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Original Articles

The Air/Surface Adsorption Equilibrium of Organic Compounds Under Ambient Conditions

Pages 339-389 | Published online: 10 Aug 2010

REFERENCES

  • Storey , J. M. E. and Pankow , J. F. 1992 . Gas-particle partitioning of semivolatile organic compounds to model atmospheric particulate materials—I. Sorption to graphite, sodium chloride, alumina, and silica particles under low humidity conditions . Atmos. Environ. , 26 : 435 – 443 .
  • Liang , C. , Pankow , J. F. , Odum , J. R. and Seinfeld , J. S. 1997 . Gas/particle partitioning of semivolatile organic compounds to model inorganic, organic, and ambient smog aerosols . Environ. Sci. Technol. , 31 : 3086 – 3092 .
  • Pankow , J. F. 1987 . Review and comparative analysis of the theories on partitioning between the gas and aerosol particulate phases in the atmosphere . Atmos. Environ. , 21 : 2275 – 2283 .
  • Pennell , K. D. , Rhue , R. D. , Rao , P. S. C. and Johnston , C. T. 1992 . Vapor-phase sorption of p-xylene and water on soils and clay minerals . Environ. Sci. Technol. , 26 : 756 – 763 .
  • Hoff , J. T. , Gillham , R. , Mackay , D. and Shiu , W. Y. 1993 . Sorption of organic vapors at the air-water interface in a sandy aquifer material . Environ. Sci. Technol. , 27 : 2789 – 2794 .
  • Chiou , C. T. and Shoup , T. D. 1985 . Soil sorption of organic vapors and effects of humidity on sorptive mechanism and capacity . Environ. Sci. Technol. , 19 : 1196 – 1200 .
  • Kim , H. , Annable , M. D. and Rao , P. S. C. 1998 . Influence of air–water interfacial adsorption and gas phase partitioning on the transport of organic chemicals in unsaturated porous media . Environ. Sci. Technol. , 32 : 1253 – 1259 .
  • Thibaud , C. , Erkey , C. and Akgerman , A. 1993 . Investigation of the effect of moisture on the sorption and desorption of chlorobenzene and toluene from soil . Environ. Sci. Technol. , 27 : 2373 – 2380 .
  • Ong , S. K. and Lion , L. W. 1991 . Mechanism for trichloroethylene vapor sorption onto soil minerals . J. Environ. Qual. , 20 : 180 – 188 .
  • Brusseau , M. L. , Popovicova , J. and Silva , J. A. K. 1997 . Characterizing gas–water interfacial and bulk-water partitioning for gas-phase transport of organic contaminants in unsaturated porous media . Environ. Sci. Technol. , 31 ( 6 ) : 1645 – 1649 .
  • Steinberg , S. M. and Kreamer , D. K. 1993 . Evaluation of the sorption of volatile organic compounds by unsaturated calcareous soil from southern Nevada using inverse gas chromatography . Environ. Sci. Technol. , 27 ( 5 ) : 883 – 888 .
  • Corley , T. L. , Farrell , J. , Hong , B. and Conklin , M. H. 1996 . VOC accumulation and pore filling in unsaturated porous media . Environ. Sci. Technol. , 30 ( 10 ) : 2884 – 2891 .
  • Goss , K.-U. 1992 . Effects of temperature and relative humidity on the sorption of organic vapors on quartz sand . Environ. Sci. Technol. , 26 : 2287 – 2294 .
  • Goss , K.-U. 1993 . Effects of temperature and relative humidity on the sorption of organic vapors on clay minerals . Environ. Sci. Technol. , 27 : 2127 – 2132 .
  • Goss , K.-U. 1993 . Adsorption of organic vapors on ice and quartz sand at temperatures below 0°C . Environ. Sci. Technol. , 27 : 2826 – 2830 .
  • Goss , K.-U. and Eisenreich , S. J. 1996 . Adsorption of VOC's from the gas phase to different minerals and a mineral mixture . Environ. Sci. Technol. , 30 : 2135 – 2142 .
  • Goss , K.-U. 1994 . Predicting the enrichment of organic compounds in fog caused by adsorption on the water surface . Atmos. Environ. , 28 ( 21 ) : 3513 – 3517 .
  • Goss , K.-U. and Schwarzenbach , R. P. 1999 . Empirical prediction of heats of vaporization and heats of adsorption of organic compounds . Environ. Sci. Technol. , 33 ( 19 ) : 3390 – 3393 .
  • Goss , K.-U. 1997 . Considerations about the adsorption of organic molecules from the gas Phase to surfaces: Implications for inverse gas chromatography and the prediction of adsorption coefficients . J. Colloid Interface Sci. , 190 : 241 – 249 .
  • Goss , K.-U. 1997 . Conceptual model for the adsorption of organic compounds from the gas phase to liquid and solid surfaces . Environ. Sci. Technol. , 31 ( 12 ) : 3600 – 3605 .
  • Goss , K.-U. and Schwarzenbach , R. P. 2002 . Adsorption of a diverse set of organic vapors on quartz, CaCO3 and α-Al2O3 at different relative humidities . J. Colloid Interface Sci. , 252 : 31 – 41 .
  • Roth , C. M. , Goss , K.-U. and Schwarzenbach , R. P. 2002 . Adsorption of a diverse set of organic vapors on a bulk water surface . J. Colloid Interface Sci. , 252 : 21 – 30 .
  • Goss , K.-U. , Buschmann , J. and Schwarzenbach , R. P. 2003 . Determination of the surface sorption properties of talc, different salts and clay minerals at various relative humidities using adsorption data of a diverse set of organic vapors . Environ. Toxicol. Chem. , 22 ( 11 ) : 2667 – 2672 .
  • Karger , B. L. , Castells , R. C. , Sewell , P. A. and Hartkopf , A. 1971 . Study of adsorption of insoluble and sparingly soluble vapors at the gas–liquid interface of water by gas chromatography . J. Phys. Chem. , 75 : 3870 – 3879 .
  • Dorris , G. M. and Gray , D. G. 1981 . Adsorption of hydrocarbons on silica-supported water surfaces . J. Phys. Chem. , 85 : 3628 – 3635 .
  • Raja , S. , Yaccone , F. S. , Ravikrishna , R. and Valsaraj , K. T. 2002 . Thermodynamic parameters for the adsorption of aromatic hydrocarbon vapors at the gas–water interface . J. Chem. Eng. Data , 47 : 1213 – 1219 .
  • Hoff , J. T. , Gillham , R. , Mackay , D. and Shiu , W. Y. 1993 . Partitioning of organic chemicals at the air-water interface in environmental systems . Environ. Sci. Technol. , 27 : 2174 – 2180 .
  • Peterson , M. S. , Lion , L. W. and Shoemaker , C. A. 1988 . Influence of vapor-phase sorption and diffusion on the fate of trichloroethylene in an unsaturated aquifer system . Environ. Sci. Technol. , 22 : 571 – 578 .
  • Pennell , K. D. 1992 . Competitive adsorption of para-xylene and water vapors on calcium, sodium, and lithium-saturated kaolinite . J. Environ. Qual. , 21 : 419 – 426 .
  • Hoff , J. T. , Wania , F. , Mackay , D. and Gillham , R. 1995 . Sorption of nonpolar organic vapors by ice and snow . Environ. Sci. Technol. , 29 : 1982 – 1989 .
  • Smith , J. A. , Chiou , C. T. , Kammer , J. A. and Kile , D. E. 1990 . Effect of soil moisture on the sorption of trichloroethylene vapor to vadose-zone soil at Picatinny Arsenal, New Jersey . Environ. Sci. Technol. , 24 : 676 – 683 .
  • Ong , S. K. and Lion , L. W. 1991 . Effects of soil properties and moisture on the sorption of trichloroethylene vapor . Water Res. , 25 : 29 – 36 .
  • Hippelein , M. and McLachlan , M. S. 1998 . Soil/air partitioning of semivolatile organic compounds. 1. Method development and influence of physical–chemical properties . Environ. Sci. Technol. , 32 : 310 – 316 .
  • Hippelein , M. and McLachlan , M. S. 2000 . Soil/air partitioning of semivolatile organic compounds. 2. influence of temperature and relative humidity . Environ. Sci. Technol. , 34 : 3521 – 3526 .
  • Baker , J. E. and Eisenreich , S. J. 1990 . Concentrations and fluxes of polycyclic aromatic hydrocarbons and polychlorinated biphenyls across the air–water interface of Lake Superior . Environ. Sci. Technol. , 24 : 342 – 352 .
  • Simcik , M. F. , Franz , T. P. , Zhang , H. and Eisenreich , S. J. 1998 . Gas–particle partitioning of PCS's in the chicago urban and adjacent coastal atmosphere: States of equilibrium . Environ. Sci. Technol. , 32 : 251 – 257 .
  • Bidleman , T. F. , Billings , W. N. and Foreman , W. T. 1986 . Vapor–particle partitioning of semivolatile organic compounds: Estimates from field collections . Environ. Sci. Technol. , 20 : 1038 – 1043 .
  • Foreman , W. T. and Bidleman , T. F. 1990 . Semivolatile organic compounds in the ambient air of Denver, Colorado . Atmos. Environ. , 24A : 2405 – 2416 .
  • Ligocki , M. P. and Pankow , J. P. 1989 . Measurements of the gas/particle distributions of atmospheric organic compounds . Environ. Sci. Technol. , 23 : 75 – 83 .
  • Yamasaki , H. , Kuwata , K. and Miyamoto , H. 1982 . Effects of ambient temperature on aspects of airborne polycyclic aromatic hydrocarbons . Environ. Sci. Technol. , 16 : 189 – 194 .
  • Goss , K.-U. and Schwarzenbach , R. P. 2001 . Linear free energy relationships used to evaluate equilibrium partitioning of organic compounds . Environ. Sci. Technol. , 35 : 1 – 9 .
  • Zagorevskaya , E. V. , Ishchenko , N. V. , Kiselev , A. V. and Kovaleva , N. V. 1985 . Studies of adsorption of polychlorocarbons on carbon blacks by gas chromatography . Ads. Sci. Technol. , 2 : 219 – 228 .
  • Vitha , M. F. and Carr , P. W. 2000 . The chemical meaning of the standard free energy of transfer: Use of van der Waals' equation of state to unravel the interplay between free volume, volume entropy, and the role of standard states . J. Phys. Chem. B. , 104 : 5343 – 5349 .
  • de Boer , J. H. The dynamic character of adsorption , 2nd ed. , p. 112, 1968 Oxford : Clarendon Press .
  • Dorris , G. M. and Gray , D. G. 1980 . Adsorption of n-alkanes at zero surface coverage on cellulose paper and wood fibers . J. Colloid Interface Sci. , 77 : 353 – 362 .
  • Abraham , M. H. 1993 . Hydrogen bonding XXVII. Solvation parameters for functionally substituted aromatic compounds and heterocyclic compounds, from gas–liquid chromatographic data . J. Chromatogr. , 644 : 95 – 139 .
  • Abraham , M. H. , Andonian-Haftvan , J. , Whiting , G. S. , Leo , A. and Taft , R. S. 1994 . Hydrogen bonding. Part 34. The factors that influence the solubility of gases and vapours in water at 298 K, and a new method for its determination . J. Chem. Soc. Perkin Trans. , 2 ( 7 ) : 1777 – 1791 .
  • Mutelet , F. and Rogalski , M. 2001 . Experimental determination and prediction of the gas–liquid n-hexadecane partition coefficients . J. Chromatogr. A , 923 : 153 – 163 .
  • Li , Q. , Poole , C. F. , Kiridena , W. and Koziol , W. W. 2000 . Chromatographic methods for the determination of the log L16 solute descriptor . Analyst , 125 : 2180 – 2188 .
  • van Oss , C. J. 1994 . Interfacial forces in aqueous media , New York : Marcel Dekker .
  • Fowkes , F. M. , Riddle , F. L. , Pastore , W. E. and Weber , A. A. 1990 . Interfacial interactions between self-associated polar liquids and squalane used to test equations for solid–liquid interfacial interactions . Colloids Surfaces , 43 : 367 – 387 .
  • Eon , C. and Guiochon , G. 1973 . Surface activity coefficients as studied by gas chromatography . J. Colloid Interface Sci. , 45 : 521 – 528 .
  • Fowkes , F. M. 1964 . Attractive forces at interfaces . Ind. Eng. Chem. , 56 ( 12 ) : 40 – 52 .
  • Kamdem , D. P. , Bose , S. K. and Luner , P. 1993 . Inverse gas chromatography characterization of birch wood meal . Langmuir , 9 : 3039 – 3044 .
  • Vidal , A. , Papirer , E. , Jiao , W. M. and Donnet , J. B. 1987 . Modification of silica surfaces by grafting of alkyl chains. I—Characterization of silica surfaces by inverse gas chromatography at zero surface coverage . Chromatographia , 23 ( 2 ) : 121 – 128 .
  • Boyd , G. E. and Livingston , H. K. 1942 . Adsorption and the energy changes at crystalline solid surfaces . J. Am. Chem. Soc. , 64 : 2383 – 2388 .
  • Harkins , W. D. and Loeser , E. H. 1950 . Surfaces of solids XIX. Molecular interaction between metals and hydrocarbons . J. Chem. Phys. , 18 ( 4 ) : 556 – 560 .
  • Papirer , E. and Balard , H. 1996 . “ Chemical and morphological characteristics of inorganic sorbents with respect to gas adsorption ” . In Adsorption on new and modified inorganic sorbents , Edited by: Dabrowski , A. and Tertykh , V. A. pp. 479 – 502 . Elsevier : Amsterdam .
  • Nardin , M. , Balard , H. and Papirer , E. 1990 . Surface characteristics of commercial carbon fibres determined by inverse gas chromatography . Carbon , 28 ( 1 ) : 43 – 48 .
  • Abraham , M. H. , Chadha , H. S. , Whiting , G. S. and Mitchell , R. C. 1994 . Hydrogen bonding. 32. An analysis of water–octanol and water–alkane partitioning and the Δlog P parameter of Seiler . J. Pharm. Sci. , 83 : 1085 – 1100 .
  • Goss , K.-U. and Schwarzenbach , R. P. 1999 . Quantification of the effect of humidity on the gas/mineral oxide and gas/salt adsorption of organic compounds . Environ. Sci. Technol. , 33 ( 22 ) : 4073 – 4078 .
  • Gustafsson , Ö. and Gschwend , P. M. 1999 . Hydrophobic organic compound partitioning from bulk water to the water/air interface . Atmos. Environ. , 33 : 163 – 167 .
  • Abraham , M. H. , Whiting , G. S. , Fuchs , R. and Chambers , E. J. 1990 . Thermodynamics of solute transfer from water to hexadecane . J. Chem. Soc. Perkin Trans. , 2 : 291 – 300 .
  • Lide , D. R. , ed. 1995 . CRC handbook of chemistry and physics , 76th ed. , Boca Raton, FL : CRC Press .
  • Goss , K.-U. and Schwarzenbach , R. P. 1998 . Gas/solid and gas/liquid partitioning of organic compounds: Critical evaluation of the interpretation of equilibrium constants . Environ. Sci. Technol. , 32 : 2025 – 2032 .
  • Pecsok , R. L. , de Yllana , A. and Abdul-Karim , A. 1964 . Liquid surface effects in gas chromatography . Anal. Chem. , 36 : 452 – 457 .
  • Castells , R. C. , Arancibia , E. L. and Nardillo , A. M. 1982 . Solution and adsorption of hydrocarbons in glycerol as studied by gas–liquid chromatography . J. Phys. Chem. , 86 : 4456 – 4460 .
  • Castells , R. C. , Romero , L. M. and Nardillo , A. M. 1997 . Concurrent solution and adsorption of hydrocarbons in gas chromatographic columns packed with different loadings of 3-methylsydnone on chromosorb P . J. Colloid Interface Sci. , 192 : 142 – 148 .
  • Arancibia , E. L. and Catoggio , J. A. 1982 . Gas chromatographic study of solution and adsorption of hydrocarbons on glycols . J. Chromatogr. , 238 : 281 – 290 .
  • Arancibia , E. L. and Catoggio , J. A. 1980 . Gas chromatographic study of solution and adsorption of hydrocarbons on glycols. I. Diethylene glycol and triethylene glycol . J. Chromatogr. , 197 : 135 – 145 .
  • Abraham , M. S. , Whiting , G. S. , Doherty , R. M. , Shuely , W. J. and Panos , S. 1992 . An analysis of polymer–probe interactions in some hydrocarbon polymers using a new solvation equation . Polymer , 33 ( 10 ) : 2162 – 2167 .
  • Abraham , M. H. , Whiting , G. S. , Doherty , R. M. and Shuely , W. J. 1991 . Hydrogen bonding XVII. The characterisation of 24 gas–liquid chromatographic stationary phases studied by poole and co–workers, including molten salts, and evaluation of solute–stationary phase interactions . J. Chromatogr. , 587 : 229 – 236 .
  • Abraham , M. H. , Poole , C. F. and Poole , S. K. 1999 . Classification of stationary phases and other materials by gas chromatography . J. Chromatogr. A , 842 : 79 – 114 .
  • Abraham , M. H. and Roses , M. 1994 . Hydrogen bonding. 38. Effect of solute structure and mobile phase composition on reversed-phase high-performance liquid chromatographic capacity factors . J. Phys. Org. Chem. , 7 : 672 – 684 .
  • Martin , S. D. , Poole , C. F. and Abraham , M. H. 1998 . Synthesis and gas chromatographic evaluation of a high-temperature hydrogen-bond acid stationary phase . J. Chromatogr. A , 805 : 217 – 235 .
  • Chessick , J. J. , Zettlemoyer , A. C. , Healey , F. H. and Young , G. J. 1955 . Interaction energies of organic molecules with rutile and graphon surfaces from heats of immersion . Can. J. Chem. , 33 : 251 – 258 .
  • Malandrini , H. , Sarraf , R. , Faucompre , B. , Partyka , S. and Douillard , J. M. 1997 . Characterization of quartz particle surfaces by immersion calorimetry . Langmuir , 13 : 1337 – 1341 .
  • McCafferty , E. and Zettlemoyer , A. C. 1971 . Adsorption of water vapour on α -Fe2 O3 . Disc. Faraday Soc. , : 239 – 263 .
  • Raoof , A. , Guilbaud , J.-P. , Van Damme , H. , Porion , P. and Levitz , P. 1998 . Analysis of the multilayer thickness relationship for water vapor and nitrogen adsorption . J. Colloid Interface Sci. , 206 : 1 – 9 .
  • Furlong , D. N. , Sing , K. S. W. and Parfitt , G. D. 1986 . Adsorption of water vapour on rutile and silica-coated rutile . Ads. Sci. Technol. , 3 : 25 – 32 .
  • Gammage , R. B. and Gregg , S. J. 1972 . The sorption of water vapor by ball-milled calcite . J. Coloid Interface Sci. , 38 : 118 – 124 .
  • Orchiston , H. D. 1954 . Adsorption of water vapor: II. Clays at 25°C . Soil Sci. , 78 : 463 – 480 .
  • Storey , J. M. , Luo , W. , Isabelle , L. M. and Pankow , J. F. 1995 . Gas/solid partitioning of semivolatile organic compounds to model atmospheric solid surfaces as a function of relative humidity. 1. Clean quartz . Environ. Sci. Technol. , 29 : 2420 – 2428 .
  • Rao , P. S. C. , Ogwada , R. A. and Rhue , R. D. 1989 . Adsorption of volatile organic compounds on anhydrous and hydrated sorbents: Equilibrium adsorption and energetics . Chemosphere , 18 : 2177 – 2191 .
  • Rhue , R. D. , Pennell , K. D. , Rao , P. S. C. and Reve , W. H. 1989 . Competetive adsorption of alkylbenzene and water vapors on predominantly mineral surfaces . Chemosphere , 18 : 1971 – 1986 .
  • Okamura , J. P. and Sawyer , D. T. 1973 . Gas chromatographic studies of sorptive interactions of normal and halogenated hydrocarbons with water-modified soil, silica, and chromosorb W . Anal. Chem. , 45 : 80 – 84 .
  • Kim , H. , Annable , M. D. and Rao , P. S. C. 2001 . Gaseous transport of volatile organic chemicals in unsaturated porous media: Effect of water-partitioning and air–water interfacial adsorption . Environ. Sci. Technol. , 35 : 4457 – 4462 .
  • Israelachvili , J. N. 1992 . Intermolecular and surface forces , London : Academic Press .
  • Drost-Hansen , W. 1969 . Structure of water near solid interfaces . Ind. Eng. Chem. , 61 : 10 – 47 .
  • Sposito , G. and Prost , R. 1982 . Structure of water adsorbed on smectites . Chem. Rev. , 82 : 553 – 573 .
  • Wilson , M. A. , Pohorille , A. and Pratt , L. R. 1987 . Molecular dynamics of the water liquid–vapor interface . J. Phys. Chem. , 91 : 4873 – 4878 .
  • Hoekstra , P. and Doyle , W. T. 1971 . Dielectric relaxation of surface adsorbed water . J. Colloid Interface Sci. , 36 : 513 – 521 .
  • Attard , P. 1996 . Patterns of hydrogen bonding in water and ice . Physica A , 233 : 742 – 753 .
  • Atkinson , D. and Curthoys , G. 1978 . The determination of heats of adsorption by gas–solid chromatography . J. Chem. Educ. , 55 : 564 – 566 .
  • Vukov , A. and Gray , D. G. 1988 . “ Properties of carbon fiber surfaces ” . In Inverse gas chromatography , Toronto, , Canada : American Chemical Society .
  • Dorris , G. M. and Gray , D. G. 1981 . Adsorption of hydrocarbons on water-swollen cellulose . J. Chem. Soc. Faraday Trans. 1 , 77 : 725 – 740 .
  • Goss , K.-U. and Eisenreich , S. J. 1997 . Sorption of volatile organic compounds to particles from a combustion source at different temperatures and relative humidities . Atmos. Environ. , 31 : 2827 – 2834 .
  • Balard , H. , Aouadj , O. and Papirer , E. 1997 . Monitoring, by inverse gas chromatography, of the variation of the surface energetic heterogeneity of ground muscovite Samples . Langmuir , 13 : 1251 – 1255 .
  • Katsanos , N. , Iliopoulou , E. , Plagianakos , V. and Mangou , H. 2001 . Interrelations between adsorption energies and local isotherms, local monolayer capacities, and energy distribution functions, as determined for heterogeneous surfaces by inverse gas chromatography . J. Colloid Interface Sci. , 239 : 10 – 19 .
  • Balard , H. , Saada , A. , Papirer , E. and Siffert , B. 1997 . Energetic surface heterogeneity of illites and kaolinites . Langmuir , 13 : 1256 – 1259 .
  • Rhue , R. D. , Rao , P. S. C. and Smith , R. E. 1988 . Vapor-phase adsorption of alkylbenzenes and water on soils and clays . Chemosphere , 17 ( 4 ) : 727 – 741 .
  • Call , F. 1957 . The mechanisms of Sorption of ethylene dibromide on moist soils . J. Agric. Food Sci. , 8 : 630 – 639 .
  • Kömp , P. and McLachlan , M. S. 1997 . Influence of temperature on the plant/air partitioning of semivolatile organic compounds . Environ. Sci. Technol. , 31 ( 3 ) : 886 – 890 .
  • Gmehling , J. , Menke , J. and Schiller , M. 1994 . Activity coefficients at infinite dilution , Frankfurt : DECHEMA .
  • Petersen , L. W. , Moldrup , P. , El-Farhan , Y. H. , Jacobsen , O. H. , Yamaguchi , T. and Rolston , D. E. 1995 . The effect of moisture and soil texture on the adsorption of organic vapors . J. Environ. Qual. , 24 : 752 – 759 .
  • Mackay , D. , Shiu , W. Y. and Ma , K. C. 1992 . Illustrated handbook of physical-chemical properties and environmental fate for organic chemicals. , Boca Raton : Lewis .
  • Glotfelty , D. E. , Seiber , J. N. and Liljedahl , L. A. 1987 . Pesticides in fog . Nature , 325 : 602 – 605 .
  • Glotfelty , D. E. , Majewski , M. S. and Seiber , J. N. 1990 . Distribution of several organophosphorus insecticides and their oxygen analogues in a foggy atmosphere . Environ. Sci. Technol. , 24 : 353 – 357 .
  • Capel , P. D. , Gunde , R. , Zürcher , F. and Giger , W. 1990 . Carbon speciation and surface tension of fog . Environ. Sci. Technol. , 24 : 722 – 727 .
  • Capel , P. D. , Leuenberger , C. and Giger , W. 1991 . Hydrophobic organic chemicals in urban fog . Atmos. Environ. , 25 : 1335 – 1346 .
  • Sagebiel , J. C. and Seiber , J. N. 1993 . Studies on the occurrence and distribution of wood smoke marker compounds in foggy atmospheres . Environ. Toxicol. Chem. , 12 : 813 – 822 .
  • Drozd , J. , Vejrosta , J. , Novak , J. and Jönsson , J. A. 1982 . Spurious adsorption effects in headspace-gas determination of hydrocarbons in water . J. Chromatogr. , 245 : 185 – 192 .
  • Valsaraj , K. T. , Porter , J. L. , Liljenfeldt , E. K. and Springer , C. 1986 . Solvent sublation for the removal of hydrophobic chlorinated compounds from aqueous solutions . Water Res. , 20 : 1161 – 1175 .
  • Pankow , J. J. 1997 . Partitioning of semi-volatile organic compounds to the air/water interface . Atmos. Environ. , 31 ( 6 ) : 927 – 929 .
  • Valsaraj , K. T. , Thoma , G. J. , Reible , D. D. and Thibodeaux , L. J. 1993 . On the enrichment of hydrophobic organic compounds in fog droplets . Atmos. Environ , 27 : 203 – 210 .
  • Perona , M. J. 1992 . The solubility of hydrophobic compounds in aqueous droplets . Atmos. Environ. , 26 : 2549 – 2533 .
  • Valsaraj , K. T. 1988 . On the physico-chemical aspects of partitioning of non-polar hydrophobic organics at the air–water Interface . Chemosphere , 17 : 875 – 887 .
  • Simcik , M. F. 2004 . The importance of surface adsorption on the washout of semivolatile organic compounds by rain . Atmospher. Environ. , 38 : 491 – 501 .
  • Schwarzenbach , R. P. , Gschwend , P. M. and Imboden , D. M. 2002 . Environmental organic chemistry , 2nd ed. , Hoboken, NJ : John Wiley & Sons .
  • Barton , A. F. M. 1983 . CRC handbook of solubility parameters and other cohesion parameters , Boca Raton, FL : CRC Press .
  • Poerschmann , J. and Kopinke , F.-D. 2001 . Sorption of very hydrophobic organic compounds (VHOCs) on dissolved humic matter (DOM). 2. Measurement of sorption and application of a Flory–Huggins concept to interpret the data . Environ. Sci. Technol. , 35 : 1142 – 1148 .
  • Gray , D. G. 1977 . Gas chromatographic measurements of polymer structure and interactions . Prog. Polym. Sci. , 5 : 1 – 60 .
  • Braun , J.-M. and Guillet , J. E. 1976 . Study of polymers by inverse gas chromatography . Adv. Polym. Sci. , 21 : 107 – 145 .
  • Xing , B. , Pignatello , J. J. and Gigliotti , B. 1996 . Competitive sorption between atrazine and other organic compounds in soils and model sorbents . Environ. Sci. Technol. , 30 : 2432 – 2440 .
  • Xing , B. and Pignatello , J. J. 1997 . Dual-mode sorption of low polarity compounds in glassy poly(vinyl chloride) and soil organic matter . Environ. Sci. Technol. , 31 ( 3 ) : 792 – 799 .
  • Leboeuf , E. J. and Weber , W. J. 1997 . A distributed reactivity model for sorption by soils and sediments . Environ. Sci. Technol. , 31 : 1697 – 1702 .
  • Huang , W. , Young , T. M. , Schlautman , M. A. , Yu , H. and Weber , W. J. 1997 . A distributed reactivity model for sorption by soils and sediments. 9. General isotherm nonlinearity and applicability of the dual reactive domain model . Environ. Sci. Technol. , 31 : 1703 – 1710 .
  • Rogers , C. E. 1965 . “ Solubility and diffusivity ” . In Physics and chemistry of the organic solid state , Edited by: Fox , D. , Labes , M. M. and Weissberger , A. pp. 509 – 634 . New York : Interscience .
  • Berens , A. R. 1989 . Transport of organic vapors and liquids in poly(vinyl chloride) . Makromol. Chem. Macromol. Symp. , 29 : 95 – 108 .
  • Pawlisch , C. A. , Macris , A. and Laurence , R. L. 1987 . Solute diffusion in polymers. 1. The use of capillary column inverse gas chromatography . Macromolecules , 20 : 1564 – 1578 .
  • Schneider , N. S. , Moseman , J. A. and Sung , N.-H. 1994 . Toluene diffusion in butyl rubber . J. Polym. Sci. B , 32 : 491 – 499 .
  • Akim , E. L. 1978 . Cellulose—Bellwether or old hat . Chemtech. , : 676 – 682 .
  • Perrier , S. , Houdier , S. , Domine , F. , Cabanes , A. , Legagneux , L. , Sumner , A. L. and Shepson , P. B. 2002 . Formaldehyde in Arctic snow. Incorporation into ice particles and evolution in the snowpack . Atmos. Environ. , 36 : 2695 – 2705 .
  • Beaglehole , D. and Nason , D. 1980 . Transition layer on the surface on ice . Surf. Sci. , 96 : 357 – 363 .
  • Jellinek , H. H. G. 1967 . Liquid-like transition layer on ice . J. Colloid Interface Sci. , 25 : 192 – 205 .
  • Orem , M. W. and Adamson , A. W. 1969 . Physical adsorption of vapor on ice. 2. n-Alkanes . J. Colloid Interface Sci. , 31 : 278 – 286 .
  • Roth , C. , Goss , K.-U. and Schwarzenbach , R. P. 2003 . Sorption of diverse organic vapors to snow . Environ. Sci. Technol. ,
  • Hoff , J. T. , Gregor , D. , Mackay , D. , Wania , F. and Jia , C. Q. 1998 . Measurement of the Specific Surface Area of Snow with the Nitrogen Adsorption Technique . Environ. Sci. Technol. , 32 ( 1 ) : 58 – 62 .
  • Hanot , L. and Domine , F. 1999 . Evolution of the surface area of a snow layer . Environ. Sci. Technol. , 33 : 4250 – 4255 .
  • Domine , F. , Cabanes , A. , Taillandier , A.-S. and Legagneux , L. 2001 . Specific surface area of snow samples determined by CH4 adsorption at 77 K and estimated by optical microscopy and scanning electron microscopy . Environ. Sci. Technol. , 35 : 771 – 780 .
  • Cabanes , A. , Legagneux , L. and Domine , F. 2003 . Rate of evolution of the specific surface area of surface snow layers . Environ. Sci. Technol. , 37 : 661 – 666 .
  • Wania , F. 1997 . Modelling the fate of non-polar organic chemicals in an ageing snow pack . Chemosphere , 35 : 2345 – 2363 .
  • Wania , F. , Semkin , R. , Hoff , J. T. and Mackay , D. 1999 . Modelling the fate of non-polar organic chemicals during the melting of an arctic snowpack . Hydrol. Process. , 13 : 2245 – 2256 .
  • Wania , F. , Hoff , J. T. , Jia , C. Q. and Mackay , D. 1998 . The effects of snow and ice on the environmental behaviour of hydrophobic organic chemicals . Environ. Pollut. , 102 : 25 – 41 .
  • Lei , Y. D. and Wania , F. 2004 . Is rain or snow a more efficient scavenger of organic chemicals? . Atmos. Environ. ,
  • Jang , M. and Kamens , R. M. 1999 . A predictive model for adsorptive gas partitioning of SOCs on fine atmospheric inorganic dust particles . Environ. Sci. Technol. , 33 : 1825 – 1831 .
  • Penner , J. E. , Hegg , D. and Leaitch , R. 2001 . Unraveling the role of aerosols in climate change . Environ. Sci. Technol. , 35 : 332A – 340A .
  • Cotham , W. E. and Bidleman , T. F. 1995 . Polycyclic aromatic hydrocarbons and polychlorinated biphenyls in air at an urban and a rural site near Lake Michigan . Environ. Sci. Technol. , 29 : 2782 – 2789 .
  • Lohmann , R. , Harner , T. , Thomas , G. O. and Jones , K. C. 2000 . A comparative study of the gas–particle partitioning of PCDD/Fs, PCBs, and PAHs . Environ. Sci. Technol. , 34 : 4943 – 4951 .
  • Corn , M. , Montgomery , T. L. and Esmen , N. A. 1971 . Suspended particulate matter: Seasonal variation in specific surface areas and densities . Environ. Sci. Technol. , 5 : 155 – 158 .
  • Sheffield , A. E. and Pankow , J. F. 1994 . Specific surface area of urban atmospheric particulate matter in Portland, Oregon . Environ. Sci. Technol. , 28 : 1759 – 1766 .
  • Roth , C. 2004 . “ Sorption behavior of organic vapors in the atmosphere ” . In Department of Environmental Sciences , Zürich : Swiss Federal Institute of Technology .
  • Bennett , D. H. , Scheringer , M. , Kone , T. E. and Hungerbühler , K. 2001 . Predicting long-range transport: A systematic evaluation of two multimedia transport models . Environ. Sci. Technol. , 35 : 1181 – 1189 .
  • Junge , C. E. 1977 . “ Basic considerations about trace constituents in the atmosphere as related to the fate of global pollutants ” . In Fate of pollutants in the air and water environments , Edited by: Suffet , I. H. pp. 7 – 25 . New York : Wiley .
  • Shoeib , M. and Harner , T. 2002 . Using measured octanol–air partition coefficients to explain environmental partitioning of organochlorine pesticides . Environ. Toxicol. Chem. SETAC , 21 ( 5 ) : 984 – 990 .
  • Harner , T. and Bidleman , T. F. 1998 . Octanol–air partition coefficient for describing particle/gas partitioning of aromatic compounds in urban air . Environ. Sci. Technol. , 32 : 1494 – 1502 .
  • Finizio , A. , Mackay , D. , Bidleman , T. and Harner , T. 1997 . Octanol–air partitioning coefficients as a predictor of partitioning of semi-volatile organic chemicals to aerosols . Atmos. Environ. , 31 ( 15 ) : 2289 – 2296 .
  • Murphy , E. M. , Zachara , J. M. and Smith , S. C. 1990 . Influence of mineral-bound humic substances on the sorption of hydrophobic organic compounds . Environ. Sci. Technol. , 24 : 1507 – 1516 .
  • Schwarzenbach , R. P. and Westall , J. 1981 . Transport of nonpolar organic compounds from surface water to groundwater . Environ. Sci. Technol. , 15 : 1360 – 1367 .
  • Stauffer , T. B. and MacIntyre , W. G. 1986 . Sorption of low-polarity organic compounds on oxide minerals and aquifer material . Environ. Tox. Chem. , 5 : 949 – 955 .
  • Mader , B. T. , Goss , K.-U. and Eisenreich , S. J. 1997 . Sorption of nonionic, hydrophobic organic chemicals to mineral surfaces . Environ. Sci. Technol. , 31 ( 4 ) : 1079 – 1086 .
  • Graber , E. R. and Borisover , M. D. 1998 . Hydration-facilitated sorption of specifically interacting organic compounds by model soil organic matter . Environ. Sci. Technol. , 32 : 258 – 263 .
  • Borisover , M. and Graber , E. R. 2002 . Relationship between strength of organic sorbate interactions in NOM and hydration effect on sorption . Environ. Sci. Technol. , 36 : 4570 – 4577 .
  • Rutherford , D. W. and Chiou , C. T. 1992 . Effect of water saturation in soil organic matter on the partitioning of organic compounds . Environ. Sci. Technol. , 26 : 965 – 970 .
  • Goss , K.-U. , Buschmann , J. and Schwarzenbach , R. P. 2004 . Adsorption of organic vapors to air-dry soils: Model predictions and experimental validation . Environ. Sci. Technol. ,
  • Steinberg , S. M. , Schmeltzer , J. S. and Kreamer , D. K. 1996 . Sorption of benzene and trichloroethylene (TCE) on a Desert Soil: Effects of moisture and organic matter . Chemosphere , 33 ( 5 ) : 961 – 980 .
  • Lorden , S. W. , Chen , W. and Lion , L. W. 1998 . Experiments and modeling of the transport of trichloroethene vapor in unsaturated aquifer material . Environ. Sci. Technol. , 32 : 2009 – 2017 .
  • Chiou , C. T. , Shoup , T. D. and Porter , P. E. 1985 . Mechanistic roles of soil humus and minerals in the sorption of nonionic organic compounds from aqueous and organic solutions . Org. Geochem. , 8 : 9 – 14 .
  • Unger , D. R. , Thientu , T. L. , Schaefer , C. E. and Kosson , D. S. 1996 . Predicting the effect of moisture on vapor-phase sorption of volatile organic compounds to soils . Environ. Sci. Technol. , 30 : 1081 – 1091 .
  • Costanza , M. S. and Brusseau , M. L. 2000 . Contaminant vapor adsorption at the gas–water interface in soils . Environ. Sci. Technol. , 34 ( 1 ) : 1 – 11 .
  • Petersen , L. W. , Rolston , D. E. , Moldrup , P. and Yamaguchi , T. 1994 . Volatile organic vapor diffusion and adsorption in soils . J. Environ. Qual. , 23 : 799 – 805 .
  • Gerstl , Z. 1990 . Estimation of organic chemical sorption by soils . J. Contam. Hydrol. , 6 : 357 – 375 .
  • McLachlan , M. S. , Welsch-Pausch , K. and Tolls , J. 1995 . Field validation of a model of the uptake of gaseous SOC in lolium multiflorum (rye grass) . Environ. Sci. Technol. , 29 : 1998 – 2004 .
  • Göth , A. , McLean , I. G. and Trevelyan , J. 2003 . “ How do dogs detect landmines? ” . In Mine detection dogs: Training, operations and odour detection , Edited by: McLean , I. G. pp. 195 – 208 . Geneva : GICHD .
  • Wolters , A. , Kromer , T. , Linnemann , V. , Schaffer , A. and Vereecken , H. 2003 . A new tool for laboratory studies on volatilization: Extension of applicability of the photovolatility chamber . Environ. Toxicol. Chem. , 22 ( 4 ) : 791 – 797 .
  • Spencer , W. F. and Cliath , M. M. 1990 . “ Movement of pesticides from soil to the atmosphere ” . In Long range transport of pesticides , Edited by: Kurtz , D. A. pp. 1 – 16 . Chelsea : Lewis MI .
  • Grass , B. , Wenclawiak , B. W. and Rüdel , H. 1994 . Influence of air velocity, air temperature and air humidity on the volatilisation of trifluralin from soil . chemosphere , 28 ( 3 ) : 491 – 499 .
  • Majewski , M. , Desjardins , R. , Rochette , P. , Pattey , E. , Seiber , J. and Glotfelty , D. 1993 . Field comparison of an eddy accumulation and an aerodynamic-gradient system for measuring pesticide volatilization fluxes . Environ. Sci. Technol. , 27 : 121 – 128 .
  • Spencer , F. W. 1987 . “ Volatilization of pesticide residues ” . In Fate of pesticides in the environment , Edited by: Bigger , J. W. and Seiber , J. N. pp. 61 – 68 . Division of Agriculture and Natural Resources, University of California .
  • Harris , C. R. 1964 . Influence of soil type and soil moisture on the toxicity of insecticides in soils to insects . Nature , 202 : 724
  • Wania , F. and McLachlan , M. S. 2001 . Estimating the influence of forests on the overall fate of semivolatile organic compounds using a multimedia model . Environ. Sci. Technol. , 35 : 582 – 590 .
  • McLachlan , M. S. and Horstmann , M. 1998 . Forests as filters of airborne organic pollutants: A Model . Environ. Sci. Technol. , 32 : 413 – 420 .

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