206
Views
5
CrossRef citations to date
0
Altmetric
Original Articles

UV-Visible Spectrophotometry for the Determination of Conjugated Polyene Structures of Poly(vinyl chloride) in 1,2-Dichloroethane

, , , , &
Pages 240-249 | Received 10 Nov 2014, Accepted 02 Dec 2014, Published online: 02 Apr 2015

REFERENCES

  • Sowe, M., I. Novák, A. Vesel, I. Junkar, M. Lehocký, P. Sáha, and I. Chodák. 2009. Analysis and characterization of printed plasma-treated polyvinyl chloride. Int. J. Polym. Anal. Charact. 14: 641–651.
  • Lenartowicz, M., B. Swinarew, A. Swinarew, and G. Rymarz. 2014. The evaluation of long-term aged PVC. Int. J. Polym. Anal. Charact. 19: 611–624.
  • Behnisch, J., and H. Zimmermann. 1992. Kinetics and mechanism of the polyene formation during dehydrochlorination of poly (vinyl chloride) in the solid state. Int. J. Polym. Mater. 16: 143–157.
  • Parab, Y. S., P. A. Wasekar, S. T. Mhaske, and S. R. Shukla. 2014. Novel synthesis, characterization and application of dibutyrate bis (2-hydroxyethyl) terephthalamide as a plasticizer in PVC compounding. Polym. Bull. 71: 2695–2707.
  • Gong, F., M. Feng, C. Zhao, S. Zhang, and M. Yang. 2004. Particle configuration and mechanical properties of poly(vinyl chloride)/montmorillonite nanocomposites via in situ suspension polymerization. Polym. Test. 23: 847–853.
  • D’Aquino, C. A., W. Balmant, R. L. L. Ribeiro, M. Munaro, J. V. C. Vargas, and S. C. Amico. 2012. A simplified mathematical model to predict PVC photodegradation in photobioreactors. Polym. Test. 31: 638–644.
  • Braun, V. D., and M. Thallnaier. 1966. Zum mechanismus der thermischen chlorwassmtoffabspaltung aus polyvinylchlorid. 3. Mitt. Über die länge der polyensequenzen in partiell dehydrohalogenierten poiyvinylchloriden, polyvinylbromiden und vinylchlorid-copolymeren. Makromol. Chem. 99: 59–75.
  • Daniels, V., and N. Rees. 1974. Analysis of the ultraviolet/visible spectrum of degraded poly (vinyl chloride) to determine polyene concentrations. J. Polym. Sci., Part A: Polym. Chem. 12: 2115–2122.
  • Sterky, K., T. Hjertberg, and H. Jacobsen. 2009. Effect of montmorillonite treatment on the thermal stability of poly (vinyl chloride) nanocomposites. Polym. Degradation Stab. 94: 1564–1570.
  • Zhang, X., H. Pi, and S. Guo. 2012. The effect of high intensity UV irradiation on color behavior of poly (vinyl chloride). J. Macromol. Sci., Phys. 51: 1303–1321.
  • Moulay, S. 2010. Chemical modification of poly (vinyl chloride)—Still on the run. Prog. Polym. Sci. 35: 303–331.
  • Andreopoulos, A., A. Pappa, and N. Tzamtzis. 1994. Testing of weathered poly (vinyl chloride). Polym. Test. 13: 3–13.
  • Wan, C., Y. Zhang, and Y. Zhang. 2004. Effect of alkyl quaternary ammonium on processing discoloration of melt-intercalated PVC-montmorillonite composites. Polym. Test. 23: 299–306.
  • Real, L. P., and J.-L. Gardette. 2001. Ageing and characterisation of PVC-based compounds utilised for exterior applications in the building construction field: 1: Thermal ageing. Polym Test. 20: 779–787.
  • Rama Mohan, K., V. Achari, V. Rao, and A. Sharma. 2011. Electrical and optical properties of (PEMA/PVC) polymer blend electrolyte doped with NaClO4. Polym Test. 30: 881–886.
  • Manzoor, W., S. Yousaf, and Z. Ahmad. 1996. Degradation of PVC: Effect of zinc chloride on the concentration of polyenes. Polym. Degradation Stab. 51: 295–299.
  • Shi, W., J. Zhang, X. M. Shi, and G. D. Jiang. 2008. Different photodegradation processes of PVC with different average degrees of polymerization. J. Appl. Polym. Sci. 107: 528–540.
  • Torikai, A., and H. Hasegawa. 1999. Accelerated photodegradation of poly (vinyl chloride). Polym. Degradation Stab. 63: 441–445.
  • Baltacioğlu, H., and D. M. Balköse. 1999. Effect of zinc stearate and/or epoxidized soybean oil on gelation and thermal stability of PVC-DOP plastigels. J. Appl. Polym. Sci. 74: 2488–2498.
  • Shindo, Y., and T. Hirai. 1972. Dehydrohalogenation of polyvinylchloride in tetrahydrofuran solution with alcoholic KOH. Makromol. Chem. 155: 1–16.
  • Boissel, J. 1977. Double bonds in poly (vinyl chloride). J. Appl. Polym. Sci. 21: 855–857.
  • Rabek, J. F., Y. J. Shur, and B. Rårnby. 1975. Studies of the photooxidation mechanism of polymers. III. Role of tetrahydrofuran in the photooxidative degradation of poly (vinyl chloride). J. Polym. Sci., Part A: Polym. Chem. 13: 1285–1295.
  • Al-Dossary, A. K., M. Gilbert, and D. Hitt. 2010. Evaluating PVC degradation using UV and Raman spectroscopies. Adv. Mater. Res. 83: 923–930.
  • Skillicorn, D., G. Perkins, A. Slark, and J. Dawkins. 1993. Molecular weight and solution viscosity characterization of PVC. J. Vinyl Technol. 15: 105–108.
  • Patel, K., A. Velazquez, H. Calderon, and G. Brown. 1992. Studies of the solid-state thermal degradation of PVC. I. Autocatalysis by hydrogen chloride. J. Appl. Polym. Sci. 46: 179–187.
  • Abbås, K. B., and E. M. Sörvik. 1973. On the thermal degradation of poly (vinyl chloride). II. The effect of atmosphere. J. Appl. Polym. Sci. 17: 3577–3594.
  • Braun, D., and D. Sonderhof. 1985. Assignment of UV-absorption maxima of degraded PVC. Polym. Bull. 14: 39–43.
  • Sondheimer, F., D. A. Ben-Efraim, and R. Wolovsky. 1961. Unsaturated macrocyclic compounds. XVII. The prototropic rearrangement of linear 1,5-enynes to conjugated polyenes. The synthesis of a series of vinylogs of butadiene. J. Am. Chem. Soc. 83: 1675–1681.
  • Ouyang, S., C. Sun, M. Zhou, D. Li, W. Wang, G. Qu, Z. Li, S. Gao, and J. Yang. 2010. Effect of solution concentration on the structured order and optical properties of short-chain polyene biomolecules. Sci. China Phys. Mech. Astron. 53: 1646–1650.
  • Paraschuk, D. Y., and V. Kobryanskii. 2001. Coherent electron-lattice vibrations in trans-nanopolyacetylene probed by Raman scattering. Phys. Rev. Lett. 87: 207402.
  • Hagler, T., K. Pakbaz, K. Voss, and A. Heeger. 1991. Enhanced order and electronic delocalization in conjugated polymers oriented by gel processing in polyethylene. Phys. Rev. B. 44: 8652–8666.
  • Rogestedt, M., and T. Hjertberg. 1993. Structure and degradation of commercial poly (vinyl chloride) obtained at different temperatures. Macromolecules. 26: 60–64.
  • Van Cauter K., B. J. Van Den Bossche, V. Van Speybroeck, and M. Waroquier. 2007. Ab initio study of free-radical polymerization: Defect structures in poly (vinyl chloride). Macromolecules. 40: 1321–1331.
  • Purmová, J., K. F. Pauwels, M. Agostini, M. Bruinsma, E. J. Vorenkamp, A. J. Schouten, and M. L. Coote. 2008. Experimental and theoretical evaluation of the reactions leading to formation of internal double bonds in suspension PVC. Macromolecules 41: 5527–5539.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.