SM02721G
   PubMed Web of Science ®Google Scholar
• Leonforte F, Mueller M. Poly(N-isopropylacrylamide)-based mixed brushes: a computer simulation study. ACS Appl Mater Interfaces. 2015;7:12450–12462.10.1021/am5076309
   PubMed Web of Science ®Google Scholar
• Wang J, Mueller M. Microphase separation of mixed polymer brushes: dependence of the morphology on grafting density, composition, chain-length asymmetry, solvent quality, and selectivity. J Phys Chem B. 2009;113:11384–11402.10.1021/jp903161j
   PubMed Web of Science ®Google Scholar
• Dong J, Li J, Zhou J. Interfacial and phase transfer behaviors of polymer brush grafted amphiphilic nanoparticles: a computer simulation study. Langmuir. 2014;30:5599–5608.10.1021/la500592 k
   PubMed Web of Science ®Google Scholar
• Lai PY, Halperin A. Polymer brushes in mixed solvents: chromatography and collapse. Macromolecules. 1992;25:6693–6695.10.1021/ma00050a045
   Web of Science ®Google Scholar
• Soga KG, Zuckermann MJ, Guo H. Binary polymer brush in a solvent. Macromolecules. 1996;29:1998–2005.10.1021/ma951102q
   Web of Science ®Google Scholar
• Zhulina E, Balazs AC. Designing patterned surfaces by grafting Y-shaped copolymers. Macromolecules. 1996;29:2667–2673.10.1021/ma951396f
   Web of Science ®Google Scholar
• Wenning L, Müller M, Binder K. How does the pattern of grafting points influence the structure of one-component and mixed polymer brushes? Europhys Lett. 2005;71:639–645.10.1209/epl/i2005-10121-4
   Google Scholar
• Marrink SJ, Risselada HJ, Yefimov S, et al. The MARTINI force field: coarse grained model for biomolecular simulations. J Phys Chem B. 2007;111:7812–7824.10.1021/jp071097f
   PubMed Web of Science ®Google Scholar
• Berendsen HJC, Postma JPM, van Gunsteren WF, et al. Molecular dynamics with coupling to an external bath. J Chem Phys. 1984;81:3684–3690.10.1063/1.448118
   Web of Science ®Google Scholar
• Hess B, Kutzner C, van der Spoel D, et al. GROMACS 4: algorithms for highly efficient, load-balanced, and scalable molecular simulation. J Chem Theory Comput. 2008;4:435–447.10.1021/ct700301q
   PubMed Web of Science ®Google Scholar
• Humphrey W, Dalke A, Schulten K. VMD: visual molecular dynamics. J Mol Graph. 1996;14(33–38):27–38.
   Google Scholar
• Wang ZL, Xu JT, Du BY, et al. Preparation and characterization of V-shaped PS-b-PEO brushes anchored on planar gold substrate through the trithiocarbonate junction group. J Colloid Interface Sci. 2012;384:29–37.10.1016/j.jcis.2012.06.067
   PubMed Web of Science ®Google Scholar
• Minko S, Muller M, Usov D, et al. Lateral versus perpendicular segregation in mixed polymer brushes. Phys Rev Lett. 2002;88:035502.10.1103/PhysRevLett.88.035502
   PubMed Web of Science ®Google Scholar