459
Views
1
CrossRef citations to date
0
Altmetric
Research Article

Rheology, morphology and phase behavior of SBS/sulfur modified asphalt based on experimental assessment and molecular dynamics

&
Article: 2159029 | Received 02 Feb 2022, Accepted 09 Dec 2022, Published online: 20 Dec 2022

Reference

  • Airey, G.D., 2003. Rheological properties of styrene butadiene styrene polymer modified road bitumens. Fuel, 82 (14), 1709–1719.
  • ASTM D4124, 2018. Standard test method for separation of asphalt into four fractions. West Conshohocken, PA: ASTM International.
  • ASTM D7173, 2020. Standard practice for determining the separation tendency of polymer from polymer-modified asphalt. West Conshohocken, PA: ASTM International.
  • ASTM D7175, 2015. Standard test method for determining the rheological properties of asphalt binder using a dynamic shear rheometer. West Conshohocken, PA: ASTM International.
  • ASTM D7405, 2015. Standard test method for multiple stress creep and recovery (MSCR) of asphalt binder using a dynamic shear rheometer. West Conshohocken, PA: ASTM International.
  • Behnood, A., and Modiri Gharehveran, M., 2019. Morphology, rheology, and physical properties of polymer-modified asphalt binders. European Polymer Journal, 112, 766–791.
  • Canto, L.B., et al., 2006. Molecular characterization of styrene-butadiene-styrene block copolymers (SBS) by GPC, NMR, and FTIR. Polymer Bulletin, 57 (4), 513–524.
  • Chen, Z., et al., 2018. Performance characteristics of asphalt materials based on molecular dynamics simulation – A review. Construction and Building Materials, 189, 695–710.
  • Chen, M., et al., 2021a. A review of phase structure of SBS modified asphalt: affecting factors, analytical methods, phase models and improvements. Construction and Building Materials, 294, 123610.
  • Chen, Z., et al., 2021b. Aggregation behavior of asphalt on the natural gas hydrate surface with different surfactant coverages. Journal of Physical Chemistry C, 125 (30), 16378–16390.
  • Chen, J.S., and Huang, C.C., 2007. Fundamental characterization of SBS-modified asphalt mixed with sulfur. Journal of Applied Polymer Science, 103 (5), 2817–2825.
  • Cui, B., et al., 2020. A multiphysics evaluation of the rejuvenator effects on aged asphalt using molecular dynamics simulations. Journal of Cleaner Production, 259, 120629.
  • Dan, H.C., et al., 2020. Effects of aggregate type and SBS copolymer on the interfacial heat transport ability of asphalt mixture using molecular dynamics simulation. Construction and Building Materials, 250, 118922.
  • D’Angelo, J., and Dongré, R., 2009. Practical use of multiple stress creep and recovery test: characterization of styrene–butadiene–styrene dispersion and other additives in polymer-modified asphalt binders. Transportation Research Record, 1, 73–82.
  • Ding, Y., et al., 2015. Molecular dynamics simulation to investigate the influence of SBS on molecular agglomeration behavior of asphalt. Journal of Materials in Civil Engineering, 27 (8), 5–11.
  • Ding, W., et al., 2020. Dissolution of polycyclic aromatic hydrocarbons in supercritical water in hydrogen production process: a molecular dynamics simulation study. International Journal of Hydrogen Energy, 45 (52), 28062–28069.
  • ElFaham, M.M., Mostafa, A.M., and Nasr, G.M., 2020. Unmanned aerial vehicle (UAV) manufacturing materials: synthesis, spectroscopic characterization and dynamic mechanical analysis (DMA). Journal of Molecular Structure, 1201, 127211.
  • Griebel, J.J., et al., 2016. Polymerizations with elemental sulfur: a novel route to high sulfur content polymers for sustainability, energy and defense. Progress in Polymer Science, 58, 90–125.
  • Hao, G., et al., 2017. Effect of aging on chemical and rheological properties of SBS modified asphalt with different compositions. Construction and Building Materials, 156, 902–910.
  • Hiemenz, P.C., and Lodge, T.P., 2007. Polymer chemistry. Boca Raton: CRC press.
  • Huang, W., and Tang, N., 2015. Characterizing SBS modified asphalt with sulfur using multiple stress creep recovery test. Construction and Building Materials, 93, 514–521.
  • JTG F41-2008, 2008. Technical Specifications for Highway Asphalt Pavement Recycling, Chinese Standard.
  • Li, C., Fan, S., and Xu, T., 2021. Method for evaluating compatibility between SBS modifier and asphalt matrix using molecular dynamics models. Journal of Materials in Civil Engineering, 33 (8), 04021207.
  • Li, D.D., and Greenfield, M.L., 2014. Chemical compositions of improved model asphalt systems for molecular simulations. Fuel, 115, 347–356.
  • Li, G., and Tan, Y., 2022. The construction and application of asphalt molecular model based on the quantum chemistry calculation. Fuel, 308, 122037.
  • Liang, M., et al., 2015. Thermo-rheological behavior and compatibility of modified asphalt with various styrene-butadiene structures in SBS copolymers. Materials and Design, 88, 177–185.
  • Liang, M., et al., 2017. Effects of polymerized sulfur on rheological properties, morphology and stability of SBS modified asphalt. Construction and Building Materials, 150, 860–871.
  • Liang, M., et al., 2019. Phase field simulation and microscopic observation of phase separation and thermal stability of polymer modified asphalt. Construction and Building Materials, 204, 132–143.
  • Luo, L., Chu, L., and Fwa, T.F., 2021. Molecular dynamics analysis of oxidative aging effects on thermodynamic and interfacial bonding properties of asphalt mixtures. Construction and Building Materials, 269, 121299.
  • Ma, Y., et al., 2021. Potential alternative to styrene–butadiene–styrene for asphalt modification using recycled rubber–plastic blends. Journal of Materials in Civil Engineering, 33 (12), 04021341.
  • Mousavi, M., and Fini, E.H., 2021. Phenolic compounds to amplify the effect of sulfur on Bitumen's thermomechanical properties. Fuel, 287, 119532.
  • Nakason, C., et al., 2006. Dynamic vulcanization of natural rubber/high-density polyethylene blends: effect of compatibilization, blend ratio and curing system. Polymer Testing, 25 (6), 782–796.
  • Pahlavan, F., Hung, A., and Fini, E.H., 2018. Evolution of molecular packing and rheology in asphalt binder during rejuvenation. Fuel, 222, 457–464.
  • Petrossi, U., Bocca, P.L., and Pacor, P., 1972. Reactions and technological properties of sulfur-treated asphalt. Industrial & Engineering Chemistry Product Research and Development, 2 (11), 214–219.
  • Qiu, G., et al., 2001. Hydrolysis of aromatic heterocyclic polymers in high temperature water.I. Hydrolysis of polyphenyl-1,2,4-triazine. Journal of Applied Polymer Science, 82 (4), 907–915.
  • Sakib, N., et al., 2021. A review of the evolution of technologies to use sulphur as a pavement construction material. International Journal of Pavement Engineering, 22 (3), 392–403.
  • Schaur, A., Unterberger, S., and Lackner, R., 2017. Impact of molecular structure of SBS on thermomechanical properties of polymer modified bitumen. European Polymer Journal, 96, 256–265.
  • Shao, L., et al., 2016. The synergy of double cross-linking agents on the properties of styrene butadiene rubber foams. Scientific Reports, 6 (July), 1–15.
  • Su, M., et al., 2020. Molecular dynamics study on influence of Nano-ZnO/SBS on physical properties and molecular structure of asphalt binder. Fuel, 263, 116777.
  • Su, M., et al., 2022. Using molecular dynamics and experiments to investigate the morphology and micro-structure of SBS modified asphalt binder. Materials Today Communications, 30, 103082.
  • Sun, D., et al., 2018. Intrinsic temperature sensitive self-healing character of asphalt binders based on molecular dynamics simulations. Fuel, 211 (October 2017), 609–620.
  • Syroezhko, A.M., et al., 2003. Modification of paving asphalts with sulfur. Russian Journal of Applied Chemistry, 76 (3), 491–496.
  • Wadi, V.S., et al., 2020. Scalable high refractive index polystyrene-sulfur nanocomposites via in situ inverse vulcanization. Scientific Reports, 10 (1), 1–12.
  • Wang, Z., et al., 2018. Enhancement of charge transport in quantum dots solar cells by N-butylamine-assisted sulfur-crosslinking of PbS quantum dots. Solar Energy, 174 (August), 399–408.
  • Wen, G., et al., 2002. Improved properties of SBS-modified asphalt with dynamic Vu lcanization. Polymer Engineering & Science, 42 (5), 1070–1081.
  • White, R.P., and Lipson, J.E.G., 2016. Polymer free volume and its connection to the glass transition. Macromolecules, 49 (11), 3987–4007.
  • Xia, T., et al., 2018. Viscoelastic phase separation and crystalline-to-amorphous phase transition in bitumen/SBS/PE blends. Polymer, 155 (August), 129–135.
  • Xu, G., and Wang, H., 2016. Study of cohesion and adhesion properties of asphalt concrete with molecular dynamics simulation. Computational Materials Science, 112, 161–169.
  • Xu, G., and Wang, H., 2017. Molecular dynamics study of oxidative aging effect on asphalt binder properties. Fuel, 188, 1–10.
  • Yang, Z., et al., 2010. Crystallization behavior of poly(ϵ-caprolactone)/layered double hydroxide nanocomposites. Journal of Applied Polymer Science, 116 (5), 2658–2667.
  • Ye, X., 2020. Study on compatibility systems and related rheological behaviors in the preparation process of high content SBS modified asphalt (In Chinese). Shanghai: East China University of Science and Technology.
  • Yu, C., et al., 2021. Multi–scale observation of oxidative aging on the enhancement of high–temperature property of SBS–modified asphalt. Construction and Building Materials, 313 (October), 125478.
  • Zhang, Y., et al., 2017. Inverse vulcanization of elemental sulfur and styrene for polymeric cathodes in Li-S batteries. Journal of Polymer Science, Part A: Polymer Chemistry, 55 (1), 107–116.
  • Zhang, Y., et al., 2019. Recent advances in the polymerization of elemental sulphur, inverse vulcanization and methods to obtain functional Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs). Polymer Chemistry, 10 (30), 4078–4105.
  • Zhang, L., and Greenfield, M.L., 2007. Relaxation time, diffusion, and viscosity analysis of model asphalt systems using molecular simulation. The Journal of Chemical Physics, 127 (19), 194502.
  • Zhang, F., and Hu, C., 2013. The research for SBS and SBR compound modified asphalts with polyphosphoric acid and sulfur. Construction and Building Materials, 43, 461–468.
  • Zhang, J., Sakhaeifar, M.S., and Little, D.N., 2022. Characterisation of rheological properties of sulfur-extended asphalt with/without crumb rubber. International Journal of Pavement Engineering, 23 (5), 1491–1499.
  • Zhang, F., Yu, J., and Wu, S., 2010. Effect of ageing on rheological properties of storage-stable SBS/sulfur-modified asphalts. Journal of Hazardous Materials, 182 (1–3), 507–517.
  • Zhou, L., et al., 2021. Analysis of quantification and mechanism of SBS modifier in SBS-modified asphalt. Journal of Materials in Civil Engineering, 33 (7), 1–11.
  • Zhu, J., Birgisson, B., and Kringos, N., 2014. Polymer modification of bitumen: advances and challenges. European Polymer Journal, 54 (1), 18–38.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.