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Original Articles

Cycloaddition Reactions of Group 14 Dimetallenes: Evidence for a Radical Pathway

Pages 123-132 | Published online: 02 Apr 2008

References

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  • The original solution of the ABX spin system for the adduct between styrene and Mes2Si=SiMes2[5] is not consistent with the J values found through the addition of trans-deutero-styrene . The ABX portion of the 1H nmr spectrum of the adduct was successfully simulated using JAX/BX=16 Hz/7 Hz.
  • 1994 . A zwitterionic intermediate with a positive charge on germanium and a negative charge on carbon was not considered likely given the lack of experimental evidence for heavy Group 14 cations in solutions . Science , 263 : 983 – 985 . A transition state trans-deuterostyrene

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