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Original Articles

CONFORMATIONAL PREFERENCES OF SPIROCYCLIC PENTAOXYPHOSPHORANES VARYING IN RING SIZE

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Pages 1-22 | Received 06 Nov 1989, Published online: 24 Sep 2006

References

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  • The function minimized was
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  • When the two sets of positions for the oxygen atoms are simultaneously included, the molecule has a pseudomirror plane which passes through atoms P, C3, C4, C5, C6, and C9 and lies normal to the phenyl group. This pseudo mirror operation takes the A set of oxygen atoms into the B set of oxygen atoms and C1 into C2 (Figures 6)
  • See ref 40 for a discussion of the pertinent background material.
  • It should be noted that the six-membered rings in 1–3 are expected to undergo exchange via diequatorial ring placement similar to that indicated in 4. However, detection of this exchange process did not occur primarily because the other ring component provided no differentiating NMR signal due to their symmetrical and/or planar structures.
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