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Original Articles

Ferromagnetic Interactions in Supramolecular Assemblies Constructed from Nitronyl Nitroxide Radical Cations and Large Inorganic Polyoxometalates

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Pages 67-74 | Published online: 04 Oct 2006

References

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  • Crystal data: (para-rad) 2-Mo6O19 , crystallises in the PI triclinic space group with cell parameters a=8.240(8)Å, b=11.394(4)Å, c=12.059(1)Å, α=65.89(1)Å, β=79.64(3)Å, γ=84.27(5)Å, V=1016 Å3, Z=1, dcalc=2.252 g.cm−3. Full-matrix leastsquares refinements gave R(F)=0.022 and Rω(F)=0.040 based on 3666 reflections with I>3[sgrave](I). (para-rad) 2-W6O19 , crystallises in the PI triclinic space group with cell parameters a=8.268(1)Å, b=11.418(6)Å, c=12.076(2)Å, α=65.77(2)Å, β=79.27(2)Å, γ=84.02(3)Å, V=1021 Å3, Z=1, dcalc=3.099 g.cm−3. Full-matrix least-squares refinements gave Rω(F)=0.019 and Rco(F)=0.030 based on 3808 reflections with 1>4[sgrave](I). The full X-Ray data will be reported elsewhere.
  • North , A. C. T. , Phillips , D. C. and Mathews , F. S. 1968 . Acta. Cryst. , A24 : 351
  • 1990 . “ Crystal Structure Analysis, Molecular Enraf-Nonius (MolEN) ” . The Netherlands : delft Instruments X-Ray Diffraction B.V Rontgenweg 1 2624 BD Delft .
  • Triki , S. , Ouahab , L. , Halet , J. F. , Peña , O. , Padiou , J. , Grandjean , D. , Garrigou-Lagrange , C. and Delhaes , P. 1992 . J. Chem. Soc. Dalton Transactions , : 1217
  • Awaga , K. , Yamaguchi , A. , Okuno , T. , Inabe , T. , Nakamura , T. , Matsumoto , M. and Maruyama , Y. 1994 . J. Mater. Chem. , 4 ( 9 ) : 1377

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