Oxidopolyborate chemistry: The self-assembled, templated, synthesis, and an XRD study of a 1-D coordination polymer, [Cu(en){B₆O₇(OH)₆}]^.3H₂O (en = 1,2-diaminoethane)

References

• Farmer, J. B. Metal Borates. Adv. Inorg. Chem. Radiochem. 1982, 25, 187–237.
   Web of Science ®Google Scholar
• Heller, G. A Survey of Structural Types of Borates and Polyborates. Top. Curr. Chem. 1986, 131, 39–98.
   Web of Science ®Google Scholar
• Schubert, D. M.; Smith, R. A.; Visi, M. Z. Studies of Crystalline Non-Metal Borates. Glass Technol. 2003, 44, 63–70.
   Google Scholar
• Schubert, D. M. Borates in Industrial Use. Struct. Bond. 2003, 105, 1–40.
   Web of Science ®Google Scholar
• Schubert, D. M. Hydrated Zinc Borates and Their Industrial Use. Molecules 2019, 24, 2419. DOI: 10.3390/molecules24132419.
   Web of Science ®Google Scholar
• Becker, P. Borate Materials in Nonlinear Optics. Adv. Mater. 1998, 10, 979–992. DOI: 10.1002/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO;2-N.
   Web of Science ®Google Scholar
• Beckett, M. A. Recent Advances in Crystalline Hydrated Borates with Non-Metal or Transition-Metal Complex Cations. Coord. Chem. Rev. 2016, 323, 2–14. DOI: 10.1016/j.ccr.2015.12.012.
   Web of Science ®Google Scholar
• Corbett, P. T.; Leclaire, J.; Vial, L.; West, K. R.; Wietor, J.-L.; Sanders, J. K. M.; Otto, S. Dynamic Combinatorial Chemistry. Chem. Rev. 2006, 106, 3652–3711. DOI: 10.1021/cr020452p.
   PubMed Web of Science ®Google Scholar
• Salentine, G. High-Field 11B NMR of Alkali Borate. Aqueous Polyborate Equilibria. Inorg. Chem. 1983, 22, 3920–3924. DOI: 10.1021/ic00168a019.
   Web of Science ®Google Scholar
• Anderson, J. L.; Eyring, E. M.; Whittaker, M. P. Temperature Jump Rate Studies of Polyborate Formation in Aqueous Boric Acid. J. Phys. Chem. 1964, 68, 1128–1132. DOI: 10.1021/j100787a027.
   Web of Science ®Google Scholar
• Sola, J.; Lafuente, M.; Atcher, J.; Alfonso, I. Constitutional Self-Selection from Dynamic Combinatorial Libraries in Aqueous Solution through Supramolecular Interactions. Chem. Commun. (Camb.) 2014, 50, 4564–4566. DOI: 10.1039/C4CC00245H.
   PubMed Web of Science ®Google Scholar
• Taube, H. Rates and Mechanisms of Substitutions of Inorganic Complexes in Aqueous Solution. Chem. Rev. 1952, 50, 69–126. DOI: 10.1021/cr60155a003.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Transition-Metal Complexes with Oxidiborates. Synthesis and Characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O″-B12O18 (OH)6-κO″′}Zn(en)(NH2CH2 CH2NH3)].8H2O (en=1,2-Diamminoethane): a Neutral Bimetallic Zwitterionic Polyborate System Containing the ‘Isolated’ Dodecaborate(6-) Anion. Pure Appl. Chem. 2018, 90, 625–632. DOI: 10.1515/pac-2017-0901.
   Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Two 1-D Coordination Polymers Containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].1.5H2O (en = 1,2-Diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-Diaminopropane). Crystals 2018, 8, 470. DOI: 10.3390/cryst8120470.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Hexaborate(2-) and Dodecaborate(12-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single Crystal XRD Characterization of [Zn{κ3O-B6O7(OH)6}(κ3N-Dien)].0.5H2O (Dien = NH(CH2CH2NH2)2), (NH4)2[Zn{κ2O-B6O7(OH)6}2 (H2O)2].2H2O and (1,3-pn)3[(κ1N-NH3{CH2}3NH2)Zn{κ3O-B12O18(OH)6}]2.14H2O. Inorganics 2019, 7, 44. DOI: 10.3390/inorganics7040044.
   Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Synthesis and Characterization of Polyborates Templated by Cationic Copper(II) Complexes: Structural (XRD), Spectroscopic, Thermal (TGA/DSC) and Magnetic Properties. Polyhedron 2017, 135, 247–257. DOI: 10.1016/j.poly.2017.07.016.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Synthesis and Characterization by a Single-Crystal XRD Study of [H3O]4[Cu7(NH3)2(H2O)4{B24O39(OH)12}].13H2O: An Unusual Bis(Hydroxytrioxidoborate) Tri-Metallic Chain Supported by a [{Cu4O}{B20O32(OH)8]6– Cluster. J. Clust. Sci. 2018, 29, 1337–1343. DOI: 10.1007/s10876-018-1452-9.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Copper(2+) Complexes of Hydroxyoxidobortates. Synthesis and Characterization of Two Clusters Containing the Hexaborate (2-) Ligand: [Cu(NH2CH2CH2NEt2){B6O7(OH)6}].5H2O and [Cu(NH3)2{B6O7(OH)6}].2H2O. J. Clust. Sci. 2019, 30, 599–603. DOI: 10.1007/s10876-019-01519-6.
   Web of Science ®Google Scholar
• Naturajan, S.; Klein, W.; Panthoefer, M.; van Wullen, L.; Jansen, M. Solution Mediated Synthesis and Structure of the First Bis(Hexaborato) Zincate Prepared in the Presence of an Organic Amine. Z. Anorg. Allg. Chem. 2003, 629, 959–962.
   Google Scholar
• Jamai, N.; Rzaigui, M.; Toumi, S. A. Piperazine-1,4-Diium Bis(Hexahydroxoheptaoxidohexaborato-κ3-O,O′,O″)Cobaltate(II) Hexahydrate. Acta Crystallogr. E Struct. Rep. Online 2014, 70, m167–168. DOI: 10.1107/S1600536814007090.
   PubMedGoogle Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. Oxido Polyborate Anions Templated by Transition-Metal Complex Cations: Self-Assembled Synthesies and Structural Studies (XRD) of [Co(NH3)6][B4O5(OH)4]3.11H2O, [Ni(Phen)3] [B7O9(OH)5].9.5H2O and [Zn(Dac)2(H2O)2][B7O9(OH)5].H2O. J. Mol. Struct. 2020, 1200, 127071. DOI: 10.1016/j.molstruc.2019.127071.
   Google Scholar
• Schubert, D. M.; Alam, F.; Visi, M. Z.; Knobler, C. B. Structural Characterization and Chemistry of an Industrially Important Zinc Borate, Zn[B3O4(OH)3]. Chem. Mater. 2003, 15, 866–871. DOI: 10.1021/cm020791z.
   Web of Science ®Google Scholar
• Wang, G.-M.; Sun, Y.-Q.; Yang, G.-Y. Synthesis and Crystal Structures of Three New Borates Templated by Transition-Metal Complexes In Situ. J. Solid State Chem. 2006, 179, 1545–1553. DOI: 10.1016/j.jssc.2006.02.002.
   Web of Science ®Google Scholar
• Yang, Y.; Wang, Y.; Zhu, J.; Liu, R.-B.; Xu, J.; Meng, C.-C. A New Mixed Ligand Copper Pentaborate with Square-Like, Rectangular-Like and Ellipse-Like Channels Formed via Hydrogen-Bonds. Inorg. Chim. Acta 2011, 376, 401–407. DOI: 10.1016/j.ica.2011.06.051.
   Web of Science ®Google Scholar
• (a) Liu, Z.-H.; Zhang, J.-J.; Zhang, W.-J. Synthesis, Crystal Structure and Vibrational Spectroscopy of a Novel Mixed Ligands Ni(II) Pentaborate [Ni(C4H10N2)(C2H8N2)2][B5O6 (OH)4]2. Inorg. Chim. Acta 2006, 359, 519–524. DOI: 10.1016/j.ica.2005.10.008.[Mismatch];
   Web of Science ®Google Scholar
  (b) Li, J.; Xia, S.; Gao, S. FT-IR and Raman Spectroscopic Study of Hydrated Borates. Spectrochim. Acta 1995, 51A, 519–532.
   Google Scholar
• Beckett, M. A.; Coles, S. J.; Davies, R. A.; Horton, P. N.; Jones, C. L. Pentaborate(1−) Salts Templated by Substituted Pyrrolidinium Cations: Synthesis, Structural Characterization, and Modelling of Solid-State H-Bond Interactions by DFT Calculations. Dalton Trans. 2015, 44, 7032–7040. DOI: 10.1039/C5DT00248F.
   PubMed Web of Science ®Google Scholar
• Hathaway, B. J.; Hodgson, P. G. Copper-Ligand Bond-Lengths in Axial Complexes of Copper(II) Ion. J. Inorg. Nucl. Chem. 1973, 35, 4071–4081. DOI: 10.1016/0022-1902(73)80395-1.
   Web of Science ®Google Scholar
• Wiebcke, M.; Freyhardt, C. C.; Felsche, J.; Engelhardt, G. Clathrates with Three-Dimensional Host Structures of Hydrogen Bonded Pentaborate [B5O6(OH)4]− Ions: Pentaborates with the Cations NMe4+, NEt4+, NPhMe3+ and pipH+ (pipH+ = Piperidinium). Z. Naturforsch. 1993, 48, 978–985. DOI: 10.1515/znb-1993-0722.
   Google Scholar
• Beckett, M. A.; Horton, P. N.; Hursthouse, M. B.; Timmis, J. L.; Varma, K. S. Templated Heptaborate and Pentaborate Salts of Cyclo-Alkylammonium Cations: structural and Thermal Properties. Dalton Trans. 2012, 41, 4396–4403. DOI: 10.1039/c2dt12310j.
   PubMed Web of Science ®Google Scholar
• Beckett, M. A.; Coles, S. J.; Light, M. E.; Fischer, L.; Stiefvater-Thomas, B. M.; Varma, K. S. Synthesis and X-Ray Characterization of the Organotriboroxinate Salts [Me3NCH2 CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-Ray Structure of the Triarylboroxine, (4-MeOC6H4)3B3O3. Polyhedron 2006, 25, 1011–1016. DOI: 10.1016/j.poly.2005.11.032.
   Web of Science ®Google Scholar
• Altahan, M. A.; Beckett, M. A.; Coles, S. J.; Horton, P. N. A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)6](2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)4] [B8O10(OH)6)]·5H2O (en = 1,2-diaminoethane). Inorg. Chem. 2015, 54, 412–414. DOI: 10.1021/ic5027834.
   PubMed Web of Science ®Google Scholar
• Visi, M. Z.; Knobler, C. B.; Owen, J. J.; Khan, M. I.; Schubert, D. M. Structures of Self-Assembled Nonmetal Borates Derived from α,ω-Diaminoalkanes. Cryst. Growth Des. 2006, 6, 538–545. DOI: 10.1021/cg0504915.
   Web of Science ®Google Scholar
• Etter, M. C. Encoding and Decoding Hydrogen-Bond Patterns of Organic Chemistry. Acc. Chem. Res. 1990, 23, 120–126. DOI: 10.1021/ar00172a005.
   Web of Science ®Google Scholar
• Procter, I. M.; Hathaway, B. J.; Nicholls, P. The Electronic Properties and Stereochemistry of the Copper(II) Ion. Bis(Ethylenediamine)Copper(II) Complexes. J. Chem. Soc. A 1968, 1678–1684. DOI: 10.1039/j19680001678.
   PubMed Web of Science ®Google Scholar
• Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. Olex2: A Complete Structure Solution, Refinement and Analysis Program. J. Appl. Crystallogr. 2009, 42, 339–341. DOI: 10.1107/S0021889808042726.
   Web of Science ®Google Scholar
• Sheldrick, G. M. ShelXT-Intergrated Space-Group and Crystal Structure Determination. Acta Crystallogr. A: Found. Adv. 2015, 71, 3–8. DOI: 10.1107/S2053273314026370.
   PubMed Web of Science ®Google Scholar
• Sheldrick, G. M. Crystal Structure Refinement with ShelXL. Acta Cryst. 2015, C27, 3–8.
   Google Scholar