Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH₂CH₂NMeH)₂(H₂O)₂][B₅O₆(OH)₄]₂^.2B(OH)₃

References

• Beckett, M. A. Recent Advances in Crystalline Hydrated Borates with Non-Metal or Transition-Metal Cations. Coord. Chem. Rev. 2016, 323, 2–14. DOI: 10.1016/j.ccr.2015.12.012.
   Web of Science ®Google Scholar
• Wiebcke, M.; Freyhardt, C. C.; Felsche, J.; Engelhardt, G. Clathrates with Three-Dimensional Host Structures of Hydrogen Bonded Pentaborate [B5O6(OH)4]- Ions: Pentaborates with the Cations NMe4+, NEt4+, NPhMe3+ and pipH+ (pipH+ = Piperidinium). Z. Naturforsch. 1993, 48b, 978–985. DOI: 10.1515/znb-1993-0722.
   Google Scholar
• Visi, M. Z.; Knobler, C. B.; Owen, J. J.; Khan, M. I.; Schubert, D. M. Structures of Self-Assembled Nonmetal Borates Derived from α,ω-Diaminoalkanes. Cryst. Growth Des. 2006, 6, 538–545. DOI: 10.1021/cg0504915.
   Web of Science ®Google Scholar
• Beckett, M. A.; Bland, C. C.; Horton, P. N.; Hursthouse, M. B.; Varma, K. S. Supramolecular Structures Containing ‘Isolated’ Pentaborate Anions and Non-Metal Cations: Crystal Structures of [Me3NCH2CH2OH][B5O6(OH)4] and [4-MepyH,4-Mepy][B5O6(OH)4]. J. Organomet. Chem. 2007, 692, 2831–2838. DOI: 10.1016/j.jorganchem.2007.02.038.
   Web of Science ®Google Scholar
• Beckett, M. A.; Coles, S. J.; Davies, R. A.; Horton, P. N.; Jones, C. L. Pentaborate(1-) Salts Template by Substituted Pyrrolidinium Cations: synthesis Structural Characterization, and Modelling of Solid-State H-Bond Interactions by DFT Calculations. Dalton Trans. 2015, 44, 7032–7040. DOI: 10.1039/C5DT00248F.
   PubMed Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. A New Polyborate Anion [B7O9(OH)6]3-: Self-Assembly, XRD and Thermal Properties of s-Fac-[Co(Dien)2][B7O9(OH)6].9H2O. Inorg. Chem. Commun. 2015, 59, 95–98. DOI: 10.1016/j.inoche.2015.07.011.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)6]2-: Synthesis and Characterization of [Co(en)3][B5O6(OH)4] [B8O10(OH)6].5H2O (en = 1,2-Diaminoethane). Inorg. Chem. 2015, 54, 412–414. DOI: 10.1021/ic5027834.
   PubMed Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Synthesis and Characterization of Polyborates Templated by Cationic Copper(II) Complexes: structural (XRD), Spectroscopic, Thermal (TGA/DSC) and Magnetic Properties. Polyhedron 2017, 135, 247–257. DOI: 10.1016/poly.2017.07.016.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Synthesis and Characterization by a Single-Crystal XRD Study of [H3O]4[Cu7(NH3)2(H2O)4{B24O39(OH)12}]13H2O: An Unusual Bis(Hydroxytrioxidoborate) Tri-Metallic Chain Supported by a [{Cu4O}{B20O32(OH)8]6- Cluster. J. Clust. Sci. 2018, 219, 1337–1343. DOI: 10.1007/s10876-018-1452-9.
   Google Scholar
• Cui, A.-L.; Chen, X.; Sun, L.; Wei, J.-Z.; Yang, Y.; Kou, H.-Z. Preparation and Thermochromic Properties of Copper(II)-N,N-Diethylethylenediamine Complexes. J. Chem. Educ. 2011, 88, 311–312. DOI: 10.1021/ed100103a.
   Web of Science ®Google Scholar
• Corbett, P. T.; Leclaire, J.; Vial, L.; West, K. R.; Wietor, J.-L.; Sanders, J. K. M.; Otto, O. Dynamic Combinatorial Chemistry. Chem. Rev. 2006, 106, 3652–3711. DOI: 10.1021/cr020452p.
   PubMed Web of Science ®Google Scholar
• Sola, J.; Lafuente, M.; Atcher, J.; Alfonso, I. Constitutional Self-Selection from Dynamic Combinatorial Libraries in Aqueous Solution through Supramolecular Interactions. Chem. Commun. 2014, 50, 4564–4566. DOI: 10.1039/C4CC00245H.
   PubMed Web of Science ®Google Scholar
• Salentine, C. G. High-Field 11B NMR of Alkali Borates. Aqueous Polyborate Equilibria. Inorg. Chem. 1983, 22, 3920–3924. DOI: 10.1021/ic00168a019.
   Web of Science ®Google Scholar
• Anderson, J. L.; Eyring, E. M.; Whittaker, M. P. Temperature Jump Rate Studies of Polyborate Formation in Aqueous Boric Acid. J. Phys. Chem. 1964, 68, 1128–1132. DOI: 10.1021/j100787a027.
   Web of Science ®Google Scholar
• Taube, H. Rates and Mechanisms of Substitutions of Inorganic Complexes in Aqueous Solution. Chem. Rev. 1952, 50, 69–126. DOI: 10.1021/cr60155a003.
   Web of Science ®Google Scholar
• Dunitz, J. D.; Gavezzotti, A. Supramolecular Synthons: validation and Ranking of Intermolecular Interaction Energies. Cryst. Growth Des. 2012, 12, 5873–5877. DOI: 10.1021/cg301293r.
   Web of Science ®Google Scholar
• Desiraju, G. R. Supramolecular Synthons in Crystal Engineering – a New Organic Synthesis. Angew. Chem. Int. Ed. Engl. 1995, 34, 2311–2327. DOI: 10.1002/anie.199523111.
   Web of Science ®Google Scholar
• Zheng, L.; Zhang, J.; Liu, Z. Synthesis, Crystal Structure and Thermal Behaviour of Coen3[B4O5(OH)4]Cl.3H2O and Nien3[B5O6(OH)4]2.2H2O. Chin. J. Chem. 2009, 27, 494–500. 10.1002/cjoc.200990081
   Google Scholar
• Liu, Z.-H.; Zhang, J.-J.; Zhang, W.-J. Synthesis, Crystal Structure and Vibrational Spectroscopy of a Novel Mixed Ligands Ni(II) Pentaborate: [Ni(C4H10N2)(C2H8N2)2][B5O6(OH)4]2. Inorg. Chim. Acta 2006, 359, 519–524. DOI: 10.1016/j.ica.2005.10.008.
   Web of Science ®Google Scholar
• Yang, Y.; Wang, Y.; Zhu, J.; Liu, R.-B.; Xu, J.; Meng, C.-G. A New Mixed-Ligand Copper Pentaborate with Square-like, Rectangle-like and Ellipse-like Channels Formed via Hydrogen Bonds. Inorg. Chem. Acta 2011, 376, 401–407. DOI: 10.1016/j.ica.2011.06.051.
   Web of Science ®Google Scholar
• Li, J.; Xia, S.; Gao, S. FT-IR and Raman Spectroscopic Study of Hydrated Borates. Spectrochim. Acta 1995, 51A, 519–532. DOI: 10584-8539(94)00183-9.
   Google Scholar
• Beckett, M. A.; Horton, P. N.; Coles, S. J.; Kose, D. A.; Kreuziger, A.-M. Structural and Thermal Studies of Non-Metal Cation Pentaborate Salts with Cations Derived from 1,5-Diazobicyclo[4.3.0]Non-5-Ene, 1,8-Diazobicyclo[5.4.0]Undec-7-Ene and 1,8-Bis(Dimethylamino)Naphthalene. Polyhedron 2012, 38, 157–161. DOI: 10.1016/j.poly.2012.02.031.
   Web of Science ®Google Scholar
• Hathaway, B. J.; Hodgson, P. G. Copper-Ligand Bond-Lengths in Axial Complexes of Copper(II) Ion. J. Inorg. Nucl. Chem. 1973, 35, 4071–4081. DOI: 10.1016/0022-1902(73)80395-1.
   Web of Science ®Google Scholar
• Etter, M. C. Encoding and Decoding Hydrogen-Bond Patterns of Organic Chemistry. Acc. Chem. Res. 1990, 23, 120–126. DOI: 10.1021/ar00172a005.
   Web of Science ®Google Scholar
• Beckett, M. A.; Coles, S. J.; Horton, P. N.; Jones, C. L. Polyborate Anions Partnered with Large Nonmetal Cations: triborate(1-) Pentaborate(1-) and Heptaborate(2-) Salts. Eur. J. Inorg. Chem. 2017, 2017, 4510–4518. DOI: 10.1002/ejic.201700551.
   Google Scholar
• Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. Olex2: A Complete Structure Solution, Refinement and Analysis Program. J. Appl. Crystallogr. 2009, 42, 339–341. DOI: 10.1107/S0021889808042726.
   Web of Science ®Google Scholar
• Sheldrick, G. M. ShelXT-Intergrated Space-Group and Crystal Structure Determination. Acta Crystallogr. A Found. Adv. 2015, A71, 3–8. DOI: 10.1107/S2053273314026370.
   Web of Science ®Google Scholar
• Sheldrick, G. M. Crystal Structure Refinement with ShelXL. Acta Crystallogr. C Struct. Chem. 2015, C27, 3–8. DOI: 10.1107/S2053229614024218.
   Google Scholar