Publication Cover
High Pressure Research
An International Journal
Volume 29, 2009 - Issue 2
83
Views
3
CrossRef citations to date
0
Altmetric
Original Articles

Thermal- and pressure-induced spin transition coupled to crystallographic phase transition in some Fe(II) molecular crystals

Pages 369-376 | Received 06 May 2008, Published online: 21 May 2009

References

  • Gütlich , P. , Hauser , A. and Spiering , H. 1994 . Themisch und optisch schaltbare Eisen(II)-Komplexe . Angew. Chemie , 106 : 2109 – 2141; . Topics in Current Chemistry: “Spin Crossover in Transition Metal Compounds I, II and III”, P. Gütlich and H.A. Goodwin eds., Vols. 233, 234 and 235, 2004
  • Drickamer , H. G. and Frank , C. W. 1973 . Electronic Transitions and the High Pressure Chemistry and Physics of Solids , 587 – 597 . London : Chapman and Hall . P. Adler, A. Hauser, A. Vef, H. Spiering, and P. Gütlich, Dynamics of spin state conversion processes in the solid state, Hyperfine Interactions 47 (1989), pp. 343–356; P. Adler, H. Spiering, and P. Gütlich, Thermodynamics and kinetics of spin state conversion processes studied by pressure dependent Mössbauer spectroscopy, J. Phys. Chem. Solids 50 (1989)
  • Gallois , B. , Real , J. A. , Hauw , C. and Zarembowitch , J. 1990 . Structural changes associated with the spin transition in Fe(phen)2(NCS)2: A single-crystal X-ray investigation . Inorg. Chem. , 29 : 1152 – 1158 .
  • Wiehl , L. , Spiering , H. , Gütlich , P. and Knorr , K. 1990 . J. Calculation of the lattice deformation at the phase transitions of [Fe(ptz)6](BF4)2 from powder diffraction patterns . Appl. Cryst. , 23 : 151 – 160 .
  • Jeftić , J. , Romstedt , H. and Hauser , A. 1996 . The interplay between the spin transition and the crystallographic phase transition in the Fe(II) spin-crossover system [Zn1−xFex(ptz)6](BF4)2 (x=0.1, 1; ptz=1-n-propyltetrazole . J. Phys. Chem. Solids, , 57 : 1743 – 1750 .
  • Jeftić , J. , Kindler , U. , Spiering , H. and Hauser , A. 1997 . Measurement science and technology, helium gas pressure cell for pressures up to 1 kbar (0.1 GPa) in conjunction with the cold head of a closed-cycle He refrigerator . Measur. Sci. Technol. , 8 : 479 – 483 .
  • Decurtins , S. , Gütlich , P. , Hasselbach , K. M. , Spiering , H. and Hauser , A. 1985 . Light-induces excited-spin-state trapping in iron(II) spin-crossover systems. Optical spectroscopic and magnetic susceptibility study . Inorg. Chem. , 24 : 2174 – 2178 .
  • Jeftić , J. and Hauser , A. 1997 . Pressure study of the thermal spin transition and the high-spin → low-spin relaxation in the R3¯ and P1¯ crystallographic phases of [Zn1−xFex(ptz)6](BF4)2 single crystals (x=0.1, 0.32, and 1; ptz=1-n-propyltetrazole . J. Phys. Chem. B , 101 : 10262 – 10270 .
  • Jeftić , J. , Hauser , A. , Varret , F. and Ecolivet , C. 2000 . Pressure, temperature and light influence on spin transition solids . High Press. Res. , 18 : 195 – 201 .
  • Lemée-Cailleau , M.-H. , Ecolivet , C. , Ouladdiaf , B. , Moussa , F. , Jeftić , J. and Létard , J. F. 2007 . Intermediate ferroelastic phase of the photo-sensible spin-crossover system [Fe(ptz)6](BF4)2 . J. Magnet. Magnet. Mater. , 310 : 1792 – 1793 .
  • Wiehl , L. 1993 . Structures of Hexakis(1-propyltetrazole)iron(II) Bis(tetrafluoroborate), [Fe(CHN4C3H7)6](BF4)2, Hexakis(1-methyltetrazole)iron(II) Bis(tetrafluoroborate), [Fe(CHN4CH3)6](BF4)2 and the analogous perchlorates. Their relation to spin crossover behaviour and comparison of Debye–Waller factors from structure determination and Mössbauer spectroscopy . Acta Cryst. , B49 : 289 – 303 .
  • Spiering , H. , Meissner , E. , Köppen , H. , Müller , E. W. and Gütlich , P. 1982 . The effect of the lattice expansion on high-spin → low-spin transitions . Chem. Phys. , 68 : 65 – 71 .
  • Adler , P. , Wiehl , L. , Meissner , E. , Köhler , C. P. , Spiering , H. and Gütlich , P. 1987 . The Influence of the lattice on the spin transition in solids. Investigations of the high-spin → low-spin transition in mixed crystals of [FexM1−x(2-pic)3]Cl2 MeOH . J. Phys. Chem. Solids , 48 : 517 – 525 .
  • Hauser , A. 1992 . Cooperative effects on the HS → LS relaxation in the [Fe(ptz)6](BF4)2 spin-crossover system . Chem. Phys. Lett. , 192 : 65 – 70 . A. Hauser, Intersystem Crossing in Iron(II) Coordination Compounds: A Model Process Between Classical and Quantum Mechanical Behaviour, Comm. Inorg. Chem. 17 (1995), 17–40
  • Jung , J. , Bruchhäuser , F. , Feile , R. , Spiering , H. and Gütlich , P. 1996 . The cooperative spin transition in [FexZn1−x(ptz)6](BF4)2: I. Elastic properties – an oriented sample rotation study by brillouin spectroscopy . Z. Phys. B , 100 : 517 – 522 .
  • Jung , J. , Schmitt , G. , Wiehl , L. , Hauser , A. , Knorr , K. , Spiering , H. and Gütlich , P. 1996 . The cooperative spin transition in [FexZn1−x(ptz)6](BF4)2: II. Structural properties and calculation of the elastic interaction . Z. Phys. B , 100 : 523 – 534 .
  • Willenbacher , N. and Spiering , H. 1988 . The elastic interaction of high-spin and low-spin complex molecules in spin-crossover compounds . J. Phys. C: Solid State Phys. , 21 : 1423 – 1439 .
  • Spiering , H. and Willenbacher , N. 1989 . Elastic interaction of high-spin and low-spin complex molecules in spin-crossover compounds: II . J. Phys. Condensed Matter , 1 : 10089 – 10105 .
  • Wiehl , L. , Spiering , H. , Gütlich , P. and Knorr , K. 1990 . Calculation of the lattice deformation at the phase transitions of [Fe(ptz)6](BF4)2 from powder diffraction patterns . J. Appl. Cryst. , 23 : 151 – 160 .
  • Hoselton , M. A. , Wilson , L. J. and Drago , R. S. 1975 . Substituent effects on the spin equilibrium observed with hexadecanate ligands on iron(II) . J. Amer. Chem. Soc. , 97 : 1722 – 1792 . B.A. Katz, C.E. Strouse, Molecular transformations in the solid state. Crystallographic resolution of the spin isomers of tris(2-picolylamine)iron(ii) dichloride and the structural relationship between the methanol and ethanol solvates, J. Amer. Chem. Soc. 101 (1979), pp. 6214–6221.; M. Mikami-Kido and Y. Saito, Structure of Tris(2-picolylamine)zinc(II) Dichloride-Ethanol, [Zn(α -pic)3]Cl2. EtOH; a complex related to an Fe II spin crossover complex, Acta Cryst. B38 (1982), 452–455
  • Wiehl , L. , Kiel , G. , Köhler , C. P. , Speiring , H. and Gütlich , P. 1986 . Structure determination and investigation of the high-spin → low-spin transition of tris[2-(aminomethyl)pyridine]iron(2+) dibromide monoethanol . Inorg. Chem. , 25 : 1565 – 1571 . R.A. Binstead and J.K. Beattie, Partial molal volumes of spin-equilibrium metal complexes, Inorg. Chem. 25 (1986), 1481–1484
  • Buhks , E. , Navon , G. , Bixon , M. and Jortner , J. 1980 . Spin conversion processes in solutions . J. Amer. Chem. Soc. , 102 : 2918 – 2923 .
  • Jeftić , J. , Hinek , R. , Capelli , S. and Hauser , A. 1997 . Cooperativity in the iron(ii) spin-crossover compound [Fe(ptz)6](PF6)2 under the influence of external pressure (ptz = 1-n-propyltetrazole) . Inorg. Chem. , 36 : 3080 – 3087 .
  • Jeftić , J. and Hauser , A. 1996 . The HS → LS relaxation under external pressure in the Fe(II) spin-crossover system [Zn1−xFe x (ptz)6](BF4)2 (ptz = 1-n-propyltetrazole, x = 0.1) . Chem. Phys. Lett. , 248 : 458 – 463 .
  • Jeftić , J. , Matsarski , M. , Hauser , A. , Goujon , A. , Codjovi , E. , Linarès , J. and Varret , F. 2001 . Quasi-static nature of the light induced thermal hysteresis in [Fe(ptz)6](BF4)2 spin-transition solid . Polyhedron , 20 : 1599 – 1606 .
  • Jeftić , J. , Varret , F. , Hauser , A. , Roubeau , O. , Matsarski , M. and Rivera , J. P. 1999 . Patterns during photoexcitation and high-spin → low-spin relaxation in [Fe(ptz)6](BF4)2 spin transition crystal . Mol. Crys. Liquid Crys. , 335 : 511 – 520 .
  • Hauser , A. , Jeftić , J. , Romstedt , H. , Hinek , R. and Spiering , H. 1999 . Cooperative phenomena and light-induced bistability in iron(II) spin-crossover compounds . Coord. Chem. Rev. , 190–192 : 471 – 491 .
  • Desaix , A. , Roubeau , O. , Jeftić , J. , Haasnoot , J. G. , Boukheddaden , K. , Codjovi , E. , Linarès , J. , Noguès , M. and Varret , F. 1998 . Light-induced bistability in spin transition solids leading to thermal and optical hysteresis . Eur. Phys. J. B , 6 : 183 – 193 .
  • Jeftić , J. 2004 . Internal pressure in a molecular crystal under influence of light: the iterplay with the structural phase transition . High Pressure Res. , 24 : 459 – 462 .
  • Varret , F. , Boukheddaden , K. , Chong , C. , Goujon , A. , Gillon , B. , Jeftić , J. and Hauser , A. 2007 . Light-induced self-organisation of like-spin domains in spin-crossover single crystal [Fe(ptz)6](BF4)2 . Eur. Phys. Lett. , 77 : 30007-1 – 6 .
  • Goujon , A. , Varret , F. , Boukheddaden , K. , Chong , C. , Jeftić , J. , Garcia , Y. , Naik , A. D. , Ameline , J. C. and Collet , E. An optical microscope study of photo-switching and relaxation in single crystals of the spin transition solid [Fe(ptz)6](BF4)2 with image processing . Inorg. Chim. Acta. , 361 4055 – 4064 .
  • Goujon , A. , Gillon , B. , Gukasov , A. , Jeftić , J. , Nau , Q. , Codjovi , E. and Varret , F. 2003 . Photoinduced molecular switching studied by polarized neutron diffraction . Phys. Rev. B. , 67 : 220401-1 –  4 .
  • Goujon , A. , Gillon , B. , Debede , A. , Cousson , A. , Gukasov , A. , Jeftić , J. , McIntyre , G. and Varret , F. 2006 . Neutron Laue diffraction on the spin crossover crystal [Fe(1-n-propyltetrazole)6](BF4)2 showing continuous photoinduced transformation . Phys. Rev. B. , 73 104413(1–5)
  • Jeftić , J. , Gillon , B. , Goujon , A. , Nau , Q. , Gukasov , A. , Codjovi , E. and Varret , F. 2003 . First study of the photo-induced metastable (paramagnetic) high-spin state in a [Fe(ptz)6](BF4)2 single crystal by polarised neutron diffraction . Polyhedron , 22 : 2155 – 2160 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.