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Original Articles

THREE-, FOUR-, AND FIVE-COORDINATE CYCLIC PHOSPHITES, PHOSPHONATES, AND PHOSPHONIUM SALTS CONTAINING SULFURYL GROUP

, , , , &
Pages 1-27 | Received 23 Sep 1999, Accepted 25 Oct 1999, Published online: 04 Oct 2006

References

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  • Chandrasekaran , A. , Sood , P. , Day , R. O. and Holmes , R. R. 1999 . Inorg. Chem. , 38 : 3952
  • Timosheva , N. V. , Chandrasekaran , A. , Day , R. O. and Holmes , R. R. 1998 . Inorg. Chem. , 37 : 4945
  • Timosheva , N. V. , Chandrasekaran , A. , Day , R. O. and Holmes , R. R. 1998 . Inorg. Chem. , 37 : 3862
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  • Holmes , R. R. 1999 . Phosphorus, Sulfur, and Silicon , 144–146 : 1
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  • Holmes , R. R. 1980 . “Pentacoordinated Phosphorus - Reaction Mechanisms,” , ACS Monograph 176 Volume II , 237 Washington, D.C. : American Chemical Society .
  • Chandrasekaran , A. , Day , R. O. and Holmes , R. R. 1996 . Organometallics , 15 : 3189
  • Kolodiazhnyi , O. I. and Golovatyi , O. R. 1995 . Phosphorus, Sulfur, and Silicon , 102 : 133
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  • Holmes , R. R. and Deiters , J. A. 1977 . J. Am. Chem. Soc. , 99 : 3318 See reference 17. In this method, the displacement of the phosphorus atom from the mean plane of the four basal ligands is calculated. This distance is 0.43 Å for a regular square pyramid for main group elements based on trans basal angles of 150°. See
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  • Huheey , J. E. , Keiter , E. A. and Keiter , R. L. 1993 . Inorganic Chemistry, , 4th ed. , Harper Collins College Publishers . Appendix E, Table E-I
  • Sutton , L. , ed. 1958 . Tables of Interatomic Distances and Configuration in Molecules and Ions , London : The Chemical Society . 1965, Special Publication Nos. 11 and 18, The displacement toward a TBP is calculated simply by noting how far the P-OSO distance is displaced from the sum of the van der Waals' radii (3.35Å)30 toward the sum of the covalent radii (1.83 Å). See
  • Harper , S. D. and Arduengo , A. J. 1982 . J. Am. Chem. Soc. , 104 : 2497

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