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Original Articles

Structural Distortions in Main Group Metallacarboranes

, , , &
Pages 129-137 | Published online: 16 Feb 2007

References

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  • Grimes , R. N. , ed. 1982 . Metal Interactions with Boron Clusters , New York : Plenum .
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  • Jutzi , P. , Galow , P. , Abu-Orabi , S. , Arif , A. M. , Cowley , A. H. and Norman , N. C. 1987 . Organometallics , 6 : 1024
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  • Hosmane , N. S. , Jia , L. , Zhang , H. and Maguire , J. A. Organometallics (accepted)
  • Synthetic, spectral, and structural details to be published elsewhere
  • The mirror plane is defined as that that contains Ga(1), B(2), B(6), and the B(4)-B(5) midpoint, see Figure 1 for the atom numbering system
  • Zhang , H. , Wang , Y. , Saxena , A. K. , Old , A. R. , Maguire , J. A. and Hosmane , N. S. 1993 . Organometallics , 12 : 3933
  • Mingos , D. M. P. , Forsyth , M. I. and Welch , A. J. 1976 . J. Chem. Soc., Dalton , : 1363 and references therein
  • Colquhoun , H. M. , Greenhough , T. J. and Wallbridge , M. G. H. 1985 . J. Chem Soc., Dalton , : 761
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  • Stewart , J. J. P. 1983 . QCPE Bull. , 3 : 43 Version 5.01 of the MOPAC package; see
  • For reference, the cage carbon lateral distances in 2 range from 1.52 Å to 1.55 Å (optimized = 1.54 Å and the unique boron from 2.38 Å to 2.52 Å (optimized = 2.49 Å), in 3 the equivalent values range from 1.41 Å to 1.52 Å (optimized = 1.45 Å) and 2.41 Å to 2.47 Å (optimized = 2.47 Å), respectively
  • Equal Sn-C2B3 atom bond distances are found at a lateral displacements of 1.05 2 in 2, and 1.12 Å in 3
  • Fisher , H. and Kollmar , H. 1970 . Theor. Chim. Acta , 16 : 163
  • Dewar , M. J. S. and Lo , D. H. 1971 . J. Am. Chem. Soc. , 93 : 7201
  • Olivella , S. and Vilarrusa , J. 1985 . J. Heterocycl. Chem. , 279 : 359

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