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Articles

Synthesizing ethylene/1-octene copolymer and its nanocomposites with graphene and carbon nanotubes using a Ziegler − Natta catalyst

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Pages 761-768 | Received 28 Apr 2020, Accepted 20 May 2020, Published online: 17 Jun 2020

References

  • Soares, J. B. P.; McKenna, T. F. L. Polyolefin Reaction Engineering, 1st ed. Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, 2012.
  • Chung, T. Synthesis of Functional Polyolefin Copolymers with Graft and Block Structures. Prog. Polym. Sci 2002, 27, 39–85. DOI: 10.1016/S0079-6700(01)00038-7.
  • Acik, G.; Altinkok, C. Polypropylene Microfibers via Solution Electrospinning under Ambient Conditions. J. Appl. Polym. Sci. 2019, 136, 48199. DOI: 10.1002/app.48199.
  • Chen, C. L. Designing Transition Metal Catalysts for Olefin Polymerization and Copolymerization: Beyond Electronic and Steric Tuning. Nat. Rev. Chem. 2018, 2, 6–14. DOI: 10.1038/s41570-018-0003-0.
  • Zou, C.; Dai, S. Y.; Chen, C. L. Ethylene Polymerization and Copolymerization Using Nickel 2-iminopyridine-N-Oxide Catalysts: modulation of Polymer Molecular Weights and Molecular-Weight Distributions. Macromolecules 2018, 51, 49–56. DOI: 10.1021/acs.macromol.7b02156.
  • Bialek, M.; Ochedzan-Siodlak, W.; Dziubek, K.; Czaja, K.; Bosowska, K. Coordination (co)Polymerization of Olefins. Chemik 2014, 68, 268–279.
  • Hoff, R. E.; Mathers, R.T.; (Eds.) Handbook of Transition Metal Polymerization Catalysts: Wiley: Hoboken, NJ, 2010.
  • Yang, H.; Zhang, L.; Fu, Z.; Fan, Z. Comonomer Effects in Copolymerization of Ethylene and 1-Hexene with MgCl2-Supported Ziegler-Natta Catalysts: New Evidences from Active Center Concentration and Molecular Weight Distribution. J. Appl. Polym. Sci. 2015, 132, 41264–41268. DOI: 10.1002/app.41264.
  • Bungu, P. S.; Pasch, H. Branching and Molar Mass Analysis of Low Density Polyethylene Using the Multiple Preparative Fractionation Concept. Polym. Chem. 2018, 9, 1116–1131. DOI: 10.1039/C7PY02076G.
  • Liu, Z.; Yu, M.; Wang, J.; Li, F.; Cheng, L.; Guo, J.; Huang, Q.; Zhou, Y.; Zhu, B.; Yi, J.; et al. Preparation and Characterization of Novel Polyethylene/Carbon Nanotubes Nanocomposites with Core-Shell Structure. J. Ind. Eng. Chem. 2014, 20, 1804–1811. DOI: 10.1016/j.jiec.2013.08.034.
  • Khoshsefat, M.; Ahmadjo, S.; Mortazavi, S. M. M.; Zohuri, G. H. Reinforcement Effects of Nano Carbons on Catalyst Behaviour and Polyethylene Properties through in Situ Polymerization. RSC Adv. 2016, 6, 88625–88632. DOI: 10.1039/C6RA16243F.
  • Ramazani, A.; Tavakolzadeh, F.; Baniasadi, H. In Situ Polymerization of Polyethylene/Clay Nanocomposites Using a Novel Clay-Supported Ziegler-Natta Catalyst. Polym. Compos. 2009, 30, 1388–1393. DOI: 10.1002/pc.20702.
  • Coiai, S.; Prevosto, D.; Bertoldo, M.; Conzatti, L.; Causin, V.; Pinzino, C.; Passaglia, E. Chemistry of Interfacial Interactions in a LDPE-Based Nanocomposite and Their Effect on the Nanoscale Hybrid Assembling. Macromolecules 2013, 46, 1563–1572. DOI: 10.1021/ma301689h.
  • Sirocic, A. P.; Rescek, A.; Scetar, M.; Krehula, L. K.; Hrnjak-Murgic, Z. Development of Low Density Polyethylene Nanocomposites Films for Packaging. Polym. Bull. 2014, 71, 705–717. DOI: 10.1007/s00289-013-1087-9.
  • Wang, J.; Li, H.; Guo, J.; Huang, Q.; Yi, J.; Liu, Y.; Gao, K.; Yang, W. Coral-Shaped and Core-Shell Structure Polyethylene Nanocomposites Particles Prepared by in Situ Coordination Polymerization. Chin. J. Polym. Sci. 2015, 33, 1650–1660. DOI: 10.1007/s10118-015-1719-7.
  • Hanifpour, A.; Bahri-Laleh, N.; Nekoomanesh-Haghighi, M.; Karimi, M. Synthesis and Characterization of poly1-Hexene/Silica Nanocomposites. Polym. Test 2017, 61, 27–34. DOI: 10.1016/j.polymertesting.2017.05.002.
  • Alikhani, A.; Hakim, S.; Nekoomanesh, M. Modified Preparation of HDPE/Clay Nanocomposite by in Situ Polymerization Using a Metallocene Catalyst. Iran. Polym. J. 2017, 26, 721–731. DOI: 10.1007/s13726-017-0557-6.
  • Kaminsky, W. Metallocene Based Polyolefin Nanocomposites. Materials (Basel) 2014, 7, 1995–2013. DOI: 10.3390/ma7031995.
  • Chen, M.; Chen, C. L. A Versatile Ligand Platform for Palladium-and Nickel-Catalyzed Ethylene Copolymerizations with Polar Monomers. Angew. Chem. Int. Ed. 2018, 57, 3094–3098. DOI: 10.1002/anie.201711753.
  • Shehzad, F.; Daud, M.; Al-Harthi, M. A. Synthesis, Characterization and Crystallization Kinetics of Nanocomposites Prepared by in Situ Polymerization of Ethylene and Grapheme. J. Therm. Anal. Calorim. 2016, 123, 1501–1511. DOI: 10.1007/s10973-015-5087-x.
  • Brandrup, J.; Immergut, E. H. Polymer Handbook; Wiley: New York, 1989.
  • Zohuri, G. H.; Damavandi, S.; Ahmadjo, S.; Sandaroos, R.; Shamekhi, M. A. Synthesis of High Molecular Weight Polyethylene Using FI Catalyst. Polyolefins J. 2014, 1, 25–32.
  • Liu, W.; Guo, S.; Fan, H.; Wang, W.; Li, B.-G.; Zhu, S. Synthesis of Ethylene/1-Octene Copolymers with Controlled Block Structures by Semibatch Living Copolymerization. AIChE J. 2013, 59, 4686–4695. DOI: 10.1002/aic.14204.
  • Zohuri, G. H.; Mortazavi, M. M.; Jamjah, R.; Ahmadjo, S. Copolymerization of Ethylene-Propylene Using High Activity bi-Supported Zeigler-Natta TiCl4 Catalyst. J. Appl. Polym. Sci. 2004, 93, 2597–2605. DOI: 10.1002/app.20827.
  • Zohuri, G. H.; R.; Jamjah, R.; Mehtarani, M.; Neokomanesh Haghighi, M.; Ahmadjo, S.  Slurry Polymerization of Ethylene Using Bisupported Ziegler-Natta Catalyst of SiO2/MgCl2(Ethoxide Type) TiCl4/TEA System. Iran. Polym. J 2003, 12, 31–36.
  • Wang, W.; Fan, Z.; Feng, L.; Li, C. Substituent Effect of Bisindenyl Zirconene Catalyst on Ethylene/1-Hexene Copolymerization and Propylene Polymerization. Eur. Polym. J. 2005, 41, 83–89. DOI: 10.1016/j.eurpolymj.2004.08.002.
  • Mortazavi, S. M. M.; Arabi, H.; Zohuri, G. H.; Ahmadjo, S.; Nekoomanesh, M.; Ahmadi, M. Copolymerization of Ethylene/α-Olefins Using Bis(2 Phenylindenyl) Zirconium Dichloride Metallocene Catalyst: Structural Study of Comonomer Distribution. Polym. Int. 2010, 59, 1258–1265. DOI: 10.1002/pi.2859.
  • Quijada, R.; Dupont, J.; Miranda, M. S. L.; Scipioni, R. B.; Galland, G. B. Copolymerization of Ethylene with 1-Hexene and 1-Octene: Correlation between Type of Catalyst and Comonomer Incorporated. Macromol. Chem. Phys. 1995, 196, 3991–4000. DOI: 10.1002/macp.1995.021961210.
  • Grieken, R.; Carrero, A.; Suarez, I.; Paredes, B. Effect of 1-Hexene Comonomer on Polyethylene Particle Growth and Kinetic Profiles. Macromol. Symp. 2007, 259, 243–252. DOI: 10.1002/masy.200751329.
  • Bernardo-Gusmao, K.; de Souza, R.; Bernardo-Gusmao, K. Effect of Alkylaluminum Cocatalyst on Ethylene Polymerization with Nickel-α-Diimine Complex. Appl. Catal. A 2007, 325, 87–90. DOI: 10.1016/j.apcata.2007.03.007.
  • Ahmadjo, S.; Dehghani, S.; Zohuri, G. H.; Nejabat, G. R.; Jafarian, H.; Ahmadi, M.; Mortazavi, S. M. M. Thermal Behavior of Polyethylene Reactor Alloys Polymerized by Ziegler–Natta/Latetransition Metal Hybrid Catalyst. Macromol. React. Eng. 2015, 9, 8–18. DOI: 10.1002/mren.201400024.
  • Białek, M.; Bisz, E. A Comparative Study on the Polymerization of 1-Octene Promoted by Vanadium and Titanium Complexes Supported by Phenoxyimine and Salen Type Ligands. J. Polym. Res. 2013, 20, 164–173.
  • Pater, J. T. M.; Weickert, G.; Loos, J.; Van Swaaij, W. P. M. High Precision Prepolymerization of Propylene at Extremely Low Reaction Rates: Kinetics and Morphology. Chem. Eng. Sci. 2001, 56, 4107–4120. DOI: 10.1016/S0009-2509(01)00081-1.
  • Pater, J. T. M.; Weickert, G.; Loos, J.; Van Swaaij, W. P. M. Polymerization of Liquid Propylene with a Fourth Generation Ziegler-Natta Catalyst: influence of Temperature, Hydrogen, Monomer Concentration, and Prepolymerization Method on Powder Morphology. J. Appl. Polym. Sci. 2003, 87, 1421–1435. DOI: 10.1002/app.11570.
  • Merz, T.; Mulrooney, M. Polyolefin Innovations & New Catalyst Systems. Presented at the 12th Saudi-Japan Symposium, Dhahran, 2002.
  • Zohuri, G. H.; Ahmadjo, S.; Jamjah, R.; Nekomanesh, M. Structural Study of Mono and bi-Supported Ziegler-Natta Catalysts of MgCl2 (Ethoxide Type) and SiO2/MgCl2 (Ethoxide Type) TiCl4/Donor Systems. Iran. Polym. J. 2001, 10, 149–155.
  • Abedi, S.; Hosseinzadeh, M.; Kazemzadeh, M. A.; Daftari-Besheli, M. Effect of Polymerization Time on the Molecular Weight and Molecular Weight Distribution of Polypropylene. J. Appl. Polym. Sci. 2006, 100, 368–371. DOI: 10.1002/app.23123.
  • Alobaidi, F.; Ye, Z.; Zhu, S. Direct Synthesis of Linear Low Density Polyethylene of Ethylene/1-Hexene from Ethylene with a Tandem Catalytic System in a Single Reactor. J. Polym. Sci. A Polym. Chem. 2004, 42, 4327–4336. DOI: 10.1002/pola.20288.
  • Masoori, M.; Ahmadjo, S.; Mortazavi, S. M. M.; Vakili, M. Copolymerization of Ethylene α-Olefin Using MgCl2-Ethanol Adduct Catalysts. J. Macromol. Sci. Part A: Pure Appl. Chem. 2017, 54, 140–144. DOI: 10.1080/10601325.2017.1265397.
  • Zohuri, G. H.; Askari, M.; Ahmadjo, S.; Damavandi, S.; Eftekhar, M.; Bonakdar, M. A. Preparation of Ultra-High-Molecular-Weight Polyethylene and Its Morphological Study with a Heterogeneous Ziegler–Natta Catalyst. J. Appl. Polym. Sci. 2010, 118, 3333–3339. DOI: 10.1002/app.32293.
  • Damavandi, S.; Samadieh, N.; Ahmadjo, S.; Etemadinia, Z.; Zohuri, G. H. Novel Ni-Based FI Catalyst for Ethylene Polymerization. Eur. Polym. J. 2015, 64, 118–125. DOI: 10.1016/j.eurpolymj.2014.12.032.
  • Jamjah, R.; Zohuri, G. H.; Vaezi, J.; Ahmadjo, S.; Nekomanesh, M.; Pouryari, M. Morphological Study of Spherical MgCl2.nEtOH Supported TiCl4 Ziegler-Natta Catalyst for Polymerization of Ethylene. J. Appl. Polym. Sci. 2006, 101, 3829–3834. DOI: 10.1002/app.24170.
  • Wang, J.; Yu, M.; Jiang, W.; Zhou, Y.; Li, F.; Cheng, L.; Yi, J.; Huang, Q.; Liu, Y.; Yang, W. The Preparation of Nanosized Polyethylene Particles via Carbon Sphere Nanotemplates. Ind. Eng. Chem. Res. 2013, 52, 17691–17694. DOI: 10.1021/ie4022946.
  • ] Mahfuz, H.; Adnan, A.; Rangari, V. K.; Jeelani, S. Manufacturing and Characterization of Carbon Nanotube/Polyethylene Composites. Int. J. Nanosci. 2005, 04, 55–72. DOI: 10.1142/S0219581X05002961.
  • Ruan, S.; Gao, P.; Yu, T. X. Ultra-Strong Gel-Spun UHMWPE Fibers Reinforced Using Multi-Walleded Carbon Nanotubes. Polymer 2006, 47, 1604–1611. DOI: 10.1016/j.polymer.2006.01.020.
  • Bonduel, D.; Mainil, M.; Alexandre, M.; Monteverde, F.; Dubois, P. Supported Coordination Polymerization: A Unique Way to Potent Polyolefin Carbon Nanotube Nanocomposites. Chem. Commun. 2005, 6, 781–783. DOI: 10.1039/b414164d.
  • Tong, X.; Liu, C.; Cheng, H. M.; Zhao, H.; Yang, F.; Zhang, X. Surface Modification of Single-Walled Carbon Nanotubes with Polyethylene via in Situ Ziegler-Natta Polymerization. J. Appl. Polym. Sci. 2004, 92, 3697–3700. DOI: 10.1002/app.20306.
  • Funck, A.; Kaminsky, W. Polypropylene Carbon Nanotube Composites by in Situ Polymerization. Comp. Sci. Technol. 2007, 67, 906–915. DOI: 10.1016/j.compscitech.2006.01.034.
  • Bonduel, D.; Bredeau, S.; Alexandre, M.; Monteverde, F.; Dubois, P. Supported Metallocene Catalysis as an Efficient Tool for the Preparation of Polyethylene/Carbon Nanotube Nanocomposites: effect of the Catalytic System on the Coating Morphology. J. Mater. Chem. 2007, 17, 2359–2366. DOI: 10.1039/b701764b.
  • Van Krevelen, D. W.; Hoftyzer, P. J. Properties of Polymer; Elsevier Scientific: New York, 1976.

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