A Kinetic View of the Mechanism of the Grignard Reaction with Alkoxysilanes

REFERENCES

• Arkles, B. In: Silverman, G.S.; Rakita P.E. ( Eds.), . Grignard Reagents and Silanes, pp. 667-675, Handbook of Grignard Reagents; Marcel Dekker: New York, 1996.
   Google Scholar
• Brook, M.A. Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley: New York, 2000.
   Google Scholar
• Reid, A.F.; Wilkins, C.J. J. Chem. Soc. 1955, 4029-4034.
   Web of Science ®Google Scholar
• Corriu, R.J. P.; Henner, B. J. Organomet. Chem. 1975, 102, 407-563.
   Web of Science ®Google Scholar
• Tuulmets, A.; Hõrak, M.; Kõopere, T.; Ruotsi, J. Org. React. (USSR)1982, 19, 102-119.
   Google Scholar
• Sassian, M.; Panov, D.; Tuulmets, A. Appl. Organomet. Chem. 2002, 16, 525-529.
   Web of Science ®Google Scholar
• Tuulmets, A.; Panov, D.; Sassian, M. Tetrahedron Lett. 2003, 44, 3943-3945.
   Web of Science ®Google Scholar
• Tuulmets, A.; Nguyen, B.T.; Panov, D.; Sassian, M.; Järv, J. J. Org. Chem. 2003, 68, 9933-9937.
   PubMed Web of Science ®Google Scholar
• Tuulmets, A.; Nguyen, B.T.; Panov, D. J. Org. Chem. 2004, 69, 5071-5076.
   PubMed Web of Science ®Google Scholar
• Panov, D.; Tuulmets, A.; Nguyen, B.T. J. Organomet. Chem. 2006, 691, 4076-4079.
   Web of Science ®Google Scholar
• Panov, D.; Ploom, A.; Tuulmets, A. Phosphorus, Sulfur, and Silicon 2006, 181, 2807-2816.
   Web of Science ®Google Scholar
• Golubev, O.; Panov, D.; Ploom, A.; Tuulmets, A.; Nguyen, B.T. J. Organomet. Chem. 2007, 692, 3700-3705.
   Web of Science ®Google Scholar
• Ploom, A.; Panov, D.; Järv, J.; Tuulmets, A. J. Organomet. Chem. 2008, 693, 2351-2354.
   Web of Science ®Google Scholar
• Ploom, A.; Tuulmets, A.; Järv, J. Phosphorus, Sulfur, and Silicon 2010, 185, 2503-2510.
   Web of Science ®Google Scholar
• Walker, F.W.; Ashby, E.C. J. Am. Chem. Soc. 1969, 91, 3845-3850.
   Web of Science ®Google Scholar
• Bassindale, A.R.; Taylor, P.G. Reaction mechanisms of nucleophilic attack at silicon, pp. 839-892, In: Patai, S.; Rappoport Z. (Eds.), The Chemistry of Organic Silicon Compounds; Wiley: Chichester, 1989, . Part 1, Chapter 13.
   Google Scholar
• Bassindale, A.R.; Glynn, S.J.; Taylor, P.G. Reaction mechanisms of nucleophilic attack at silicon, pp. 495-511, In: Rappoport, Z.; Apeloig Y. (Eds.), The Chemistry of Organic Silicon Compounds; Wiley: Chichester, 1998, vol. 190, . Chapter 9.
   Google Scholar
• Sommer, L.H. Stereochemistry, Mechanism and Silicon; McGraw: New York, 1965.
   Google Scholar
• Corriu, R.J. P.; Guérin, C.; Moreau, J.J. E. Dynamic stereochemistry at silicon, pp. 305-370, In: Patai, S.; Rappoport Z. (Eds.), The Chemistry of Organic Silicon Compounds; Wiley: Chichester, 1989, . Part 1, Chapter 4.
   Google Scholar
• Holmes, R.R. Chem. Rev. 1990, 90, 17-31.
   Web of Science ®Google Scholar
• Williams, A. Free Energy Relationships in Organic and Bio-organic Chemistry, RSC: Cambridge, 2003.
   Google Scholar
• The scale Es(Si) was first proposed by Cartledge23 and further revised and complemented in.24,25
   Google Scholar
• Cartledge, F.K. Organometallics 1983, 2, 425-430.
   Web of Science ®Google Scholar
• Ploom, A.; Panov, D.; Tuulmets, A. ARKIVOC 2006, 5, 37-42.
   Google Scholar
• Ploom, A.; Tuulmets, A. J. Organomet. Chem. 2009, 694, 313-315.
   Web of Science ®Google Scholar
• Ploom, A.; Tuulmets, A.; Järv, J. Cent. Eur. J. Chem. 2011, 9, 910-916.
   Web of Science ®Google Scholar
• Tuulmets, A.; Ploom, A.; Panov, D.; Järv, J. Synlett 2010, 2, 291-293.
   Web of Science ®Google Scholar
• Mori, T.; Kato, S. J. Phys. Chem. A 2009, 113, 6158-6165.
   PubMed Web of Science ®Google Scholar
• Blomberg, C. Mechanisms of Reactions in Grignard Reagents, pp 219-248, In: Silverman, G.S.; Rakita P.E. (Eds), Handbook of Grignard Reagents; Marcel Dekker: New York, 1996, . Chapter 11.
   Google Scholar
• Holm, T.; Crossland, J. Mechanistic Features of the Reactions of Organomagnesium Compounds, pp. 1-26, In: Richey, H.G. Jr. (Ed.), Grignard Reagents: New Developments; Wiley: New York, 2000, . Chapter 1.
   Google Scholar
• Lindsell, W.E. In: Wilkinson G. (Ed.), vol. 190, Comprehensive Organometallic Chemistry II; Pergamon Press: New York, 1995, Chapter 3.
   Google Scholar
• Eaborn, C. Organosilicon Compounds, Butterworths: London, 1960.
   Google Scholar
• Wakefield, B.J. Organomagnesium Methods in Organic Synthesis; Academic Press: New York, 1995.
   Google Scholar