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Journal of Environmental Science and Health, Part A
Toxic/Hazardous Substances and Environmental Engineering
Volume 46, 2011 - Issue 8
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ARTICLES

Optimization process parameters for in-situ synthesis of ammonia by catalytic hydrolysis of urea with fly ash in a batch reactor for safe feedstock in power plants

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Pages 874-886 | Received 17 Nov 2010, Published online: 16 Jun 2011

References

  • Cooper , H. B.H. and Spencer , H. W. 2004 . Methods for the production of Ammonia from Urea and/or Biuret, and uses for No x and/or particulate matter removal . United States Patent application no. US 6,730,280 B2
  • Del Prato , T. A. and Spicer , H. G. 2005 . On-site Generation, Purification, and Distribution of Ultra-Pure Anhydrous Ammonia . United States Patent application no. 20050260108 A1
  • Brooks , B. , Jessup , W. A. and Macarthur , B. W. 2005 . Method of Quantitatively Producing Ammonia from Urea . United States Patent application no. US 6,887,449 B2
  • Schell , L. P. 1978 . Method for hydrolyzing urea contained in waste water streams . United States Patent application no. US 4,087,513
  • Sahu , J. N. , Gangadharan , P. , Patwardhan , A. V. and Meikap , B. C. 2009 . Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NO x reduction . Ind. Eng. Chem. Res. , 48 : 727 – 734 .
  • Sahu , J. N. , Patwardhan , A. V. and Meikap , B. C. 2009 . Equilibrium and kinetic studies of in-situ generation of ammonia from urea in a batch reactor for flue gas conditioning of thermal power plants . Ind. Eng. Chem. Res. , 48 : 2705 – 2712 .
  • Isla , M. A. , Irazoqui , H. A. and Genoud , C. M. 1993 . Simulation of a urea synthesis reactor . Part 1. Thermodynamic framework. Ind. Eng. Chem. Res. , 32 : 2662 – 2670 .
  • Claudel , B. , Brousse , E. and Shehadeh , G. 1986 . Novel thermodynamic and kinetic investigation of ammonium carbamate decomposition into urea . Thermochimica Acta , 102 : 357 – 371 .
  • Young , D. C. 1993 . Transporting urea for quantitative conversion into ammonia . US Patent application no. US 5,252,308
  • Jones , D. G. 1998 . Method for Converting Urea to Ammonia . United States Patent application no. US 5,827,490
  • Sahu , J. N. , Mahalik , K. , Patwardhan , A. V. and Meikap , B. C. 2008 . Equilibrium and kinetic studies on the hydrolysis of urea for ammonia generation in a semi-batch reactor . Ind. Eng. Chem. Res. , 47 : 4689 – 4696 .
  • Sahu , J. N. , Mahalik , K. K. , Patwardhan , A. V. and Meikap , B. C. 2009 . Equilibrium studies on hydrolysis of urea in a semi-batch reactor for production of ammonia to reduce hazardous pollutants from flue gas . J. Hazard. Mater. , 164 : 659 – 664 .
  • Alam , M. Z. , Muyibi , S. A. and Toramae , J. 2007 . Statistical optimization of adsorption processes for removal of 2,4-dichlorophenol by activated carbon derived from oil palm empty fruit bunches . J. Environ. Sci. , 19 : 674 – 677 .
  • Sahu , J. N. , Acharya , J. and Meikap , B. C. 2010 . Optimization of production conditions for activated carbons from Tamarind wood by zinc chloride using response surface methodology . Bioresour. Technol. , 101 : 1974 – 1982 .
  • Sahu , J. N. , Patwardhan , A. V. and Meikap , B. C. 2009 . Response surface modeling and optimization for production of ammonia from urea in a batch reactor . Asia-Pacific J. Chem. Eng. , 4 : 462 – 470 .
  • Mahalik , K. , Sahu , J. N. , Patwardhan , A. V. and Meikap , B. C. 2010 . Statistical modelling and optimization of hydrolysis of urea to generate ammonia for flue gas conditioning . J. Hazard. Mater. , 182 ( 1–3 ) : 603 – 610 .
  • Sahu , J. N. , Patwardhan , A. V. and Meikap , B. C. 2010 . Optimization for production of ammonia from urea in a semi-batch reactor for safe feedstock in power plants: Experimental and statistical studies . CLEAN - Soil, Air, Water , 38 ( 5–6 ) : 533 – 542 .
  • Sahu , J. N. , Acharya , J. and Meikap , B. C. 2009 . Response surface modeling and optimization of chromium(VI) removal from aqueous solution using Tamarind wood activated carbon in batch process . J. Hazard. Mater. , 172 : 818 – 825 .
  • Montgomery , D. C. 2001 . Design and analysis of experiments, (5th edition) , New York, USA : John Wiley and Sons .
  • Myers , R H . 1971 . Response Surface Methodology , New York : Allyn and Bacon .
  • Gunaraj , V. and Murugan , N . 1999 . Application of response surface methodologies for predicting weld base quality in submerged arc welding of pipes . J. Mater. Process. Technol. , 88 : 266 – 275 .
  • Box , G. E.P. and Hunter , J S . 1957 . Multi-factor experimental design for exploring response surfaces . Ann. Math. Stat. , 28 : 195 – 241 .
  • Napier-Munn , T. J. 2000 . The Central Composite Rotatable Design JKMRC,” , Brisbane, Australia : The University of Queensland .
  • Al Ghouti , M. , Khraisheh , M. A.M. , Allen , S. and Ahmad , M. N.M. 2003 . The removal of dyes from textile wastewater: A study of the physical characteristics and adsorption mechanisms of diatomaceous Earth . J. Environ. Manag. , 69 : 229 – 238 .

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