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Technical Paper

Characterization of PFAS air emissions from thermal application of fluoropolymer dispersions on fabrics

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Pages 533-552 | Received 18 Oct 2022, Accepted 10 Mar 2023, Published online: 02 Jun 2023

References

  • Baker, B.B., and D.J. Kasprzak. 1993. Thermal degradation of commercial fluoropolymers in air. Polym. Degrad. Stab. 42 (2):181–88. doi:10.1016/0141-3910(93)90111-U.
  • Buck, R.C., J. Franklin, U. Berger, J.M. Conder, I.T. Cousins, P. de Voogt, A.A. Jensen, K. Kannan, S.A. Mabury, and S.P.J. van Leeuwen. 2011. Perfluoroalkyl and polyfluoroalkyl substances in the environment: Terminology, classification, and origins. Integr. Environ. Assess. Manag. 7 (4):513–41. doi:10.1002/ieam.258.
  • The Chemours Company FC, LLC. 2017. FEP Fluoroplastic Dispersion FEPD 121, FEP Fluoroplastic Dispersion FEPD 121. SDS No: 1336887-00032. https://www.fuelcellstore.com/msds-sheets/chemours-teflon-fepd121-msds.pdf
  • The Chemours Company, LLC. 2020a. Teflon™ FEPD 121 Fluoroplastic Resin FEP Aqueous Dispersion Product Information. https://www.teflon.com/en/-/media/files/teflon/teflon-fepd-121-product-info.pdf?rev=6c7648855b99404d8c45c9b552318eeb
  • The Chemours Company, LLC. 2020b. Teflon™ PTFE DISP 30 Fluoroplastic Dispersion Product Description Information. https://www.teflon.com/en/-/media/files/teflon/teflon-ptfe-disp-30-product-info.pdf?rev=9edbd400fa65486292d5c2c4fed3af0a
  • Conesa, J.A., and R. Font. 2001. Polytetrafluoroethylene decomposition in air and nitrogen. Polym. Eng. Sci. 41 (12):2137–47. doi:10.1002/pen.10908.
  • D’Ambro, E.L., H.O.T. Pye, J.O. Bash, J. Bowyer, C. Allen, C. Efstathiou, R.C. Gilliam, L. Reynolds, K. Talgo, and B.N. Murphy. 2021. Characterizing the air emissions, transport, and deposition of per- and polyfluoroalkyl substances from a fluoropolymer manufacturing facility. Environ. Sci. Technol. 55 (2):862–70. doi:10.1021/acs.est.0c06580.
  • DuPont. 2010. DuPont GenX processing aid for making fluoropolymer resins. https://bladenonline.com/wp-content/uploads/2017/06/Chemours_GenX_Brochure_Final_07July2010.pdf
  • Ellis, D.A., S.A. Mabury, J.W. Martin, and D.C.G. Muir. 2001. Thermolysis of fluoropolymers as a potential source of halogenated organic acids in the environment. Nature 412 (6844):321–24. doi:10.1038/35085548.
  • Ellis, D.A., J.W. Martin, A.O. De Silva, S.A. Mabury, M.D. Hurley, M.P. Sulbaek Andersen, and T.J. Wallington. 2004. Degradation of fluorotelomer alcohols: A likely atmospheric source of perfluorinated carboxylic acids. Environ. Sci. Technol. 38 (12):3316–21. doi:10.1021/es049860w.
  • Ellis, D.A., J.W. Martin, D.C.G. Muir, and S.A. Mabury. 2003. The use of 19F NMR and mass spectrometry for the elucidation of novel fluorinated acids and atmospheric fluoroacid precursors evolved in the thermolysis of fluoropolymers. Analyst. (Lond) 128 (6):756–64. doi:10.1039/b212658c.
  • Greenberg, M.I., and D. Vearrier. 2015. Metal fume fever and polymer fume fever. Clin. Toxicol. 53 (4):4, 195–203. doi:10.3109/15563650.2015.1013548.
  • Hassel, D. 2016. David Hassel testimony during ‘Public Hearing on Water Quality and Contamination’ Committee on Health & Environmental Conservation, New York State Senate. Accessed September 7, 2016. https://www.nysenate.gov/calendar/public-hearings/september-07-2016/water-quality-and-contamination.
  • Heydebreck, F., J. Tang, Z. Xie, and R. Ebinghaus. 2016. Emissions of per- and polyfluoroalkyl substances in a textile manufacturing plant in China and their relevance for workers’ exposure. Environ. Sci. Technol. 50 (19):10386–96. doi:10.1021/acs.est.6b03213.
  • Huber, S., M.K. Moe, N. Schmidbauer, G.H. Hansen, and D. Herzke. 2009. Emissions from incineration of fluoropolymer materials. Kjeller, Norway: Norwegian Institute for Air Research.
  • Lewis, E.E., and M.A. Naylor. 1947. Pyrolysis of Polytetrafluoroethylene. J. Am. Chem. Soc. 69 (8):1968–70. doi:10.1021/ja01200a039.
  • Liberatore, H.K., S.R. Jackson, M.J. Strynar, and J.P. McCord. 2020. Solvent suitability for HFPO-DA (“GenX” Parent Acid) in toxicological studies. Environ. Sci. Technol. Lett. 7 (7):477–81. doi:10.1021/acs.estlett.0c00323.
  • McKeen, L.W. 2006. Fluorinated coatings and finishes handbook. 1st ed. Norwich, NY: William Andrew Publishing.
  • Prevedouros, K., I.T. Cousins, R.C. Buck, and S.H. Korzeniowski. 2006. Sources, fate and transport of perfluorocarboxylates. Environ. Sci. Technol. 40 (1):32–44. doi:10.1021/es0512475.
  • Riedel, T.P., M.A. Geer Wallace, E.P. Shields, J.V. Ryan, C.W. Lee, and W.P. Linak. 2021. Low temperature thermal treatment of gas-phase fluorotelomer alcohols by calcium oxide. Chemosphere 272:129859. doi:10.1016/j.chemosphere.2021.129859.
  • Schlummer, M., C. Solch, T. Meisel, M. Still, L. Gruber, and G. Wolz. 2015. Emission of perfluoroalkyl carboxylic acids (PFCA) from heated surfaces made of polytetrafluoroethylene (PTFE) applied in food contact materials and consumer products. Chemosphere 129:46–53. doi:10.1016/j.chemosphere.2014.11.036.
  • The Chemours Company, L.L.C. 2022. PTFE Fluoroplastic Dispersion DISP 30, PTFE Fluoroplastic Dispersion DISP 30. In SDS No: 1339069-00047. https://fluorogistx.com/wp-content/uploads/2022/11/PTFE-Fluoroplastic-Dispersion-DISP-30-SDS.pdf.
  • Treon, J.F., J.W. Cappel, F.P. Clevelan.d, E.E. Larson, R.W. Atchley, and R.T. Denham. 1955. The toxicity of the products formed by the thermal decomposition of certain organic substances. Am. Ind. Hyg. Assoc. Q 16 (3):187–95. doi:10.1080/00968205509344029.
  • U.S. EPA. 1999. Air method, Toxic Organics-15 (TO-15): Compendium of methods for the determination of toxic organic compounds in ambient air, second edition: Determination of Volatile Organic Compounds (VOCs) in air collected in specially-prepared canisters and analyzed by Gas Chromatography/Mass Spectrometry (GC/MS).
  • U.S. EPA. 2023. Recommended procedures for development of emissions factors and use of the WebFIRE database. Publication no. EPA-453/R-23-001.
  • Waritz, R.S., and B.K. Kwon. 1968. The inhalation toxicity of products of polytetrafluoroethylene heated below 500 degrees centigrade. Am. Ind. Hyg. Assoc. J. 29 (1):19–26. doi:10.1080/00028896809342976.
  • Washington, J.W., J.E. Naile, T.M. Jenkins, and D.G. Lynch. 2014. Characterizing fluorotelomer and polyfluoroalkyl substances in new and aged fluorotelomer-based polymers for degradation studies with GC/MS and LC/MS/MS. Environ. Sci. Technol. 48 (10):5762–69. doi:10.1021/es500373b.
  • Watkins, T.H. 2019. Laboratory data Report #6: Non-Targeted PFAS measurements in MM5 sample trains. Edited by New Hampshire Department of Environmental Services. United States Environmental Protection Agency. https://www4.des.state.nh.us/nh-pfas-investigation/?p=1019.
  • Weston Solutions, Inc. 2016. Perfluorinated sulfonic acids and perfluorinated carboxylic acids testing program report, saint-gobain performance plastics, Merrimack, New Hampshire. New Hampshire Department of Environmental Services.
  • Yuan, B., A.R. Koss, C. Warneke, M. Coggon, K. Sekimoto, and J.A. de Gouw. 2017. Proton-transfer-reaction mass spectrometry: Applications in atmospheric sciences. Chem. Rev. 117 (21):13187–229. doi:10.1021/acs.chemrev.7b00325.

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