273
Views
6
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis and properties of stable alumoles

, , &
Pages 584-587 | Received 02 Dec 2015, Accepted 02 Dec 2015, Published online: 06 Apr 2016

References

  • (a)Yamaguchi, S.; Wakamiya, A. Pure Appl. Chem. 2006, 78, 1413-1424. (b)Braunschweig, H.; Kupfer, T. Chem. Commun. 2011, 47, 10903-10914.
  • (a) Mes*-substituted gallole and indacyclopentadiene: Cowley, A. H.; Gabbaï, F. P.; Decken, A. Angew. Chem., Int. Ed. Engl. 1994, 33, 1370-1372. (b) Synthesis and crystal structure of a pentaalkylgallole derivative: Cowley, A. H.; Brown, D. S.; Decken, A.; Kamepalli, S. Chem. Commun. 1996, 2425-2426.
  • Lewis base complexes of gallole derivatives: (a)Matsumoto, T.; Tanaka, K.; Chujo, Y. J. Am. Chem. Soc. 2013, 135, 4211-4214. (b)Saito, M.; Akiba, T.; Kaneko, M.; Kawamura, T.; Abe, M.; Hada, M.; Minoura, M.Chem. Eur. J. 2013, 19, 16946-16953. (c)Wei, P.; Li, X.-W.; Robinson, G. H. Chem. Commun. 1999, 1287-1288. (d)Clyburne, J. A. C.; Culp, R. D.; Kamepalli, S.; Cowley, A. H.; Decken, A. Inorg. Chem. 1996, 35, 6651-6655. (e)Fagan, P. J.; Nugent, W. A.; Calabrese, J. C. J. Am. Chem. Soc. 1994, 116, 1880-1889.
  • (a)D'yakonov, V. A.; Tuktarova, R. A.; Dzhemilev, U. M. Russ. Chem. Bull. 2011, 60, 1633-1639. (b)Xi, Z.; Li, P. Angew. Chem. Int. Ed. 2000, 39, 2950-2952. (c)Eisch, J. J.; Kaska, W. C. J. Am. Chem. Soc. 1966, 88, 2976-2983. (d)Eisch, J. J.; Harrell, R. L. Jr. J. Organomet. Chem. 1969, 20, 257-260.
  • Et2o complexes of pentaphenylalumole were synthesized and structurally characterized. (a)Hoberg, H.; Kraus-Göing, R. J. Organomet. Chem. 1977, 127, C29-C31. (b)Krüger, C.; Sekutowski, J. C.; Hoberg, H.; Kause-Göing, R. J. Organomet. Chem. 1977, 141, 141-148. (c)Hoberg, H.; Richter, W. J. Organomet. Chem. 1980, 195, 347-353.
  • Agou, T.; Wasano, T; Jin, P.; Nagase, S.; Tokitoh, N. Angew. Chem. Int. Ed. 2013, 52, 10031-10034.
  • Wasano, T.; Agou, T.; Sasamori, T.; Tokitoh, N. Chem. Commun. 2014, 50, 8148-8150.
  • Liu, L.; Zhang, W.-X.; Luo, Q.; Li, H.; Xi, Z. Organometallics 2010, 29, 278-281.
  • Wehmschulte, R. J.; Power, P. P. Inorg. Chem. 1996, 35, 3262-3267.
  • (a)Schulz, S.; Pusch, S.; Pohl, E.; Dielkus, S.; Herbst-Irmer, R.; Meller, A.; Roesky, H. W. Inorg. Chem. 1993, 32, 3343-3346. (b)Petrie, M. A.; Power, P. P.; Rasika Dias, H.V.; Ruhlandt-Senge, K.; Waggoner, K. M.; Wehmschulte, R. J. Organometallics 1993, 12, 1086–1093.
  • Agou, T.; Wasano, T.; Sasamori, T.; Tokitoh, N. J. Phys. Org. Chem. 2015, 28, 104-107.
  • Crystallographic data for 1-chloroalumole 6: Empirical formula C24H40Al2Cl2, FW 453.42, monoclinic, space group P21/n, a = 9.037(1) Å, b = 15.8043(1) Å, c = 18.6295(1) Å, β = 100.3693(3)º, V = 2617.05(2) Å3, ρ = 1.151 g cm‑3, Z = 4, μ = 0.323 mm− 1, 1.70 ≤ θ≤ 25.50, reflections collected 70459, independent reflections 4608 Rint = 0.0524), completeness to θ(25.24º) = 99.7%, GOF on F2 = 1.028, R1 [I > 2σ(I)] = 0.0301, wR2 (all data) = 0.0836, largest difference peak and hole 0.301 and –0.340 e Å− 3. CCDC-1417355.
  • Crystallographic data for IPr-complex 9: Empirical formula C39H56AlBrN2, FW 659.74, monoclinic, space group P21/n, a = 10.6985(2) Å, b = 16.9795(3) Å, c = 20.8014(4) Å, β = 90.4499(10)º, V = 3778.57(12) Å3, ρ = 1.160 g cm‑3, Z = 4, μ = 1.138 mm− 1, 1.55 ≤ θ≤ 25.50, reflections collected 40426, independent reflections 6928 Rint = 0.0545), completeness to θ(25.24º) = 99.0%, GOF on F2 = 1.025, R1 [I > 2σ(I)] = 0.0367, wR2 (all data) = 0.0965, largest difference peak and hole 0.546 and –0.474 e Å− 3. CCDC-1417291.
  • Agou, T.; Wasano, T.; Sasamori, T.; Tokitoh, N. Organometallics 2014, 33, 6963-6966.
  • Agou, T.; Wasano, T.; Sasamori, T.; Guo, J.-D.; Nagase, S.; Tokitoh, N. Angew. Chem. Int. Ed. 2015, 54, 9568-9571.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.