158
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Aqueous phase properties on governing particle coagulation and mechanism nucleation in one-step emulsion polymerization of styrene

, , , , &
Pages 181-188 | Received 29 Nov 2018, Accepted 05 Oct 2019, Published online: 23 Oct 2019

References

  • Sacanna, S.; Irvine, W. T. M.; Chaikin, P. M.; Pine, D. J. Lock and Key Colloids. Nature 2010, 464, 575–578. DOI: 10.1038/nature08906.
  • Zheng, Y.; Wang, D.; Li, Z.; Sun, X.; Gao, T.; Zhou, G. Laccase Biosensor Fabricated on Flower-Shaped Yolk-Shell SiO2 Nanospheres for Catechol Detection. Colloids Surface A 2018, 538, 202–209. DOI: 10.1016/j.colsurfa.2017.10.086.
  • Walther, A.; Müller, A. H. Janus Particles. Soft Matter 2008, 4, 663–668. DOI: 10.1039/b718131k.
  • Camli, S. T.; Buyukserin, F.; Balci, O.; Budak, G. G. Size Controlled Synthesis of Sub-100 nm Monodisperse Poly(Methylmethacrylate) Nanoparticles Using Surfactant-Free Emulsion Polymerization. J. Colloid Interf. Sci. 2010, 344, 528–532. DOI: 10.1016/j.jcis.2010.01.041.
  • Unzueta, E.; Forcada, J. Semicontinuous Emulsion Copolymerization of Methyl Methacrylate and n-Butyl Acrylate: 1. Effect of Mixed Emulsifiers in Seeded Polymerization. Polymer 1995, 36, 1045–1052. DOI: 10.1016/0032-3861(95)93606-M.
  • Asua, J. M. Miniemulsion Polymerization. Prog. Polym. Sci. 2002, 27, 1283–1346. DOI: 10.1016/S0079-6700(02)00010-2.
  • Schwab, M. G.; Crespy, D.; Feng, X.; Landfester, K.; Müllen, K. Preparation of Microporous Melamine-Based Polymer Networks in an Anhydrous High-Temperature Miniemulsion. Macromol. Rapid Commun. 2011, 32, 1798–1803. DOI: 10.1002/marc.201100511.
  • Yan, R.; Zhang, Y.; Wang, X.; Xu, J.; Wang, D.; Zhang, W. Synthesis of Porous Poly(Styrene-co-Acrylic Acid) Microspheres through One-Step Soap-Free Emulsion Polymerization: whys and Wherefores. J. Colloid Interf. Sci. 2012, 368, 220–225. DOI: 10.1016/j.jcis.2011.11.016.
  • Chiu, W. Y.; Shih, C. C. A Study of the Soap-Free Emulsion Polymerization of Styrene. J. Appl. Polym. Sci. 1986, 31, 2117–2128. DOI: 10.1002/app.1986.070310715.
  • Goodall, A. R.; Wilkinson, M. C.; Hearn, J. Mechanism of Emulsion Polymerization of Styrene in Soap-Free Systems. J. Polym. Sci. Polym. Chem. Ed. 1977, 15, 2193–2218. DOI: 10.1002/pol.1977.170150912.
  • Liu, B.; Fu, Z.; Han, Y.; Zhang, M.; Zhang, H. Facile Synthesis of Large Sized and Monodispersed Polymer Particles Using Particle Coagulation Mechanism: An Overview. Colloid Polym. Sci. 2017, 295, 749–757. DOI: 10.1007/s00396-017-4058-0.
  • Liu, B.; Sun, S.; Zhang, M.; Ren, L.; Zhang, H. Facile Synthesis of Large Scale and Narrow Particle Size Distribution Polymer Particles via Control Particle Coagulation during One-Step Emulsion Polymerization. Colloids Surface A 2015, 484, 81–88. DOI: 10.1016/j.colsurfa.2015.07.050.
  • Liu, B.; Zhang, M.; Liu, Y.; Tan, Z.; Zhou, C.; Zhang, H. Particle Nucleation and Growth in the Emulsion Polymerization of Styrene: Effect of Monomer/Water Ratio and Electrolyte Concentration. J. Macromol. Sci. Part A 2015, 52, 147–154. DOI: 10.1080/10601325.2015.980765.
  • Kemmere, M. F.; Meuldijk, J.; Drinkenburg, A. A. H.; German, A. L. Aspects of Coagulation during Emulsion Polymerization of Styrene and Vinyl Acetate. J. Appl. Polym. Sci. 1998, 69, 2409–2421. DOI: 10.1002/(SICI)1097-4628(19980919)69:12 < 2409::AID-APP12 > 3.0.C0;2-S.
  • Peach, S. Coagulative Nucleation in Surfactant-Free Emulsion Polymerization. Macromolecules 1998, 31, 3372–3373. DOI: 10.1021/ma980064i.
  • Sajjadi, S.; Brooks, B. W. Unseeded Semibatch Emulsion Polymerization of Butyl Acrylate: Bimodal Particle Size Distribution. J. Polym. Sci. A Polym. Chem. 2000, 38, 528–545. DOI: 10.1002/(SICI)1099-0518(20000201)38:3 < 528::AID-POLA19 > 3.0.CO;2-H.
  • Liu, B.; Zhang, M.; Yu, G.; Chen, D.; Zhang, H. Effect of Aqueous Phase Composition on Particle Coagulation Behavior in Batch Emulsion Polymerization of Styrene. Colloid Surface A 2014, 452, 159–164. DOI: 10.1016/j.colsurfa.2014.03.100.
  • Xu, X.; Liu, B.; Zhang, M.; Liu, S.; Zhu, F.; Wang, J. Electrolytes on Governing Particle Coagulation and Size Distribution in the Emulsion Polymerization of Butyl Acrylate. J. Polym. Res. 2016, 23, 9. DOI: 10.1007/s10965-015-0900-6.
  • Abdollahi, M.; Yousefi, M. R.; Ghahramani, M.; Ranjbar, H.; Najafi, F. S. Synthesis of Polybutadiene Nanoparticles by Emulsion Polymerization: The Effect of Electrolyte and Initiator Type on Particle Size and Reaction Kinetics. Iran. Polym. J. 2017, 26, 1–10. DOI: 10.1007/s13726-016-0491-z.
  • Sajjadi, S.; Jahanzad, F. Nanoparticle Formation by Highly Diffusion-Controlled Emulsion Polymerisation. Chem. Eng. Sci. 2006, 61, 3001–3008. DOI: 10.1016/j.ces.2005.11.043.
  • Herrera-Ordonez, J.; Rivera, O.; Maldonado-Textle, H.; Ramirez, J. C. Kinetics of Styrene Emulsion Polymerization above the Critical Micelle Concentration: Effect of the Initial Monomer Concentration on the Molecular Weight. J. Polym. Sci. A Polym. Chem. 2005, 43, 1963–1972. DOI: 10.1002/pola.20661.
  • Li, H. C.; Fu, B. Concise Solvent Manual; Chemical Industry Press: Beijing, 2008.
  • Adamson, A. W. Physical Chemistry of Surface; John Wiley: New York, 1976; p. 698.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.