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Original Articles

Crystal and molecular structures of trans-[PdCl2(SMePh)2] · C6H6, trans-[Pd2Cl2(#-SPh)2(SPh2)2], and trans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2

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Pages 125-136 | Received 10 Jun 2006, Published online: 15 Feb 2007

References

  • Vigo , L. , Risto , M. , Jahr , E. M. , Bajorek , T. , Oilunkaniemi , R. , Laitinen , R. S. , Lahtinen , M. and Ahlgren , M. 2006 . Isomerism in [MCl2(ERR′)2] (M=Pd, Pt; E=S, Se; R, R′=Me, Ph) . Crystal Growth Design , 6 : 2376
  • Johansson , M. H. , Oskarsson , A. , Lövqvist , K. , Kiriakidou , F. and Kapoor , P. 2001 . Cis- and trans-influences in [PtCl2(SPh2)2] . Acta Crystallogr., Sect. C , 57 : 1053
  • Kharasch , M. S. , Seyler , R. C. and Mayo , F. R. 1938 . Coordination compounds of palladous chloride . J. Am. Chem. Soc. , 60 : 882
  • Altomare , A. , Cascarano , G. , Giacovazzo , C. and Gualardi , A. 1993 . Completion and refinement of crystal structures with SIR92 . J. Appl. Cryst. , 26 : 343
  • Sheldrick , G. M. 1997 . SHELXS-97: Program for Crystal Structure Determination , Göttingen, , Germany : University of Göttingen .
  • Sheldrick , G. M. 1997 . SHELXL-97: Program for Crystal Structure Refinement , Göttingen, , Germany : University of Göttingen .
  • Bondi , A. 1964 . Van der Waals volumes and radii . J. Phys. Chem. , 68 : 441
  • Oilunkaniemi , R. , Komulainen , J. , Laitinen , R. S. , Ahlgrén , M. and Pursiainen , J. 1998 . Trends in the structure and bonding of [MCl2{(C4H3S)ECH3}2] (M=Pd, Pt; E=Te, Se) . J. Organomet. Chem. , 521 : 129
  • Padilla , E. M. , Golen , J. A. , Richmann , P. N. and Jensen , C. M. 1991 . Effects of sulfur substituents on the geometries of dipalladium μ-thiolatocomplexes: crystal structures of Pd2Cl2(μ-Cl)(μ-SR)(PMe3)2 (R=methyl, tert-butyl and phenyl) and Pd2Cl2(μ-SPh)2(PEt3)2 . Polyhedron , 10 : 1343
  • Cao , R. , Hong , M. , Jiang , F. , Kang , B. , Xie , X. and Liu , H. 1996 . Syntheses of palladium(II) complexes with thiolate and phosphine ligands. X-ray crystal structures of [Pd(tdt)(PPh3)2]• C2H4Cl2 and [Pd2(Hmp)2(PPh3)2Cl2] . Polyhedron , 15 : 2661
  • Gibson , V. C. , Long , N. J. , Long , R. J. , White , A. J.P. , Williams , C. K. , Williams , D. J. , Grigiotti , E. and Zanello , P. 2004 . Synthesis, characterization, and metal complexation of unsymmetrical 1,1′-bis(organylthiolato)ferrocenes . Organometallics , 23 : 957
  • Gibson , V. C. , Long , N. J. , White , A. J.P. , Williams , C. K. and Williams , D. J. 2000 . New unsymmetrical thioether- and thiolate-substituted ferrocene ligands and an unusual bridged-Pd dimer complex . Chem. Commun. , : 2359
  • Aurivillius , K. and Bertinsson , G. -I. 1981 . μ-[1,9-Bis(diphenylphosphino)-3,7-dithianonane]-bis[dichloropalladium(II)] . Acta Crystallogr., Sect. B , 37 : 2073
  • Jain , V. K. , Patel , R. P. , Muralidharan , K. V. and Bohra , R. 1989 . Dinuclear palladium(II) complexes with bridging mercapto group: x-ray crystal structure of a chloro/mercapto bridged dimmer . Polyhedron , 8 : 2151
  • Liu , S. -T. , Tsao , C. -L. , Cheng , M. -C. and Peng , S. -M. 1990 . Tripodal ligands with mixed donors. Synthesis of 2-diphenylphosphinomethyl-2-phenylthiometryl-1-methoxypropane (PSO) and its transition metal complexes . Polyhedron , 9 : 2579
  • Padilla , E. M. and Jensen , C. M. 1991 . Isolation of a tetrakis(μ-thiolato)tripalladium complex: crystal structure of trans-Pd3(μ-SCy)4Cl2(PMe3)2 . Polyhedron , 10 : 89
  • Yamamoto , J. H. , Yap , G. P.A. and Jensen , C. M. 1991 . Ring-opening and insertion of a cyclic thioether into a palladium-chlorine bond . J. Am. Chem. Soc. , 113 : 5060
  • Zhang , L. -F. , Yang , J. , Huang , D. -J. and Li , G. -N. 1993 . Synthesis and molecular structure of phosphorus-sulfur hybrid atom ligand and their palladium complexes with the studies on the C-H bond activation and photochemical carbonylation reaction of benzene . Sci. China, Ser. B , 36 : 513
  • Alvarez-Larena , A. , Piniella , J. F. , Arnau , N. , Moreno-Manas , M. and Pleixats , R. 1993 . Crystal structure of trans-(benzenethiolato)chlorobis(triphenylphosphine) palladium(II), Pd(SC6H5)(P(C6H5)3)2Cl . Z. Kristallogr. , 208 : 249
  • Sunkel , K. and Blum , A. 1995 . Palladium(II) and platinum(II) complexes of [C5(SMe)5]Mn(CO)3, [C5Cl2(SMe)3]Mn(CO)3, and [C5Cl2(SMe)2(PPh2)]Mn(CO)3 . Z. Naturforsch., B , 50 : 1307
  • Leung , P. -H. , Loh , S. -K. , Mok , K. F. , White , A. J.P. and Williams , D. J. 1996 . Asymmetric syntheses, structures and co-ordination chemistry of palladium(II) complexes containing a chiral P,S hybrid bidentate ligand . J. Chem. Soc., Dalton Trans. , : 4443
  • Albinati , A. , Herrmann , J. and Pregosin , P. S. 1997 . Ferrocene-based chiral dinuclear thiolato-bridged complexes of Pd(II) and Pt(II) . Inorg. Chim. Acta , 264 : 33
  • Abu-Surrah , A. S. , Lappalainen , K. , Klinga , M. , Leskela , M. , Hodali , H. A. and Rieger , B. 1999 . A dichloropalladium(II) complex with a mixed donor bidentate ligand: dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II) . Acta Crystallogr., Sect. C , 55 : 188
  • Brugat , N. , Polo , A. , Alvarez-Larena , A. , Piniella , J. F. and Real , J. 1999 . Palladium phosphinothiolato complexes. Syntheses and crystal structures of mononuclear [PdCl(SC2H4PPh2)PPh3] and binuclear [Pd2Cl2(μ-SC3H6PPh2)2] and their performance in catalytic carbonylation . Inorg. Chem. , 38 : 4829
  • Hauptman , E. , Fagan , P. J. and Marshall , W. 1999 . Synthesis of novel (P,S) ligands based on chiral nonracemic episulfides. Use in asymmetric hydrogenation . Organometallics , 18 : 2061
  • Evans , D. A. , Campos , K. R. , Tedrow , J. S. , Michael , F. E. and Gagne , M. R. 2000 . Application of chiral mixed phosphorus/sulfur ligands to palladium-catalyzed allylic substitutions . J. Am. Chem. Soc. , 122 : 7905
  • Kranich , R. , Eis , K. , Geis , O. , Muhle , S. , Bats , J. W. and Schmalz , H. -G. 2000 . A modular approach to structurally diverse bidentate chelate ligands for transition metal catalysis . Chem.-Eur. J. , 6 : 2874
  • Jones , W. D. , Reynolds , K. A. , Sperry , C. K. , Lachicotte , R. J. , Godleski , S. A. and Valente , R. R. 2000 . Selective carbonylation routes to thiocarbamates. An alternative to phosgene . Organometallics , 19 : 1661
  • Aupers , J. H. , Ferguson , G. , Glidewell , C. , Low , J. N. and Wardell , J. L. 2000 . Chloro(2-nitrobenzenethiolato-S)bis(triphenylphosphine-P)palladium(II) monoacetone solvate . Acta Crystallogr., Sect. C , 56 : 945
  • Alyea , E. C. , Kannan , S. and Ferguson , G. 2000 . Cis-μ-chloro-μ-p-toluenethiolato-bis[chloro(triethylphosphine)palladium] . Acta Crystallogr., Sect. C , 56 ( e493 )
  • Arena , C. G. , Drommi , D. , Faraone , F. , Graiff , C. and Tiripicchio , A. 2001 . Formation of metallamacrocycles from palladium(II), platinum(II) and copper(I) complexes and the ditopic ligands [{p-(Ph2PO)C6H4}2CMe2], [{2-Ph2PO-3,5-(Me3C)2C6H2}2S], [{p-[(C10H6O)2PO]C6H4}2CMe2] . Eur. J. Inorg. Chem. , : 247
  • Zhang , Q. , Slawin , A. M.Z. and Woollins , J. D. 2001 . Chiral palladium complexes from N-diphenylphosphinoamino methyl esters . J. Chem. Soc., Dalton Trans. , : 3598
  • Howie , R. A. and Wardell , J. L. 2002 . trans-Chloro(4-nitrobenzenethiolato-S)bis(triphenyl-phosphine-P)palladium(II) 1,2-dichloroethane hemisolvate at 120 K . Acta Crystallogr., Sect. E , 58 ( m178 )
  • Morales-Morales , D. , Redon , R. , Zheng , Y. and Dilworth , J. R. 2002 . Highly efficient and regioselective couplings of aryl halides to olefins catalyzed by a palladium complex with a hybrid phosphorus-sulfur ligand . Inorg. Chim. Acta , 328 : 39
  • Priego , J. , Mancheno , O. G. , Cabrera , S. , Arrayas , R. G. , Llamas , T. and Carretero , J. C. 2002 . 1-Phosphino-2-sulfenylferrocenes: efficient ligands in enantioselective palladium-catalyzed allylic substitutions and ring opening of 7-oxabenzonorbornadienes . Chem. Commun. , : 2512
  • Al-Shami , E. M. , Abu-Surrah , A. S. , Klinga , M. and Hodali , H. A. 2002 . Palladium(II) complexes with the mixed-donor ligand CH3S-(CH2)3-PPh2 crystal structures of [PdCl2{CH3S-(CH2)3-PPh2}n] (n=1, 2) . Z. Anorg. Allg. Chem. , 628 : 1433
  • Nakano , H. , Suzuki , Y. , Kabuto , C. , Fujita , R. and Hongo , H. 2002 . Chiral phosphinooxathiane ligands for catalytic asymmetric Diels-Alder reaction . J. Org. Chem. , 67 : 5011
  • Escriche , L. , Munoz , J. A. , Kivekas , R. , Sillanpää , R. and Casabo , J. 2002 . Synthesis, characterisation and reactivity towards PdII and PtII of ortho-, meta- and para-xylyl-based phosphorus-containing macrocycles . Eur. J. Inorg. Chem. , : 3258
  • Mancheno , O. G. , Priego , J. , Cabrera , S. , Arrayas , R. G. , Llamas , T. and Carretero , J. C. 2003 . 1-Phosphino-2-sulfenylferrocenes as planar chiral ligands in enantioselective palladium-catalyzed allylic substitutions . J. Org. Chem. , 68 : 3679
  • Dervisi , A. , Jenkins , R. L. , Malik , K. M.A. , Hursthouse , M. B. and Coles , S. 2003 . Synthesis of Ni(II), Pd(II) and Pt(II) complexes containing chiral phosphino-thiol and -thioether ligands . Dalton Trans. , : 1133
  • Kostas , I. D. , Steele , B. R. , Terzis , A. and Amosova , S. V. 2003 . A palladium complex with a new hemilabile amino- and sulfur-containing phosphinite ligand as an efficient catalyst for the Heck reaction of aryl bromides with styrene. The effect of the amino group . Tetrahedron , 59 : 3467
  • Seibert , M. , Merzweiler , K. , Wagner , C. and Weichmann , H. 2003 . Ligand behavior of P-functionally substituted organotin halides: palladium(II) and platinum(II) complexes with Ph2PCH2CH2SnCl3 . J. Organomet. Chem. , 687 : 131
  • Al-Shami , E. M. , Abu-Surrah , A. S. , Klinga , M. , Ahlgren , M. and Hodali , H. A. 2003 . Crystal structure of dichloro(3-methylthio-2-methylpropyl)diphenylphosphine palladium(II) dichloromethane (1:1), Pd(C17H21PS)Cl2• CH2Cl2 . Z. Kristallogr.-New Cryst. Struct. , 218 : 537
  • Shi , M. and Zhang , W. 2004 . Axially chiral P,S-heterodonor ligands with a binaphthalene framework for palladium-catalyzed asymmetric allylic substitutions: experimental investigation on the reversal of enantioselectivity between different alkyl groups on sulfur atom . Tetrahedron: Asymm. , 15 : 3467
  • Molander , G. A. , Burke , J. P. and Carroll , P. J. 2004 . Synthesis and application of chiral cyclopropane-based ligands in palladium-catalyzed allylic alkylation . J. Org. Chem. , 69 : 8062
  • Mancheno , O. G. , Arrayas , R. G. and Carretero , J. C. 2005 . Palladium complexes of chiral planar 1-phosphino-2-sulfenylferrocenes as efficient catalysts in enantioselective Diels-Alder reactions . Organometallics , 24 : 557

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