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Original Articles

Grain Size Effects in Sensor Response of Nanostructured SnO2- and In2O3-Based Conductometric Thin Film Gas Sensor

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Pages 1-17 | Published online: 29 Apr 2009

REFERENCES

  • Yamazoe , N. , Sakai , G. and Shimanoe , K. 2003 . Oxide semiconductor gas sensors . Catalysis Surv. Asia , 7 : 63
  • Gopel , W. , Hese , J. and Zemel , J. N. , eds. 1991 . Sensors: A, Comprehensive Survey, Chemical and Biochemical Sensors , vol. 2 , Germany : VCH . Part 1
  • Sberveglieri , G. 1995 . Recent developments in semiconducting thin-film gas sensors . Sens. Actuators B Chem. , 23 : 103
  • Madou , M. J. and Morrison , S. R. 1989 . Chemical Sensing with Solid State Devices , San Diego and London : Academic Press, Inc. .
  • Moseley , P. T. and Tofield , B. C. , eds. 1987 . Solid State Gas Sensors , Bristol and Philadelphia : Adam Hilgen .
  • Sberveglieri , G. , ed. 1992 . Gas Sensors , The Netherlands : Kluwer Academic Publishers .
  • Eranna , G. , Joshi , B. C. , Runthala , D. P. and Gupta , R. P. 2004 . Oxide materials for development of integrated gas sensors—A comprehensive review . Critical Rev. Sol. St. Mater. Sci. , 29 : 111
  • Korotcenkov , G. 2007 . Metal oxides for solid state gas sensors. What determines our choice? . Mater. Sci. Eng. B , 139 : 1
  • Korotcenkov , G. 2007 . Practical aspects in design of one-electrode semiconductor gas sensors: Status report . Sens. Actuators B Chem. , 121 : 664
  • Williams , D. E. 1999 . Semiconducting oxides as gas-sensitive resistors . Sensors Actuators B Chem. , 57 : 1
  • Wilson , D. M. , Hoyt , S. , Janata , J. , Booksh , K. and Obando , L. 2001 . Chemical sensors for portable, handheld field instruments . IEEE Sensor J. , 1 : 256
  • Barsan , N. and Weimar , U. 2001 . Conduction model of metal oxide gas sensors . J. Electroceramics , 7 : 143
  • Barsan , N. , Schweizer-Belberich , M. and Gopel , W. 1999 . Fundamental and practical aspects in the design of nanoscaled SnO2 gas sensors: a status report . Fresenius' J. Anal. Chem. , 365 : 287
  • Wang , X. , Yee , S. S. and Carey , W. P. 1995 . Transition between neck-controlled and grain-boundary-controlled sensitivity of metal-oxide gas sensors . Sens. Actuators B Chem. , 25 : 454
  • Rothschild , A. and Komen , Y. 2004 . The effect of grain size on the sensitivity of nanocrystalline metal oxide gas sensors . J. Appl. Phys. , 95 : 6374
  • Xu , C. , Tamaki , J. , Miura , N. and Yamazoe , N. 1991 . Grain size effects on gas sensitivity of porous SnO2-based elements . Sens. Actuators B Chem. , 3 : 147
  • Yamazoe , N. 1991 . New approaches for improving semiconductor gas sensors . Sens. Actuators B Chem. , 5 : 7
  • Gopel , W. and Schierbaum , K. D. 1995 . SnO2 sensors: current status and future prospects . Sens. Actuators B Chem. , 26–27 : 1
  • Chabanis , G. , Parkin , I. P. and Williams , D. E. 2003 . A simple equivalent circuit model to represent microstructure effects on the response of semiconducting oxide-based gas sensors . Meas. Sci. Technol. , 14 : 76
  • Williams , D. E. and Pratt , K. F. E. 2000 . Microstructure effects on the response of gas-sensitive resistors based on semiconducting oxides . Sens. Actuators B Chem. , 70 : 214
  • Ulrich , M. , Bunde , A. and Kohl , C. D. 2004 . Percolation and gas sensitivity in nanocrystalline metal oxide films . Appl. Phys. Lett. , 85 : 242
  • Gas'kov , A. M. and Rumyantseva , M. N. 2001 . Nature of gas sensitivity in nanocrystalline metal oxides . Rus. J. Appl. Chem. , 74 : 440
  • Schierbaum , K. D. , Weimar , U. , Gopel , W. and Kowalkowski , R. 1991 . Conductance, work function and catalytic activity of SnO2-based gas sensors . Sens. Actuators B Chem. , 3 : 205
  • Franke , M. E. , Koplin , T. J. and Simon , U. 2006 . Metal and metal oxide nanoparticles in chemiresistors: does the nanoscale matter? . Small , 2 : 36
  • Williams , D. E. and Pratt , K. F. E. 1998 . Classification of reactive sites on the surface of polycrystalline tin dioxide . J. Chem. Soc. Faraday Trans. , 94 : 3493
  • Sahm , T. , Gurlo , A. , Barsan , N. , Weimar , U. and Madler , L. 2005 . Fundamental studies on SnO2 by means of simultaneous work function change and conduction measurements . Thin Solid Films , 490 : 43
  • Gurlo , A. 2006 . Interplay between O2 and SnO2: Oxygen ionosorption and spectroscopic evidence for adsorbed oxygen . Chem. Phys. Chem. , 7 : 2041
  • Brynzari , V. , Korotchenkov , G. and Dmitriev , S. 2000 . Theoretical study of semiconductor thin film gas sensitivity: Attempt to consistent approach . J. Electron. Technol. , 33 : 225
  • Brinzari , V. , Korotcenkov , G. and Schwank , J. . Optimization of thin film gas sensors for environmental monitoring through theoretical modeling . Chemical Microsensors and Applications, Proceedings of SPIE, vol. 3857 . Edited by: Buettgenbach , S. pp. 186 Bellingham, WA, , USA : SPIE .
  • Sakai , G. , Matsunaga , N. , Shimanoe , K. and Yamazoe , N. 2001 . Theory of gas-diffusion controlled sensitivity for thin film semiconductor gas sensors . Sens. Actuators B Chem. , 80 : 125
  • Matsunaga , N. , Sakai , G. , Shimanoe , K. and Yamazoe , N. 2003 . Formulation of gas diffusion dynamics for thin film semiconductor gas sensor based on simple reaction–diffusion equation . Sens. Actuators B Chem. , 96 : 226
  • Yamazoe , N. and Shimanoe , K. 2008 . Roles of shape and size of component crystals in semiconductor gas sensors: II. Response to NO2 and H2 . J. Electrochem. Soc. , 155 : J93
  • Ding , J. , McAvoy , T. J. , Cavicchi , R. E. and Semancik , S. 2001 . Surface state trapping models for SnO2-based microhotplate sensors . Sens. Actuators B Chem. , 77 : 597
  • Kamp , B. , Merkle , R. and Maier , J. 2001 . Chemical diffusion of oxygen in tin dioxide . Sens. Actuators B Chem. , 77 : 534
  • Chwieroth , B. and Patton , B. R. 2001 . Conduction and gas-surface reaction modeling in metal oxide gas sensors . J. Electroceram. , 6 : 27
  • Rothschild , A. and Komen , Y. 2003 . Numerical computation of chemisorption isoterms for device modeling of semiconductor gas sensors . Sens. Actuators B Chem. , 93 : 362
  • Brynzari , V. , Korotchenkov , G. and Dmitriev , S. 1999 . Simulation of thin film gas sensor kinetics . Sens. Actuators. B Chem. , 61 : 143
  • Kohl , D. 2001 . Function and applications of gas sensors . J. Phys. D: Appl. Phys. , 34 : R125
  • Ogawa , H. , Nishikawa , M. and Abe , A. 1982 . Hall measurement studies and an electrical conduction model of tin oxide ultrafine particle films . J. Appl. Phys. , 53 : 4448
  • Korotcenkov , G. 2005 . Gas response control through structural and chemical modification of metal oxides: State of the art and approaches . Sens. Actuators B Chem. , 107 : 209
  • Brinzari , V. , Korotcenkov , G. and Golovanov , V. 2001 . Factors influencing the gas sensing characteristics of tin dioxide films deposited by spray pyrolysis: understanding and possibilities for control . Thin Solid Films , 391 : 167
  • Kanda , K. and Maekawa , T. 2005 . Development of a WO3 thick-film-based sensors for the detection of VOC . Sens. Actuators B Chem. , 108 : 97
  • Gillet , M. , Aguir , K. , Bendahan , M. and Mennini , P. 2005 . Grain size effect in sputtered tungsten trioxide thin films on the sensitivity to ozone . Thin Solid Films , 484 : 358
  • Tamaki , J. , Zhang , Z. , Fujimori , K. , Akiyama , M. , Harada , T. , Miura , N. and Yamazoe , N. 1994 . Grain-size effects in tungsten oxide-based sensor for nitrogen oxides . J. Electrochem. Soc. , 141 : 2207
  • Yamazoe , N. and Miura , N. 1992 . “ Some basic aspects of semiconductor gas sensors ” . In Chemical Sensors Technology , Edited by: Yamauchi , S. vol. 4 , 20 Tokyo : Kodansha .
  • Suzuki , T. and Yamazaki , T. 1990 . Effect of annealing on the gas sensitivity of thin oxide ultra-thin films . J. Mater. Sci. Lett. , 9 : 750
  • Shimizu , Y. and Egashira , M. 1999 . Basic aspects and challenges of semiconductor gas sensors . MRS Bull. , 24 : 8
  • Ansari , S. G. , Boroojerdian , P. , Sainkar , S. R. , Karekar , R. N. , Aiyer , R. C. and Kulkarni , S. K. 1997 . Grain size effects on H2 gas sensitivity of thick film resistor using SnO2 nanoparticles . Thin Solid Films , 295 : 271
  • Gurlo , A. , Ivanovskaya , M. , Barsan , N. , Schweizer-Berberich , M. , Weimar , U. , Gopel , W. and Dieguez , A. 1997 . Grain size control in nanocrystalline In2O3 semiconductor sensors . Sens. Actuators B Chem. , 44 : 327
  • Gurlo , A. , Barsan , N. , Ivanovskaya , M. , Weimar , U. and Gopel , W. 1998 . In2O3 and MoO3–In2O3 thin film semiconductor sensors: interaction with NO2 and O3 . Sens. Actuators B Chem. , 47 : 92
  • Cha , G. Y. , Baek , W. W. , Lee , S. T. , Lim , J. O. and Huh , J. S. 2004 . Effects of crystal structure and particle size on ethanol; gas sensing characteristics of nanocrystalline ITO thick film . J. Cer. Soc. Jpn. , 112 : 252
  • Hu , Y. , Tan , O. K. , Pan , J. S. , Huang , H. and Cao , W. 2005 . The effects of annealing temperature on the sensing properties of low temperature nano-sized SrTiO3 oxygen gas sensor . Sens. Actuators B Chem. , 108 : 244
  • Mazzone , A. M. and Morandi , V. 2006 . A computational study on CO adsorption onto SnO2 small grains . Sens. Actuators A Phys. , 126 : 56
  • Mandayo , G. G. 2007 . Gas detection by semiconductor ceramics: Tin oxide as improved sensing material . Sensor Letters , 5 : 341
  • Ihokura , K. and Watson , J. 1994 . The Stannic Oxide Gas Sensor: Principles and Applications , Boca Raton, FL : CRC Press .
  • Korotcenkov , G. and Stetter , J. R. 2008 . Comparative study of SnO2- and In2O3-based ozone sensors . ECS Transactions , 6 ( 20 ) : 29
  • Korotcenkov , G. , Cerneavschi , A. , Brinzari , V. , Vasiliev , A. , Cornet , A. , Morante , J. R. , Cabot , A. and Arbiol , J. 2004 . In2O3 films deposited by spray pyrolysis as a material for ozone gas sensors . Sens. Actuators B Chem. , 99 : 304
  • Epifani , M. , Comini , E. , Arbiol , J. , Pellicer , E. , Siciliano , P. , Faglia , G. and Morante , J. R. 2007 . Nanocrystals as very active interfaces: Ultrasensitive room-temperature ozone sensors with In2O3 nanocrystals prepared by a low-temperature sol-gel process in a coordinating environment . J. Phys. Chem. C. , 111 : 13967
  • Golovanov , V. , Pekna , T. , Kiv , A. , Litovchenko , V. , Korotcenkov , G. , Brinzari , V. , Cornet , A. and Morante , J. R. 2005 . The influence of structural factors on sensitivity of SnO2-based gas sensors to CO in humid atmosphere . Ukr. Phys. J. , 50 : 374
  • Golovanov , V. , Maki-Jaskari , M. A. , Rantala , T. T. , Korotcenkov , G. , Brinzari , V. , Cornet , A. and Morante , J. R. 2005 . Experimental and theoretical studies of the indium oxide-based gas sensors deposited by spray pyrolysis . Sens. Actuators B Chem. , 106 : 563
  • Korotchenkov , G. , Brynzari , V. and Dmitriev , S. . Kinetics characteristics of SnO2 thin film gas sensors for environmental monitoring . Chemical Microsensors and Applications, Proceedings of SPIE . Edited by: Buettgenbach , S. vol. 3539 , pp. 196 Bellingham, WA, , USA : SPIE .
  • Korotcenkov , G. , Brinzari , V. , Golovanov , V. and Blinov , Y. 2004 . Kinetics of gas response to reducing gases of SnO2 films deposited by spray pyrolysis . Sens. Actuators B Chem. , 98 : 41
  • Korotcenkov , G. , Brinzari , V. , Stetter , J. R. , Blinov , I. and Blaja , V. 2007 . The nature of processes controlling the kinetics of indium oxide-based thin film gas sensor response . Sens. Actuators B Chem. , 128 : 51
  • Korotcenkov , G. , Ivanov , M. , Blinov , I. and Stetter , J. R. 2007 . Kinetics of In2O3-based thin film gas sensor response: The role of “redox” and adsorption/desorption processes in gas sensing effects . Thin Solid Films , 515 : 3987
  • Korotcenkov , G. , Blinov , I. , Brinzari , V. and Stetter , J. R. 2007 . Effect of air humidity on gas response of SnO2 thin film ozone sensors . Sens. Actuators B Chem. , 122 : 519
  • Korotcenkov , G. , Boris , I. , Cornet , A. , Rodriguez , I. , Cirera , A. , Golovanov , V. , Lychkovsky , Yu. and Karkotsky , G. 2007 . Influence of additives on gas sensing and structural properties of In2O3-based ceramics . Sens. Actuators B Chem. , 120 : 657
  • Korotcenkov , G. , Blinov , I. , Ivanov , M. and Stetter , J. R. 2007 . Ozone sensors on the base of SnO2 thin films deposited by spray pyrolysis . Sens. Actuators B Chem. , 120 : 679
  • Korotcenkov , G. , Brinzari , V. , Cerneavschi , A. , Ivanov , M. , Cornet , A. , Morante , J. R. , Cabot , A. and Arbiol , J. 2004 . In2O3 films deposited by spray pyrolysis: gas response to reducing (CO, H2) gases . Sens. Actuators B Chem. , 98 : 122
  • Korotcenkov , G. , Brinzari , V. , Ivanov , M. , Cerneavschi , A. , Rodriguez , J. , Cirera , A. , Cornet , A. and Morante , J. R. 2005 . Structural stability of In2O3 films deposited by spray pyrolysis during thermal annealing . Thin Solid Films , 479 : 38
  • Korotcenkov , G. , Cornet , A. , Rossinyol , E. , Arbiol , J. , Brinzari , V. and Blinov , Y. 2005 . Faceting characterization of SnO2 nanocrystals deposited by spray pyrolysis from SnCl4-5H2O water solution . Thin Solid Films , 471 : 310
  • Korotcenkov , G. , Brinzari , V. , Cerneavschi , A. , Ivanov , M. , Golovanov , V. , Cornet , A. , Morante , J. R. , Cabot , A. and Arbiol , J. 2004 . The influence of film structure on In2O3 gas response . Thin Solid Films , 460 : 315
  • Korotcenkov , G. , Macsanov , V. , Tolstoy , V. , Brinzari , V. , Schwank , J. and Faglia , G. 2003 . Structural and gas response characterization of nano-size SnO2 films deposited by SILD method . Sens. Actuators B Chem. , 96 : 602
  • Brinzari , V. , Korotcenkov , G. , Schwank , J. , Lantto , V. , Saukko , S. and Golovanov , V. 2002 . Morphological rank of nano-scale tin dioxide films deposited by spray pyrolysis from SnCl4· 5H2O water solution . Thin Solid Films , 408 : 51
  • Korotcenkov , G. , DiBattista , M. , Schwank , J. and Brinzari , V. 2000 . Structural characterization of SnO2 gas sensing films deposited by spray pyrolysis . J. Mater. Sci. Eng., B , 77 : 3
  • Rumyantseva , M. N. , Kovalenko , V. V. , Gaskov , A. M. , Pagnier , T. , Machon , D. , Arbiol , J. and Morante , J. R. 2005 . Nanocomposites SnO2/Fe2O3: Wet chemical synthesis and nanostructure characterization . Sens. Actuators B Chem. , 109 : 64
  • Korotcenkov , G. , Brinzari , V. , Schwank , J. and Cerneavschi , A. 2001 . Possibilities of aerosol technology for deposition of SnO2-based films with improved gas sensing characteristics . J. Mater. Sci. Eng. C , 19 : 73
  • Palatnik , L. S. , Fuks , M. I. and Kosevich , V. M. 1972 . Mechanism of Formation and Substructure of Condensed Films , Moscow : Nauka . (in Russian)
  • Korotcenkov , G. , Brinzari , V. , DiBattista , M. , Schwank , J. and Vasiliev , A. 2001 . Peculiarities of SnO2 thin film deposition by spray pyrolysis for gas sensor application . Sens. Actuators B Chem. , 77 : 244
  • Bender , M. , Gagaoudakis , E. , Douloufakis , E. , Natsakou , E. , Katsarakis , N. , Cimalla , V. , Kiriakidis , G. , Fortunato , E. , Nunes , P. , Marques , A. and Martins , R. 2002 . Production and characterization of zinc oxide thin films for room temperature ozone sensing . Thin Solid Films , 418 : 45
  • Kiriakidis , G. , Suchea , M. , Christoulakis , S. , Horvath , P. , Kitsopoulos , T. and Stoemenos , J. 2007 . Structural characterization of ZnO thin films deposited by dc magnetron sputtering . Thin Solid Films , 515 : 8577
  • Suchea , M. , Katsarakis , N. , Christoulakis , S. , Nikolopoulou , S. and Kiriakidis , G. 2006 . Low temperature indium oxide gas sensors . Sens. Actuators B Chem. , 118 : 135
  • Dolbec , R. , El Khakani , M. A. , Serventi , A. M. and Saint-Jacques , R. G. 2003 . Influence of the nanostructural characteristics on the gas sensing properties of pulsed laser deposited tin oxide thin films . Sens. Actuators B Chem. , 93 : 566
  • Huang , H. , Tan , O. K. , Lee , Y. C. and Tse , M. S. 2006 . Preparation and characterization of nanocrystalline SnO2 thin films by PECVD . J. Crystal Growth , 288 : 70
  • Vuong , D. D. , Sakai , G. , Shimanoe , K. and Yamazoe , N. 2004 . Preparation of grain size-controlled tin oxide sols by hydrothermal treatment for thin film sensor application . Sens. Actuators B Chem. , 103 : 386
  • Rumyantseva , M. N. , Gaskov , A. M. , Rosman , N. , Pagnier , T. and Morante , J. R. 2005 . Raman surface vibration modes in nanocrystalline SnO2: Correlation with gas sensor performances . Chem. Mater. , 17 : 893
  • Risti , M. , Ivanda , M. , Popovi , S. and Musi , S. 2002 . Dependence of nanocrystalline SnO2 particle size on synthesis route . J. Non-Crystalline Solids , 303 : 270
  • Amjoud , M. , Rhouta , B. , Alimoussa , A. , Hajji , L. , Mezzane , D. and Ahamdane , H. 2005 . Effect of pH adjustment in sol-gel synthesis route on grain size of tin dioxide intended for gas sensors application . Phys. Chem. News , 22 : 120
  • Dieguez , A. , Romano-Rodrıguez , A. , Alay , J. L. , Morante , J. R. , Barsan , N. , Kappler , J. , Weimar , U. and Gopel , W. 2000 . Parameter optimisation in SnO2 gas sensors for NO2 detection with low cross-sensitivity to CO: sol–gel preparation, film preparation, powder calcination, doping and grinding . Sens. Actuators B Chem. , 65 : 166
  • Gillet , M. , Aguir , K. , Bendahan , M. and Mennini , P. 2005 . Grain size effect in sputtered tungsten trioxide thin films on the sensitivity to ozone . Thin Solid Films , 484 : 358
  • Vallejos , S. , Khatko , V. , Calderer , J. , Gracia , I. , Cane , C. , Llobet , E. and Correig , X. 2008 . Micro-machined WO3-based sensors selective to oxidizing gases . Sens. Actuators B Chem. , 132 : 209
  • Vallejos , S. , Khatko , V. , Aguir , K. , Ngo , K. A. , Calderer , J. , Gracia , I. , Cane , C. , Llobet , E. and Correig , X. 2007 . Ozone monitoring by micro-machined sensors with WO3 sensing films . Sens. Actuators B Chem. , 126 : 573
  • Liao , L. , Lu , H. B. , Li , J. C. , He , H. , Wang , D. F. , Fu , D. F. , Liu , C. and Zhang , W. F. 2007 . Size dependence of gas sensitivity of ZnO nanorods . J. Phys. Chem. C , 111 : 1900
  • Brinzari , V. , Korotcenkov , G. and Matolin , V. 2005 . Synchrotron radiation photoemission study of indium oxide surface prepared by pyrolysis method . Appl. Surf. Sci. , 243 : 335
  • Serrini , P. , Briois , V. , Horrillo , M. C. , Traverse , A. and Manes , L. 1997 . Chemical composition and crystalline structure of SnO2 thin films used as gas sensors . Thin Solid Films , 304 : 113
  • Vuong , D. D. , Sakai , G. , Shimanoe , K. and Yamazoe , N. 2005 . Hydrogen sulfide gas sensing properties of thin films derived from SnO2 sols different in grain size . Sens. Actuators B Chem. , 105 : 437
  • Choe , Y. S. 2001 . New gas sensing mechanism for SnO2 thin film gas sensors fabricated by using dual ion beam sputtering . Sens. Actuators B Chem. , 77 : 200
  • Tiemann , M. 2007 . Porous metal oxides as gas sensors . Chem. Eur. J. , 13 : 8376
  • Dieguez , A. , Romano-Rodriguez , A. , Morante , J. R. , Kappler , J. , Barsan , N. and Gopel , W. 1999 . Nanoparticle engineering for gas sensor optimisation: improved sol–gel fabricated nanocrystalline SnO2 thick film gas sensor for NO2 detection by calcination, catalytic metal introduction and grinding treatments . Sens. Actuators B Chem. , 60 : 125
  • Shen , Y. , Yamazaki , T. , Liu , Z. , Jin , C. , Kikuta , T. and Nakatani , N. 2008 . Porous SnO2 sputtered films with high H2 sensitivity at low operation temperature . Thin Solid Films , 516 : 5111
  • Liu , Z. , Yamazaki , T. , Shen , Y. , Kikuta , T. and Nakatani , N. 2007 . Influence of annealing on microstructure and NO2-sensing properties of sputtered WO3 thin films . Sens. Actuators B Chem. , 128 : 173
  • Sergent , N. , Gelin , P. , Perier-Camby , L. , Praliaud , H. and Thomas , G. 2002 . Preparation and characterisation of high surface area stannic oxides: structural, textural and semiconducting properties . Sens. Actuators B Chem. , 84 : 176
  • Kaye , B. H. 1989 . A Random Walk Through Fractal Dimensions , Weinheim : VCH Verlagsgesellschaft .
  • De Souza Brito , G. E. , Santilli , C. V. and Pulcenelli , S. H. 1995 . Evolution of the fractal structural during sintering of SnO2 compacted sol-gel powders . Coloids Surf. A , 97 : 217
  • Lucas , E. , Decker , S. , Khaleel , A. , Seitz , A. , Fultz , S. , Ponce , A. , Li , W. , Carnes , C. and Klabunde , K. 2001 . Nanocrystalline metal oxides as uniquie chemical reagent/sorbents . Chem. Eur. J. , 7 : 2505
  • Uvarov , N. F. and Boldyrev , V. V. 2001 . Size effects in chemistry of heterogeneous systems . Rus. Chem. Rev. , 70 : 265
  • Maffeıs , T. G. G. , Owen , G. Y. , Malag , C. , Martinelli , G. , Kennedy , M. K. , Kruis , F. E. and Wilks , S. P. 2004 . Direct evidence of the dependence of surface state density on the size of SnO2 nanoparticles observed by scanning tunneling spectroscopy . Surf. Sci. , 550 : 21
  • Zhangyk , H. , Liuy , Y. , Zhuy , K. , Siuz , G. , Xiong , Y. and Xiong , C. 1998 . Fourier transform infrared characterization of nanometer SnO2 . J. Phys.: Condens. Matter , 10 : 11121
  • Yu , B. , Guo , L. , Yang , Z. , Zhu , C. , Gan , F. , Zhang , G. , Tang , G. , Wu , X. and Chen , W. 1999 . The infrared vibration characteristics of SnO2 nanoparticles . Phys. Lett. A , 251 : 67
  • Dieguez , A. , Romano-Rodriguez , A. , Vila , A. and Morante , J. R. 2001 . The complete Raman spectrum of nanometric SnO2 particles . J. Appl. Phys. , 90 : 1550
  • Rao , C. N. R. , Kulkarni , G. U. , Thomas , P. J. and Edwards , P. P. 2002 . Size-dependent chemistry: properties of nanocrystals . Chem. Euro. J. , 8 : 28
  • Hermanek , M. , Zboril , R. , Medrik , I. , Pechousek , J. and Gregor , C. 2007 . Catalytic Efficiency of Iron(III) Oxides in Decomposition of Hydrogen Peroxide: Competition between the Surface Area and Crystallinity of Nanoparticles . J. Am. Chem. Soc. , 129 : 10929
  • Chang , J. F. , Kuo , H. H. , Leu , I. C. and Hon , M. H. 2002 . The effects of thickness and operation temperature on ZnO:Al thin film CO gas sensor . Sens. Actuators B Chem. , 84 : 258
  • Williams , D. E. and Pratt , K. F. E. 1995 . Theory of self-diagnostic sensor array devices using gas-sensitive resistors . J. Chem. Soc., Faraday Trans. , 91 : 1961
  • Berger , J. , Riess , I. and Tannhauser , D. S. 1985 . Dynamic measurement of oxygen diffusion in indium-tin oxide . Sol. St. Ionics , 15 : 225
  • Wirtz , G. P. and Takiar , H. P. 1981 . Oxygen diffusion in vapor-deposited indium oxide films . J. Am. Ceram. Soc. , 64 : 748
  • Liess , M. 2002 . Electric-field-induced migration of chemisorbed gas molecules on a sensitive film- a new chemical sensors . Thin Solid Films , 410 : 183
  • Ikuma , Y. and Murekami , T. 1996 . Oxygen tracer diffusion in polycrystalline In2O3 . J. Electrochem. Soc. Inc. , 143 : 2698
  • Aliwell , S. R. , Halsall , J. F. , Pratt , K. F. E. , Sullivan , J. O. , Jones , R. L. , Cox , R. A. , Utembe , S. R. , Hansford , G. M. and Williams , D. E. 2001 . Ozone sensors based on WO3: a model for sensors drift and a measurement correction method . Meas. Sci. Technol. , 12 : 684
  • Izu , N. , Shin , W. and Murayama , N. 2003 . Fast response of resistive-type oxygen gas sensors based on nano-sized ceria powder . Sens. Actuators B Chem. , 93 : 449
  • Izu , N. , Shin , W. , Matsubara , I. and Murayama , N. 2003 . The effects of the particle size and crystallite size on the response time for resistive oxygen gas sensor using cerium oxide thick film . Sens. Actuators B Chem. , 94 : 222
  • Kennedy , M. K. , Kruis , F. E. , Fissan , H. , Mehta , B. R. , Stappert , S. and Dumpich , G. 2003 . Tailored nanoparticle films from monosized tin oxide nanocrystals: Particle synthesis, film formation, and size-dependent gas-sensing properties . J. App. Phys. , 93 : 551
  • Thompson , C. V. 2000 . Structure evolution during processing of polycrystalline films . Ann. Rev. Mater. Sci. , 30 : 159
  • Mazzone , A. M. 2002 . A quantum mechanical study of the stability of SnO2 nanocrystalline grains . J. Phys.: Cond. Matter , 14 : 12819
  • Sun , C. Q. 2007 . Size dependence of nanostructures: Impact of bond order deficiency . Prog. Sol. St. Chem. , 35 : 1
  • Goldstein , N. , Echer , C. M. and Alivistos , A. P. 1992 . Melting in semiconductor nanocrystals . Science , 256 : 1425
  • Zhang , Z. , Li , Z. C. and Jiang , Q. 2000 . Modelling for size-dependent and dimension-dependent melting of nanocrystals . J. Phys. D.: Appl. Phys. , 33 : 2653
  • Ouyang , G. , Li , X. L. , Tan , X. and Yang , G. W. 2008 . Surface energy of nanowires . Nanotechnology , 19 : 045709
  • Guisbiers , G. and Pereira , S. 2007 . Theoretical investigation of size and shape effects on the melting temperature of ZnO nanostructures . Nanotechnology , 18 : 435710
  • Atkinson , H. V. and Duffy , D. M. 1986 . Calculation of activation energies for defect movement during coincidence boundary migration in nickel oxide using computer simulation techniques . Acta Metallurgica , 34 : 2371
  • Duffy , D. M. , Hoare , J. P. and Tasker , P. W. 1984 . Vacancy formation energies near the surface of an ionic crystal . J. Phys. C.: Sol. St. Phys. , 17 : L195
  • Aggarwal , S. and Ramesh , R. 1998 . Point defects chemistry of metal oxide heterostructures . Ann. Rev. Mater. Sci. , 28 : 463
  • Leite , E. R. , Weber , I. T. , Longo , E. and Varela , J. A. 2000 . A new method to control particle size and particle size distribution of SnO2 nanoparticles for gas sensor applications . Adv. Mater. , 12 : 965
  • Baik , N. S. , Sakai , G. , Shimanoe , K. , Miura , N. and Yamazoe , N. 2000 . Hydrothermal treatment of tin oxide sol solution for preparation of thin-film sensor with enhanced thermal stability and gas sensitivity . Sens. Actuators B Chem. , 65 : 97
  • Adamyan , A. Z. , Adamian , Z. N. and Aroutiounian , V. M. 2003 . Preparation of SnO2 films with thermally stable nanoparticles . Sensors , 3 : 438
  • Kersen , U. and Sundberg , M. R. 2003 . The reactive surface sites and the H2S sensing potential for the SnO2 produced by a mechanochemical milling . J. Electrochem. Soc. , 150 : H129
  • Baik , N. S. , Sakai , G. , Miura , N. and Yamazoe , N. 2000 . Preparation of stabilized nanosized tin oxide particles by hydrothermal treatment . J. American Cer. Soc. , 83 : 2983
  • Comini , E. , Faglia , G. , Sberveglieri , G. , Pan , Z. W. and Wang , Z. L. 2002 . Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts . Appl. Phys. Lett. , 81 : 1869
  • Kolmakov , A. and Moskovits , M. 2004 . Chemical sensing and catalysis by one-dimensional metal-oxide nanostructures . Annu. Rev. Mater. Res. , 34 : 151
  • Sberveglieri , G. , Baratto , C. , Comini , E. , Faglia , G. , Ferroni , M. , Ponzoni , A. and Vomiero , A. 2007 . Synthesis and characterization of semiconducting nanowires for gas sensing . Sens. Actuators B Chem. , 121 : 208
  • Korotcenkov , G. , Brinzari , V. and Boris , I. 2008 . (Cu, Fe, Co or Ni)-doped SnO2 films deposited by spray pyrolysis: Doping influence on film morphology . J. Mater. Sci. , 43 : 2761
  • Morimoto , T. , Nagao , M. and Tokuda , F. 1969 . The relation between the amounts of chemisorbed and physisorbed water on metal oxides . J. Phys. Chem. , 73 : 243
  • Traversa , E. 1995 . Ceramic sensors for humidity detection: the state-of-the-art and future developments . Sens. Actuators B Chem. , 23 : 135
  • Takeda , S. and Fukawa , M. 2005 . Role of surface OH groups in surface chemical properties of metal oxide films . Mater. Sci. Eng. B , 119 : 265
  • Barsan , N. and Weimar , U. 2003 . Understanding the fundamental principles of metal oxide based gas sensors; the example of CO sensing with SnO2 sensors in the presence of humidity . J. Phys.: Condens. Matter , 15 : R813
  • Yamazoe , N. , Fuchigami , J. , Kishikawa , M. and Seiyama , T. 1979 . Interactions of tin oxide surfaces with O2, H2O and H2 . Surf. Sci. , 86 : 335
  • Williams , G. and Coles , G. S. V. 1998 . Gas sensing properties of nanocrystalline metal oxide powders produced by a laser evaporation technique . J. Mater. Chem. , 8 : 1657
  • Batzill , M. , Katsiev , K. , Burst , J. M. , Diebold , U. , Chaka , A. M. and Delley , B. 2005 . Gas-phase-dependent properties of SnO2 (110), (100), and (101) single-crystal surfaces: Structure, composition, and electronic properties . Phys. Rev. B , 72 : 165414
  • Batzill , M. , Bergermayer , W. , Tanaka , I. and Diebolda , U. 2006 . Tuning the chemical functionality of a gas sensitive material: Water adsorption on SnO2(101) . Surf. Sci. , 600 : L29
  • Emiroglu , S. , Barsan , N. , Weimar , U. and Hoffmann , V. 2001 . In-situ diffuse reflectance infrared spectroscopy study of CO adsorption on SnO2 . Thin Solid Films , 391 : 176
  • Michel , H. J. , Leiste , H. , Schierbaum , K. D. and Halbritter , J. 1998 . Adsorbates and their effects on gas sensing properties of sputtered SnO2 films . Appl. Surf. Sci. , 126 : 57
  • De Souza Brito , G. E. , Santilli , C. V. and Pulcenelli , S. H. 1995 . Evolution of the fractal structure during sintering of SnO2 compacted sol-gel powder . Coloids Surf. A , 97 : 217
  • Barsan , N. , Koziej , D. and Weimar , U. 2007 . Metal oxide-based gas sensor research: How to? . Sens. Actuators B Chem. , 121 : 18
  • Gurlo , A. and Riedel , R. 2007 . In situ and operando spectroscopy for assessing mechanisms of gas sensing . Angewandte Chemie – Int. Ed. , 46 : 3826
  • Abe , S. , Choi , U. S. , Shimanoe , K. and Yamazoe , N. 2005 . Influences of ball-milling time on gas-sensing properties of Co3O4–SnO2 composites . Sens. Actuators B Chem. , 107 : 516

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