Synthesis of the Diol Epoxide Metabolites of Carcinogenic PAH

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• The proton NMR spectrum of 28 fully agreed with its assignment (300 MHz in DMSO-d6/D2O): δ 4. 75 (d, 1, H3), 4. 84 (d, 1, H4), 6. 46 (dd, 1, H2), 7. 38 (dd, 1, H1), 7. 86–7. 95 (m, 4, H10, 11, 14, 15), 8. 15 (d, 1, H5), 8. 34 (d, 2, H7, 8) 8. 61 (d, 1, H6), 8. 90–9. 07(m, 3, H12, 13, 16); J 1, 2 = 10. 4, J 1, 3 = 1. 7, J 2, 3 = 2. 0, J 3, 4 = 10. 84 Hz
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