References
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- A 1:1 complex follows to the equation, CHCG/ (A-AH) = (ϵHG-ϵH)−1 × CG+(ϵHG-ϵH)−1 × K−1 (where CH and CG mean the initial host concentration and the added guest concentration, respectively; A and AH mean the measured absorbance and the initial host absorbance, respectively; ϵHG and ϵH mean the molar absorption coefficients of the complex and of the host, respectively). On the basis of a plot of CG vs CHCG/ (A-AH), the association constant K is estimated from the slope divided by the intercept. Similarly, a 1:2 complex follows to the equation, CHC2 G/(A - AH) = (ϵHG - ϵH)−1 × C2 G + (ϵHG - ϵH)−1 × K−1
- Young , R. and Chang , C. K. 1985 . J. Am. Chem. Soc. , 107 : 898