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Articles

Molecular understanding of the LCST phase behaviour of P(MEO2MA-b-OEGMA) block copolymers

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Pages 299-305 | Received 18 Aug 2020, Accepted 19 Dec 2020, Published online: 11 Feb 2021

References

  • Dai S, Ravi P, Tam KC. Thermo- and photo-responsive polymeric systems. Soft Matter. 2009;5(13):2513–2533.
  • Kocak G, Tuncer C, Bütün V. pH-Responsive polymers. Polym Chem. 2017;8(1):144–176.
  • Liu P. 1 – redox- and pH-responsive polymeric nanocarriers. In: Makhlouf ASH, Abu-Thabit NY, editors. Stimuli responsive polymeric nanocarriers for drug delivery applications. Oxford: Woodhead Publishing; 2019. p. 3–36.
  • Teotia AK, Sami H, Kumar A. 1 – Thermo-responsive polymers: structure and design of smart materials. In: Zhang Z, editor. Switchable and responsive surfaces and materials for biomedical applications. Oxford: Woodhead Publishing; 2015. p. 3–43.
  • Sardon H, Tan JPK, Chan JMW, et al. Thermoresponsive random poly(ether urethanes) with tailorable LCSTs for anticancer drug delivery. Macromol Rapid Commun. 2015;36(19):1761–1767.
  • Mallick S, Gandhi A, Joshi N, et al. Outcomes of pediatric glioblastoma treated with adjuvant chemoradiation with temozolomide and correlation with prognostic factors. Indian J Med Paediatr Oncol. 2015;36(2):99–104.
  • Cheng YH, Xia MG, Meng ZQ, et al. Structure-function integrated construction of nanocomposite hydrogels and their applications. Acta Polymerica Sinica. 2014;10:1342–1349.
  • Roy D, Brooks WLA, Sumerlin BS. New directions in thermoresponsive polymers. Chem Soc Rev. 2013;42(17):7214–7243.
  • Schild HG. Poly(N-isopropylacrylamide): experiment, theory and application. Prog Polym Sci. 1992;17(2):163–249.
  • Halperin A, Kröger M, Winnik FM. Poly(N-isopropylacrylamide) phase diagrams: fifty years of research. Angew Chemie Int Ed. 2015;54(51):15342–15367.
  • Ranganathan K, Deng R, Kainthan RK, et al. Synthesis of thermoresponsive mixed arm star polymers by combination of RAFT and ATRP from a multifunctional core and its self-assembly in water. Macromolecules. 2008;41(12):4226–4234.
  • Narang P, Venkatesu P. Unravelling the role of polyols with increasing carbon chain length and OH groups on the phase transition behavior of PNIPAM. New J Chem. 2018;42(16):13708–13717.
  • Yadav R, Kumar S, Narang P, et al. How does the addition of shape distinct gold nanoparticles influence on the conformational transition of poly(N-isopropylacrylamide)? J Colloid Interface Sci. 2021;582:478–487.
  • Yadav R, Aruchamy K, Mondal D, et al. Biomass-derived carbon helices induced phase transition in poly(N-ispropylacrylamide): a sustainable tailoring of coil-globule transition in thermoresponsive polymer. Colloids Surf B. 2020;187:110637.
  • Sambe L, Delarosa VR, Belal K, et al. Programmable polymer-based supramolecular temperature sensor with a Memory function. Angew Chemie Int Ed. 2014;53(20):5044–5048.
  • Vihola H, Laukkanen A, Valtola L, et al. Cytotoxicity of thermosensitive polymers poly(N-isopropylacrylamide), poly(N-vinylcaprolactam) and amphiphilically modified poly(N-vinylcaprolactam). Biomaterials. 2005;26(16):3055–3064.
  • Mehri S, Abnous K, Mousavi SH, et al. Neuroprotective effect of crocin on acrylamide-induced cytotoxicity in PC12 cells. Cell Mol Neurobiol. 2012;32(2):227–235.
  • Deshmukh SA, Kamath G, Suthar KJ, et al. Non-equilibrium effects evidenced by vibrational spectra during the coil-to-globule transition in poly(N-isopropylacrylamide) subjected to an ultrafast heating-cooling cycle. Soft Matter. 2014;10(10):1462–1480.
  • Hou L, Ma K, An Z, et al. Exploring the volume phase transition behavior of POEGA- and PNIPAM-based core–shell nanogels from infrared-spectral insights. Macromolecules. 2014;47(3):1144–1154.
  • Hou L, Wu P. Microgels with linear thermosensitivity in a wide temperature range. Macromolecules. 2016;49(16):6095–6100.
  • Ishizone T, Seki A, Hagiwara M, et al. Anionic polymerizations of oligo(ethylene glycol) alkyl ether methacrylates: effect of side chain length and ω-alkyl group of side chain on cloud point in water. Macromolecules. 2008;41(8):2963–2967.
  • Lutz J. Polymerization of oligo(ethylene glycol) (meth)acrylates: toward new generations of smart biocompatible materials. J Polym Sci Part A. 2008;46(11):3459–3470.
  • Özgür A, Badi N, Pfeifer S, et al. Design of thermoresponsive materials by ATRP of oligo(ethylene glycol)-based (macro)monomers. Acs Symp. 2009;1023:189–202.
  • Yamamoto S-I, Pietrasik J, Matyjaszewski K. The effect of structure on the thermoresponsive nature of well-defined poly(oligo(ethylene oxide) methacrylates) synthesized by ATRP. J Polym Sci Part A: Polym Chem. 2008;46(1):194–202.
  • Liu C, Li Y, Gao B, et al. Comb-shaped, temperature-tunable and water-soluble porphyrin-based thermoresponsive copolymer for enhanced photodynamic therapy. Mat Sci Eng C. 2018;82:155–162.
  • Guo Y, Liu H-J, Chen J-Q, et al. Synthesis of P(MEO2MA-co-OEGMA) random copolymers and thermally induced phase transition behaviors in aqueous solutions. Acta Physico-Chimica Sinica. 2015;31(10):1914–1923.
  • Abbott LJ, Tucker AK, Stevens MJ. Single chain structure of a poly(N-isopropylacrylamide) surfactant in water. J Phys Chem B. 2015;119(9):3837–3845.
  • Du H, Wickramasinghe R, Qian X. Effects of salt on the lower critical solution temperature of poly (N-isopropylacrylamide). J Phys Chem B. 2010;114(49):16594–16604.
  • de Oliveira TE, Mukherji D, Kremer K, et al. Effects of stereochemistry and copolymerization on the LCST of PNIPAm. J Chem Phys. 2017;146(3):034904.
  • de Solorzano O, Bejagam I, An KK, et al. Solvation dynamics of N-substituted acrylamide polymers and the importance for phase transition behavior. Soft Matter. 2020;16(6):1582–1593.
  • Dalgakiran E, Tatlipinar H. A computational study on the LCST phase transition of a poegma type thermoresponsive block copolymer: effect of water ordering and individual behavior of blocks. J Phys Chem B. 2019;123(6):1283–1293.
  • Dalgakiran E, Tatlipinar H. The role of hydrophobic hydration in the LCST behaviour of POEGMA300 by all-atom molecular dynamics simulations. Phys Chem Chem Phys. 2018;20(22):15389–15399.
  • Zhang C, Peng H, Puttick S, et al. Conformation of hydrophobically modified thermoresponsive poly(OEGMA-co-TFEA) across the LCST revealed by NMR and molecular dynamics studies. Macromolecules. 2015;48(10):3310–3317.
  • Wang J, Wolf RM, Caldwell JW, et al. Development and testing of a general Amber force field. J Comput Chem. 2004;25(9):1157–1174.
  • Case DA, Cerutti DS, Cheatham TE, et al. Amber. San Francisco, CA: University of California; 2017.
  • Frisch MJ, Trucks GW, Schlegel HB, et al. Gaussian 09. Wallingford: Gaussian; 2009.
  • Lu T, Chen F. Multiwfn: a multifunctional wavefunction analyzer. J Comput Chem. 2012;33(5):580–592.
  • Stephens PJ, Devlin FJ, Chabalowski CF, et al. Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields. J Phys Chem B. 1994;98(45):11623–11627.
  • Krishnan R, Binkley JS, Seeger R, et al. Self-consistent molecular orbital methods. XX. A basis set for correlated wave functions. J Chem Phys. 1980;72(1):650–654.
  • Miertuš S, Scrocco E, Tomasi J. Electrostatic interaction of a solute with a continuum. A direct utilizaion of AB initio molecular potentials for the prevision of solvent effects. Chem Phys. 1981;55(1):117–129.
  • Wang J, Cieplak P, Kollman PA. How well does a restrained electrostatic potential (RESP) model perform in calculating conformational energies of organic and biological molecules? J Comput Chem. 2000;21(12):1049–1074.
  • Abraham MJ, Murtola T, Schulz R, et al. GROMACS: high performance molecular simulations through multi-level parallelism from laptops to supercomputers. SoftwareX. 2015;1–2:19–25.
  • Jorgensen WL, Chandrasekhar J, Madura JD, et al. Comparison of simple potential functions for simulating liquid water. J Chem Phys. 1983;79(2):926–935.
  • Essmann U, Perera L, Berkowitz ML, et al. A smooth particle mesh Ewald method. J Chem Phys. 1995;103(19):8577–8593.
  • Hess B. P-LINCS: A parallel linear constraint solver for molecular simulation. J Chem Theory Comput. 2008;4(1):116–122.
  • Grubmüller H, Heller H, Windemuth A, et al. Generalized Verlet algorithm for efficient molecular dynamics simulations with long-range interactions. Mol Simul. 1991;6(1–3):121–142.
  • Bussi G, Donadio D, Parrinello M. Canonical sampling through velocity rescaling. J Chem Phys. 2007;126(1):014101.
  • Berendsen HJC, Postma JPM, van Gunsteren WF, et al. Molecular dynamics with coupling to an external bath. J Chem Phys. 1984;81(8):3684–3690.
  • Parrinello M, Rahman A. Polymorphic transitions in single crystals: a new molecular dynamics method. J Appl Phys. 1981;52(12):7182–7190.
  • Humphrey W, Dalke A, Schulten K. VMD: visual molecular dynamics. J Mol Graph. 1996;14(1):33–38.

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