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Original Articles

Heterogeneous Photocatalysis as an Advanced Oxidation Process for the Abatement of Chlorinated, Monocyclic Aromatic and Sulfurous Volatile Organic Compounds in Air: State of the Art

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Pages 489-538 | Published online: 05 Sep 2007

REFERENCES

  • Agrios , A. G. and Pichat , P. 2005 . State of the art and perspectives on materials and applications of photocatalysis over TiO2 . J. Appl. Electrochem. , 35 : 655 – 663 .
  • Alberici , R. M. and Jardim , W. F. 1997 . Photocatalytic destruction of VOCs in the gas-phase using TiO2 . Appl. Catal. B Environ. , 14 : 55 – 68 .
  • Alberici , R. M. , Mendes , M. A. , Jardim , W. F. and Eberlin , M. N. 1998 . Mass spectrometry on-line monitoring and MS2 product characterization of TiO2/UV photocatalytic degradation of chlorinated volatile organic compounds . J. Am. Soc. Mass Spectrom. , 9 : 1321 – 1327 .
  • Amama , P. B. , Itoh , K. and Murabayashi , M. 2001 . Photocatalytic oxidation of trichloroethylene in humidified atmosphere . J. Mol. Catal. A Chem. , 176 : 165 – 172 .
  • Amama , P. B. , Itoh , K. and Murabayashi , M. 2002 . Gas-phase photocatalytic degradation of trichloroethylene on pretreated TiO2 . Appl. Catal. B Environ. , 37 : 321 – 330 .
  • Amama , P. B. , Itoh , K. and Murabayashi , M. 2004 . Photocatalytic degradation of trichloroethylene in dry and humid atmospheres: Role of gas-phase reactions . J. Mol. Catal. A Chem. , 217 : 109 – 115 .
  • Ameen , M. M. and Raupp , G. B. 1999 . Reversible catalyst deactivation in the photocatalytic oxidation of dilute o-xylene in air . J. Catal. , 184 : 112 – 122 .
  • Annapragada , R. , Leet , R. , Changrani , R. and Raupp , G. B. 1997 . Vacuum photocatalytic degradation of trichloroethylene . Environ. Sci. Technol. , 31 : 1898 – 1901 .
  • Ao , C. H. and Lee , S. C. 2003 . Enhancement effect of TiO2 immobilized on activated carbon filter for the photodegradation of pollutants at typical indoor air level . Appl. Catal. B Environ. , 44 : 191 – 205 .
  • Ao , C. H. , Lee , S. C. , Mak , C. L. and Chan , L. Y. 2003 . Photodegradation of volatile organic compounds (VOCs) and NO for indoor air purification using TiO2: Promotion versus inhibition effect of NO . Appl. Catal. B Environ. , 42 : 119 – 129 .
  • Ao , C. H. and Lee , S. C. 2004 . Combination effect of activated carbon with TiO2 for the photodegradation of binary pollutants at typical indoor level . J. Photochem. Photobiol. A Chem. , 161 : 131 – 140 .
  • Ao , C. H. , Lee , S. C. , Zou , S. C. and Mak , C. L. 2004 . Inhibition effect of SO2 on NOx and VOCs during the photodegradation of synchronous indoor air pollutants at parts per billion (ppb) level by TiO2 . Appl. Catal. B Environ. , 49 : 187 – 193 .
  • Ao , C. H. and Lee , S. C. 2005 . Indoor air purification by photocatalyst TiO2 immobilized on an activated carbon filter installed in an air cleaner . Chem. Eng. Sci. , 60 : 103 – 109 .
  • Augugliaro , V. , Coluccia , S. , Loddo , V. , Marchese , L. , Martra , G. , Palmisano , L. and Schiavello , M. 1999 . Photocatalytic oxidation of gaseous toluene on anatase TiO2 catalyst: mechanistic aspects and FT-IR investigation . Appl. Catal. B Environ. , 20 : 15 – 27 .
  • Avila , P. , Bahamonde , A. , Blanco , J. , Sánchez , B. , Cardona , A. I. and Romero , M. 1998 . Gas-phase photo-assisted mineralization of volatile organic compounds by monolythic titania catalysts . Appl. Catal. B Environ. , 17 : 75 – 88 .
  • Belver , C. , López-Muñoz , M. J. , Coronado , J. M. and Soria , J. 2003 . Palladium enhanced resistance to deactivation of titanium dioxide during the photocatalytic oxidation of toluene vapors . Appl. Catal. B Environ. , 46 : 497 – 509 .
  • Bhatkhande , D. S. , Pangarkar , V. G. and Beenackers , A. A.C.M. 2001 . Photocatalytic degradation for environmental applications—A review . J. Chem. Technol. Biotechnol. , 77 : 102 – 116 .
  • Blake , D. M. , Maness , P. , Huang , Z. , Wolfrum , E. J. and Huang , J. 1999 . Application of the photocatalytic chemistry of titanium dioxide to disinfection and the killing of cancer cells . Sep. Purif. Technol. , 28 : 1 – 50 .
  • Blake , D. M. 2001 . Bibliography of work on the heterogeneous photocatalytic removal of hazardous compounds from water and air (Updat Number 4 to October 2001) , Golden, CO : National Renewable Energy Laboratory . Technical report
  • Blount , M. C. and Falconer , J. L. 2001 . Characterization of adsorbed species on TiO2 after photocatalytic oxidation of toluene . J. Catal. , 200 : 21 – 33 .
  • Blount , M. C. and Falconer , J. L. 2002 . Steady-state surface species during toluene photocatalysis . Appl. Catal. B Environ. , 39 : 39 – 50 .
  • Borisch , J. , Pilkenton , S. , Miller , M. L. , Raftery , D. and Francisco , J. S. 2004 . TiO2 photocatalytic degradation of dichloromethane: An FTIR and solid-state NMR study . J. Phys. Chem. B , 108 : 5640 – 5646 .
  • Bouzaza , A. and Laplanche , A. 2002 . Photocatalytic degradation of toluene in gas phase: comparative study of some TiO2 supports . J. Photochem. Photobiol. A Chem. , 150 : 207 – 212 .
  • Buechler , K. J. , Noble , R. D. , Koval , C. A. and Jacoby , W. A. 1999 . Investigation of the effects of controlled periodic illumination on the oxidation of gaseous trichloroethylene using a thin film of TiO2 . Ind. Eng. Chem. Res. , 38 : 892 – 896 .
  • Calvert , J. G. 1994 . Chemistry for the 21st century. The chemistry of the atmosphere: its impact on global change , Oxford : Blackwell Scientific Publications .
  • Canela , M. C. , Alberici , R. M. , Sofia , R. C.R. , Eberlin , M. N. and Jardim , W. F. 1999 . Destruction of malodorous compounds using heterogeneous photocatalysis . Environ. Sci. Technol. , 33 : 2788 – 2792 .
  • Cao , L. , Huang , A. , Spiess , F. and Suib , S. L. 1999 . Gas-phase oxidation of 1-butene using nanoscale TiO2 photocatalysts . J. Catal. , 188 : 48 – 57 .
  • Cao , L. , Gao , Z. , Suib , S. L. , Obee , T. N. , Hay , S. O. and Freihaut , J. D. 2000 . Photocatalytic oxidation of toluene on nanoscale TiO2 catalysts: Studies of deactivation and regeneration . J. Catal. , 196 : 253 – 261 .
  • De Bo , I. , Heyman , J. , Vincke , J. , Verstraete , W. and Van Langenhove , H. 2003 . Dimethyl sulfide removal from synthetic waste gas using a flat poly(dimethylsiloxane)-coated composite membrane bioreactor . Environ. Sci. Technol. , 37 : 4228 – 4234 .
  • Defoer , N. , De Bo , I. , Van Langenhove , H. , Dewulf , J. and Van Elst , T. 2002 . Gas chromatography-mass spectrometry as a tool for estimating odour concentrations of biofilter effluents at aerobic composting and rendering plants . J. Chromatogr. A , 970 : 259 – 273 .
  • Demeestere , K. , Dewulf , J. , Van Langenhove , H. and Sercu , B. 2003 . Gas–solid adsorption of selected volatile organic compounds on titanium dioxide Degussa P25 . Chem. Eng. Sci. , 58 : 2255 – 2267 .
  • Demeestere , K. , De Visscher , A. , Dewulf , J. , Van Leeuwen , M. and Van Langenhove , H. 2004 . A new kinetic model for titanium dioxide mediated heterogeneous photocatalytic degradation of trichloroethylene in gas-phase . Appl. Catal. B Environ. , 54 : 261 – 274 .
  • Demeestere , K. , Dewulf , J. , De Witte , B. and Van Langenhove , H. 2005a . Titanium dioxide mediated heterogeneous photocatalytic degradation of gaseous dimethyl sulfide: parameter study and reaction pathways . Appl. Catal. B Environ. , 60 : 93 – 106 .
  • Demeestere , K. , Dewulf , J. , Ohno , T. , Herrera Salgado , P. and Van Langenhove , H. 2005b . Visible light mediated photocatalytic degradation of gaseous trichloroethylene and dimethyl sulfide on modified titanium dioxide . Appl. Catal. B Environ. , 61 : 140 – 149 .
  • Deng , X. , Yue , Y. and Gao , Z. 2002 . Gas-phase photo-oxidation of organic compounds over nanosized TiO2 photocatalysts by various preparations . Appl. Catal. B Environ. , 39 : 135 – 147 .
  • d'Hennezel , O. and Ollis , D. F. 2001 . Surface prechlorination of anatase TiO2 for enhanced photocatalytic oxidation of toluene and hexane . Helv. Chim. Acta , 84 : 3511 – 3518 .
  • d'Hennezel , O. , Pichat , P. and Ollis , D. F. 1998 . Benzene and toluene gas-phase photocatalytic degradation over H2O and HCl pretreated TiO2: By-products and mechanisms . J. Photochem. Photobiol. A Chem. , 118 : 197 – 204 .
  • Dibble , L. A. and Raupp , G. B. 1990 . Kinetics of the gas–solid heterogeneous photocatalytic oxidation of trichloroethylene by near UV illuminated titanium-dioxide . Catal. Lett. , 4 : 345 – 354 .
  • Disdier , J. , Pichat , P. and Mas , D. 2005 . Measuring the effect of photocatalytic purifiers on indoor air hydrocarbons and carbonyl pollutants . J. Air Waste Manage. Assoc. , 55 : 88 – 96 .
  • Dombi , A. , Fekete , Z. A. and Kiricsi , I. 2000 . In situ photocatalytic reactor with FT-IR analysis for heterogeneous catalytic studies . Appl. Catal. A Gen. , 193 : L5 – L8 .
  • Driessen , M. D. , Goodman , A. L. , Miller , T. M. , Zaharias , G. A. and Grassian , V. H. 1998 . Gas-phase photooxidation of trichloroethylene on TiO2 and ZnO: Influence of trichloroethylene pressure, oxygen pressure, and the photocatalyst surface on the product distribution . J. Phys. Chem. B , 102 : 549 – 556 .
  • Driessen , M. D. and Grassian , V. H. 1998 . Photooxidation of trichloroethylene on Pt/TiO2 . J. Phys. Chem. B , 102 : 1418 – 1423 .
  • Dvorak , B. I. , Herbeck , C. J. , Meurer , C. P. , Lawler , D. F. and Speitel , G. E. 1996 . Selection among aqueous and off-gas treatment technologies for synthetic organic chemicals . J. Environ. Eng. ASCE , 122 : 571 – 580 .
  • Einaga , H. , Futamura , S. and Ibusuki , T. 1999 . Photocatalytic decomposition of benzene over TiO2 in a humidified airstream . Phys. Chem. Chem. Phys. , 1 : 4903 – 4908 .
  • Einaga , H. , Futamura , S. and Ibusuki , T. 2001 . Complete oxidation of benzene in gas phase by platinized titania photocatalysts . Environ. Sci. Technol. , 35 : 1880 – 1884 .
  • Einaga , H. , Futamura , S. and Ibusuki , T. 2002 . Heterogeneous photocatalytic oxidation of benzene, toluene, cyclohexene and cyclohexane in humidified air: Comparison of decomposition behaviour on photoirradiated TiO2 catalysts . Appl. Catal. B Environ. , 38 : 215 – 225 .
  • Forst , L. and Conroy , L. M. 1998 . “ Health effects and exposure assessments of VOCs ” . In Odor and VOC control handbook , Edited by: Rafson , H. J. 3.1 – 3.27 . New York : McGraw-Hill .
  • Fotou , G. P. and Pratsinis , S. 1996 . Photocatalytic destruction of phenol and salicylic acid with aerosol-made and commercial titania powders . Chem. Eng. Commun. , 151 : 251 – 269 .
  • Fox , M. A. and Dulay , M. T. 1993 . Heterogeneous photocatalysis . Chem. Rev. , 93 : 341 – 357 .
  • Fu , X. , Zeltner , W. A. and Anderson , M. A. 1996 . “ Applications in photocatalytic purification of air ” . In Semiconductor nanoclusters. Studies in surface science and catalysis , Edited by: Kamat , P. V. and Meisel , D. 445 – 461 . Amsterdam : Elsevier Science .
  • Fukami , N. , Yosida , M. , Lee , B. D. , Taku , K. and Hosomi , M. 2001 . Photocatalytic degradation of gaseous perchloroethylene: products and pathway . Chemosphere , 42 : 345 – 350 .
  • González-Garcia , N. , Ayllón , J. A. , Doménech , X. and Peral , J. 2004 . TiO2 deactivation during the gas-phase photocatalytic oxidation of dimethyl sulfide . Appl. Catal. B Environ. , 52 : 69 – 77 .
  • Guo-Min , Z. , Zhen-Xing , C. , Min , X. and Xian-Qing , Q. 2003 . Study on the gas-phase photolytic and photocatalytic oxidation of trichloroethylene . J. Photochem. Photobiol. A Chem. , 161 : 51 – 56 .
  • Hager , S. and Bauer , R. 1999 . Heterogeneous photocatalytic oxidation of organics for air purification by near UV irradiated titanium dioxide . Chemosphere , 38 : 1549 – 1559 .
  • Hager , S. , Bauer , R. and Kudielka , G. 2000 . Photocatalytic oxidation of gaseous chlorinated organics over titanium dioxide . Chemosphere , 41 : 1219 – 1225 .
  • Hamill , N. A. , Hardacre , C. , Barth , J. A.C. , Kalin , R. M. and Cunningham , J. F. 2001 . Gas-phase photocatalytic oxidation of dichlorobutenes . Environ. Sci. Technol. , 35 : 2823 – 2827 .
  • Hegedüs , M. and Dombi , A. 2004a . Comparative study of heterogeneous photocatalytic decomposition of tetrachloroethylene and trichloroethylene in the gas phase . Appl. Catal. A Gen. , 271 : 177 – 184 .
  • Hegedüs , M. and Dombi , A. 2004b . Gas-phase heterogeneous photocatalytic oxidation of chlorinated ethenes over titanium dioxide: Perchloroethylene . Appl. Catal. B Environ. , 53 : 141 – 151 .
  • Hegedüs , M. , Dombi , A. and Kiricsi , I. 2001 . Photocatalytic decomposition of tetrachloroethylene in the gas phase with titanium dioxide as catalyst . React. Kinet. Catal. Lett. , 74 : 209 – 215 .
  • Hoffmann , M. R. , Martin , S. T. , Choi , W. and Bahnemann , D. F. 1995 . Environmental applications of semiconductor photocatalysis . Chem. Rev. , 95 : 69 – 96 .
  • Huang , W. , Tang , X. , Wang , Y. , Koltypin , Y. and Gedanken , A. 2000 . Selective synthesis of anatase and rutile via ultrasound irradiation . Chem. Commun. , 2000 : 1415 – 1416 .
  • Hung , C. H. and Mariñas , B. J. 1997a . Role of chlorine and oxygen in the photocatalytic degradation of trichloroethylene vapor on TiO2 films . Environ. Sci. Technol. , 31 : 562 – 568 .
  • Hung , C. H. and Mariñas , B. J. 1997b . Role of water in the photocatalytic degradation of trichloroethylene vapor on TiO2 films . Environ. Sci. Technol. , 31 : 1440 – 1445 .
  • Hunter , P. and Oyama , S. T. 2000 . Control of volatile organic compound emissions: Conventional and emerging technologies , New York : John Wiley & Sons, Inc. .
  • Hwang , S. J. , Petucci , C. and Raftery , D. 1998 . In situ solid-state NMR studies of trichloroethylene photocatalysis: Formation and characterization of surface-bound intermediates . J. Am. Chem. Soc. , 120 : 4388 – 4397 .
  • Ibrahim , H. and de Lasa , H. 1999 . Novel photocatalytic reactor for the destruction of airborne pollutants reaction kinetics and quantum yields . Ind. Eng. Chem. Res. , 38 : 3211 – 3217 .
  • Jeong , J. , Sekiguchi , K. and Sakamoto , K. 2004 . Photochemical and photocatalytic degradation of gaseous toluene using short-wavelength UV irradiation with TiO2 catalysts: comparison of three UV sources . Chemosphere , 57 : 663 – 671 .
  • Jeong , J. , Sekiguchi , K. , Lee , W. and Sakamoto , K. 2005 . Photodegradation of gaseous volatile organic compounds (VOCs) using TiO2 photoirradiated by an ozone-producing UV lamp: decomposition characteristics, identification of by-products and water-soluble organic intermediates . J. Photochem. Photobiol. A Chem. , 169 : 279 – 287 .
  • Jo , W. K. , Park , J. H. and Chun , H. D. 2002 . Photocatalytic destruction of VOCs for in-vehicle air cleaning . J. Photochem. Photobiol. A Chem. , 148 : 109 – 119 .
  • Jo , W. K. and Park , K. H. 2004 . Heterogeneous photocatalysis of aromatic and chlorinated volatile organic compounds (VOCs) for nonoccupational indoor air application . Chemosphere , 57 : 555 – 565 .
  • Jung , K. Y. and Park , S. B. 1999 . Anatase-phase titania: Preparation by embedding silica and photocatalytic activity for the decomposition of trichloroethylene . J. Photochem. Photobiol. A Chem. , 127 : 117 – 122 .
  • Kennes , C. , Veiga , M. C. and Prado , O. 2001 . “ Nonbiological treatment technologies ” . In Bioreactors for waste gas treatment , Edited by: Kennes , C. and Veiga , M. C. 17 – 46 . Dordrecht : Kluwer Academic Publishers .
  • Keshmiri , M. , Mohseni , M. and Troczynski , T. 2004 . Development of novel TiO2 sol-gel-derived composite and its photocatalytic activities for trichloroethylene oxidation . Appl. Catal. B Environ. , 53 : 209 – 219 .
  • Kim , S. B. and Hong , S. C. 2002 . Kinetic study for photocatalytic degradation of volatile organic compounds in air using thin film TiO2 photocatalyst . Appl. Catal. B Environ. , 35 : 305 – 315 .
  • Kim , S. B. , Hwang , H. T. and Hong , S. C. 2002 . Photocatalytic degradation of volatile organic compounds at the gas–solid interface of a TiO2 photocatalyst . Chemosphere , 48 : 437 – 444 .
  • Kim , J. S. , Itoh , K. and Murabayashi , M. 1998 . Photocatalytic degradation of trichloroethylene in the gas phase over TiO2 sol-gel films: Analysis of products . Chemosphere , 36 : 483 – 495 .
  • Kim , J. S. , Itoh , K. , Murabayashi , M. and Kim , B. A. 1999 . Pretreatment of the photocatalyst and the photocatalytic degradation of trichloroethylene in the gas-phase . Chemosphere , 38 : 2969 – 2978 .
  • Kozlov , D. V. , Vorontsov , A. V. , Smirniotis , P. G. and Savinov , E. N. 2003 . Gas-phase photocatalytic oxidation of diethyl sulfide over TiO2: Kinetic investigations and catalyst deactivation . Appl. Catal. B Environ. , 42 : 77 – 87 .
  • Ku , Y. , Ma , C. M. and Shen , Y. S. 2001 . Decomposition of gaseous trichloroethylene in a photoreactor with TiO2-coated nonwoven fiber textile . Appl. Catal. B Environ. , 34 : 181 – 190 .
  • Larson , R. B. and Weber , E. J. 1994 . Reaction mechanisms in environmental organic chemistry , Boca Raton, FL : Lewis .
  • Lee , B. Y. , Park , S. H. , Kang , M. , Lee , S. C. and Choung , S. J. 2003 . Preparation of Al/TiO2 nanometer photo-catalyst film and the effect of H2O addition on photo-catalytic performance for benzene removal . Appl. Catal. A Gen. , 253 : 371 – 380 .
  • Lewandowski , M. and Ollis , D. F. 2003a . A two-site kinetic model simulating apparent deactivation during photocatalytic oxidation of aromatics on titanium dioxide (TiO2) . Appl. Catal. B Environ. , 43 : 309 – 327 .
  • Lewandowski , M. and Ollis , D. F. 2003b . Extension of a two-site transient kinetic model of TiO2 deactivation during photocatalytic oxidation of aromatics: Concentration variations and catalyst regeneration studies . Appl. Catal. B Environ. , 45 : 223 – 238 .
  • Lichtin , N. N. and Sadeghi , M. 1998 . Oxidative photocatalytic degradation of benzene vapor over TiO2 . J. Photochem. Photobiol. A Chem. , 113 : 81 – 88 .
  • Lim , T. H. and Kim , S. D. 2004 . Trichloroethylene degradation by photocatalysis in annular flow and annulus fluidized bed photoreactors . Chemosphere , 54 : 305 – 312 .
  • Liu , H. , Cheng , S. , Zhang , J. , Cao , C. and Jiang , W. 1997 . The gas-photocatalytic degradation of trichloroethylene without water . Chemosphere , 35 : 2881 – 2889 .
  • Maira , A. J. , Coronado , J. M. , Augugliaro , V. , Yeung , K. L. , Conesa , J. C. and Soria , J. 2001a . Fourier transform infrared study of the performance of nanostructured TiO2 particles for the photocatalytic oxidation of gaseous toluene . J. Catal. , 202 : 413 – 420 .
  • Maira , A. J. , Lau , W. N. , Lee , C. Y. , Yue , P. L. , Chan , C. K. and Yeung , K. L. 2003 . Performance of a membrane-catalyst for photocatalytic oxidation of volatile organic compounds . Chem. Eng. Sci. , 58 : 959 – 962 .
  • Maira , A. J. , Yeung , K. L. , Soria , J. , Coronado , J. M. , Belver , C. , Lee , C. Y. and Augugliaro , V. 2001b . Gas-phase photo-oxidation of toluene using nanometer-size TiO2 catalysts . Appl. Catal. B Environ. , 29 : 327 – 336 .
  • Marcí , G. , Addamo , M. , Augugliaro , V. , Coluccia , S. , García-López , E. , Loddo , V. , Martra , G. , Palmisano , L. and Schiavello , M. 2003 . Photocatalytic oxidation of toluene on irradiated TiO2: Comparison of degradation performance in humidified air, in water and in water containing a zwitterionic surfactant . J. Photochem. Photobiol. A Chem. , 160 : 105 – 114 .
  • Martra , G. , Coluccia , S. , Marchese , L. , Augugliaro , V. , Loddo , V. , Palmisano , L. and Schiavello , M. 1999 . The role of H2O in the photocatalytic oxidation of toluene in vapour phase on anatase TiO2 catalyst: A FTIR study . Catal. Today , 53 : 695 – 702 .
  • Martyanov , I. N. and Klabunde , K. J. 2003 . Photocatalytic oxidation of gaseous 2-chloroethyl ethyl sulfide over TiO2 . Environ. Sci. Technol. , 37 : 3448 – 3453 .
  • Méndez-Román , R. and Cardona-Martínez , N. 1998 . Relationship between the formation of surface species and catalyst deactivation during the gas-phase photocatalytic oxidation of toluene . Catal. Today , 40 : 353 – 365 .
  • Mills , A. and Le Hunte , S. 1997 . An overview of semiconductor photocatalysis . J. Photochem. Photobiol. A Chem. , 108 : 97 – 101 .
  • Mohseni , M. and David , A. 2003 . Gas phase vinyl chloride (VC) oxidation using TiO2-based photocatalysis . Appl. Catal. B Environ. , 46 : 219 – 228 .
  • Mohseni , M. and Taghipour , F. 2004 . Experimental and CFD analysis of photocatalytic gas phase vinyl chloride (VC) oxidation . Chem. Eng. Sci. , 59 : 1601 – 1609 .
  • Muggli , D. S. , Odland , M. J. and Schmidt , L. R. 2001 . Effect of trichloroethylene on the photocatalytic oxidation of methanol on TiO2 . J. Catal. , 203 : 51 – 63 .
  • Nishikawa , H. and Takahara , Y. 2001 . Adsorption and photocatalytic decomposition of odor compounds containing sulfur using TiO2/SiO2 bead . J. Mol. Catal. A Chem. , 172 : 247 – 251 .
  • Nozawa , M. , Tanigawa , K. , Hosomi , M. , Chikusa , T. and Kawada , E. 2001 . Removal and decomposition of malodorants by using titanium dioxide photocatalyst supported on fiber activated carbon . Water Sci. Technol. , 44 : 127 – 133 .
  • Ohko , Y. , Ikeda , K. , Rao , T. N. , Hashimoto , K. and Fujishima , A. 1999 . Photocatalytic reaction kinetics on TiO2 thin films under light-limited and mass transport-limited conditions . Z. Phys. Chem. , 213 : 33 – 42 .
  • Ozaki , S. , Zhao , L. H. , Amemiya , T. , Itoh , K. and Murabayashi , M. 2004 . Gas-phase photocatalytic degradation of cis-1,2-dichloroethylene using titanium dioxide under near-UV-illumination . Appl. Catal. B Environ. , 52 : 81 – 89 .
  • Palmisano , L. and Sclafani , A . 1997 . “ Thermodynamics and kinetics for heterogeneous photocatalytic processes ” . In Heterogeneous photocatalysis , Edited by: Schiavello , M. 109 – 132 . Chichester : Wiley & Sons .
  • Pelizzetti , E. and Minero , C. 1993 . Mechanism of the photo-oxidative degradation of organic pollutants over TiO2 particles . Electrochim. Acta , 38 : 47 – 55 .
  • Pengyi , Z. , Fuyan , L. , Gang , Y. , Qing , C. and Wanpeng , Z. 2003 . A comparative study on decomposition of gaseous toluene by O3/UV, TiO2/UV and O3/TiO2/UV . J. Photochem. Photobiol. A Chem. , 156 : 189 – 194 .
  • Peral , J. , Domènech , X. and Ollis , D. F. 1997 . Heterogeneous photocatalysis for purification, decontamination and deodorization of air . J. Chem. Technol. Biotechnol. , 70 : 117 – 140 .
  • Peral , J. and Ollis , D. F. 1997 . TiO2 photocatalyst deactivation by gas-phase oxidation of heteroatom organics . J. Mol. Catal. A Chem. , 115 : 347 – 354 .
  • Petlicki , J. and van de Ven , T. G.M. 1998 . The equilibrium between the oxidation of hydrogen peroxide by oxygen and the dismutation of peroxyl or superoxide radicals in aqueous solutions in contact with oxygen . J. Chem. Soc. Faraday Trans. , 94 : 2763 – 2767 .
  • Pichat , P. , Disdier , J. , Hoang-Van , C. , Mas , D. , Goutailler , G. and Gaysse , C. 2000 . Purification/deodorization of indoor air and gaseous effluents by TiO2 photocatalysis . Catal. Today , 63 : 363 – 369 .
  • Prousek , J. 1996 . Advanced oxidation processes for water treatment. Photochemical processes . Chem. Listy , 90 : 307 – 315 .
  • Rice , C. V. and Raftery , D. 1999 . Photocatalytic oxidation of trichloroethylene using TiO2 coated optical microfibres . Chem. Commun. , 1999 : 895 – 896 .
  • Sánchez , B. , Cardona , A. I. , Romero , M. , Avila , P. and Bahamonde , A. 1999 . Influence of temperature on gas-phase photo-assisted mineralization of TCE using tubular and monolithic catalysts . Catal. Today , 54 : 369 – 377 .
  • Sano , T. , Negishi , N. , Kutsuna , S. and Takeuchi , K. 2001 . Photocatalytic mineralization of vinyl chloride on TiO2 . J. Mol. Catal. A Chem. , 168 : 233 – 240 .
  • Sano , T. , Kutsuna , S. , Negishi , N. and Takeuchi , K. 2002 . Effect of Pd-photodeposition over TiO2 on product selectivity in photocatalytic degradation of vinyl chloride monomer . J. Mol. Catal. A Chem. , 189 : 263 – 270 .
  • Sattler , M. L. and Liljestrand , H. M. 2003 . Method for predicting photocatalytic oxidation rates of organic compounds . J. Air Waste Manage. Assoc. , 53 : 3 – 12 .
  • Sclafani , A. and Herrmann , J. M. 1996 . Comparison of the photoelectronic and photocatalytic activities of various anatase and rutile forms of titania in pure liquid organic phases and in aqueous solutions . J. Phys. Chem. , 100 : 13655 – 13661 .
  • Shen , Y. S. and Ku , Y. 2002 . Decomposition of gas-phase trichloroethylene by the UV/TiO2 process in the presence of ozone . Chemosphere , 46 : 101 – 107 .
  • Smet , E. , Lens , P. and Van Langenhove , H. 1998 . Treatment of waste gases contaminated with odorous sulfur compounds . Crit. Rev. Environ. Sci. Technol. , 28 : 89 – 117 .
  • Strini , A. , Cassese , S. and Schiavi , L. 2005 . Measurement of benzene, toluene, ethylbenzene and o-xylene gas phase photodegradation by titanium dioxide dispersed in cementitious materials using a mixed flow reactor . Appl. Catal. B Environ. , 61 : 90 – 97 .
  • Sun , R. , Nakajima , A. , Watanabe , I. , Watanabe , T. and Hashimoto , K. 2000 . TiO2-coated optical fiber bundles used as a photocatalytic filter for decomposition of gaseous organic compounds . J. Photochem. Photobiol. A Chem. , 136 : 111 – 116 .
  • Van Craeynest , K. , Van Langenhove , H. and Stuetz , R. M. 2004 . “ AOPs for VOCs and odor treatment ” . In Advanced oxidation processes for water and wastewater treatment , Edited by: Parsons , S. 275 – 301 . London : IWA Publishing .
  • Vorontsov , A. V. , Lion , C. , Savinov , E. N. and Smirniotis , P. G. 2003a . Pathways of photocatalytic gas phase destruction of HD simulant 2-chloroethyl ethyl sulfide . J. Catal. , 220 : 414 – 423 .
  • Vorontsov , A. V. , Panchenko , A. A. , Savinov , E. N. , Lion , C. and Smirniotis , P. G. 2002 . Photocatalytic degradation of 2-phenethyl-2-chloroethyl sulfide in liquid and gas phases . Environ. Sci. Technol. , 36 : 5261 – 5269 .
  • Vorontsov , A. V. , Savinov , E. V. , Davydov , L. and Smirniotis , P. G. 2001 . Photocatalytic destruction of gaseous diethyl sulfide over TiO2 . Appl. Catal. B Environ. , 32 : 11 – 24 .
  • Vorontsov , A. V. , Savinov , E. N. , Lion , C. and Smirniotis , P. G. 2003b . TiO2 reactivation in photocatalytic destruction of gaseous diethyl sulfide in a coil reactor . Appl. Catal. B Environ. , 44 : 25 – 40 .
  • Wang , K. H. and Hsieh , Y. H. 1998 . Heterogeneous photocatalytic degradation of trichloroethylene in vapor phase by titanium dioxide . Environ. Int. , 24 : 267 – 274 .
  • Wang , K. H. , Hsieh , Y. H. , Lin , C. H. and Chang , C. Y. 1999 . The study of the photocatalytic degradation kinetics for dichloroethylene in vapor phase . Chemosphere , 39 : 1371 – 1384 .
  • Wang , K. H. , Jehng , J. M. , Hsieh , Y. H. and Chang , C. Y. 2002 . The reaction pathway for the heterogeneous photocatalysis of trichloroethylene in gas phase . J. Hazard. Mater. , B90 : 63 – 75 .
  • Wang , W. and Ku , Y. 2003 . Photocatalytic degradation of gaseous benzene in air streams by using an optical fiber photoreactor . J. Photochem. Photobiol. A Chem. , 159 : 47 – 59 .
  • Wang , K. H. , Tsai , H. H. and Hsieh , Y. H. 1998a . The kinetics of photocatalytic degradation of trichloroethylene in gas phase over TiO2 supported on glass bead . Appl. Catal. B Environ. , 17 : 313 – 320 .
  • Wang , K. H. , Tsai , H. H. and Hsieh , Y. H. 1998b . A study of photocatalytic degradation of trichloroethylene in vapor phase on TiO2 photocatalyst . Chemosphere , 36 : 2763 – 2773 .
  • Watt , A. S. , Magrini , K. A. , Carlson , L. E. , Wolfrum , E. J. , Larson , S. A. , Roth , C. and Glatzmaier , G. C. 1999 . Pilot-scale demonstration of an innovative treatment for vapor emissions . J. Air Waste Manage. Assoc. , 49 : 1368 – 1373 .
  • Wittmann , G. , Demeestere , K. , Dombi , A. , Dewulf , J. and Van Langenhove , H. 2005 . Preparation, structural characterization and photocatalytic activity of mesoporous Ti-silicates . Appl. Catal. B Environ. , 61 : 47 – 57 .
  • Wolfrum , E. J. , Huang , J. , Blake , D. M. , Maness , P. , Huang , Z. , Fiest , J. and Jacoby , W. A. 2002 . Photocatalytic oxidation of bacteria, bacterial and fungal spores, and model biofilm components to carbon dioxide on titanium dioxide-coated surfaces . Environ. Sci. Technol. , 36 : 3412 – 3419 .
  • Wu , W. C. , Liao , L. F. , Lien , C. F. and Lin , J. L. 2001 . FTIR study of adsorption, thermal reactions and photochemistry of benzene on powdered TiO2 . Phys. Chem. Chem. Phys. , 3 : 4456 – 4461 .
  • Xu , Y. and Schoonen , M. A.A. 2000 . The absolute energy positions of conduction and valence band of selected semiconducting minerals . Am. Mineral. , 85 : 543 – 556 .
  • Yamazaki , S. , Tsukamoto , H. , Araki , K. , Tanimura , T. , Tejedor-Tejedor , I. and Anderson , M. A. 2001 . Photocatalytic degradation of gaseous tetrachloroethylene on porous TiO2 pellets . Appl. Catal. B Environ. , 33 : 109 – 117 .
  • Yamazaki , S. , Yoshida , A. and Abe , H. 2005 . Photocatalytic degradation of chloroform in the gas phase on the porous TiO2 pellets: Effect of Cl accumulated on the catalyst surface . J. Photochem. Photobiol. A Chem. , 169 : 191 – 196 .
  • Yeung , K. L. , Maira , A. J. , Stolz , J. , Hung , E. , Ho , N. K.C. , Wei , A. C. , Soria , J. , Chao , K. J. and Yue , P. L. 2002 . Ensemble effects in nanostructured TiO2 used in the gas-phase photooxidation of trichloroethylene . J. Phys. Chem. B , 106 : 4698 – 4616 .
  • Young , C. , Lim , T. M. , Chiang , K. and Amal , R. 2004 . Photocatalytic degradation of toluene by platinized titanium dioxide photocatalysts . Water Sci. Technol. , 50 : 251 – 256 .
  • Zhao , J. and Yang , X. 2003 . Photocatalytic oxidation for indoor air purification: A literature review . Build. Environ. , 38 : 645 – 654 .

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