269
Views
23
CrossRef citations to date
0
Altmetric
Articles

Biosorption and regeneration potentials of magnetite nanoparticle loaded Solanum tuberosum peel for celestine blue dye

&

References

  • Abbaszadeh S, Nodeh HR, Alwi SRW. 2018. Bio-adsorbent derived from papaya peel waste and magnetic nanoparticles fabricated for lead determination. Pure Appl Chem. 90(1):79–92. doi:10.1515/pac-2017-0503.
  • Aguayo-Villarreal IA, Cortes-Arriagada D, Rojas-Mayorga CK, Pineda-Urbina K, Muñiz-Valencia R, González J. 2020. Importance of the interaction adsorbent –adsorbate in the dyes adsorption process and DFT modeling. J Mol Struct. 1203:127398. doi:10.1016/j.molstruc.2019.127398.
  • Ahmad T, Danish M. 2018. Prospects of banana waste utilization in wastewater treatment: a review. J Environ Manage. 206:330–348. doi:10.1016/j.jenvman.2017.10.061.
  • Akinola L, Umar A. 2015. Adsorption of crystal violet onto adsorbents derived from agricultural wastes: kinetic and equilibrium studies. J Appl Sci Environ Manag. 19(2):279. doi:10.4314/jasem.v19i2.15.
  • Akpomie KG, Conradie J. 2020a. Banana peel as a biosorbent for the decontamination of water pollutants. A review. Environ Chem Lett. 18(4):1085–1112. doi:10.1007/s10311-020-00995-x.
  • Akpomie KG, Conradie J. 2020b. Efficient synthesis of magnetic nanoparticle-Musa acuminata peel composite for the adsorption of anionic dye. Arab J Chem. doi:10.1016/j.arabjc.2020.07.017.
  • Akpomie KG, Conradie J. 2020c. Advances in application of cotton-based adsorbents for heavy metals trapping, surface modifications and future perspectives. Ecotoxicol Environ Saf. 201:110825. doi:10.1016/j.ecoenv.2020.110825.
  • Akpomie KG, Dawodu FA, Adebowale KO. 2015. Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential. Alexandria Eng J. 54(3):757–767. doi:10.1016/j.aej.2015.03.025.
  • Akpomie KG, Ezeofor CC, Olikagu CS, Odewole OA, Ezeorah CJ. 2018. Abstraction and regeneration potential of temperature-enhanced rice husk montmorillonite combo for oil spill. Environ Sci Pollut Res Int. 25(34):34711–34719. doi:10.1007/s11356-018-3425-9.
  • Aleem M, Cao J, Li C, Rashid H, Wu Y, Nawaz MI, Abbas M, Akram MW. 2020. Coagulation- and adsorption-based environmental impact assessment and textile effluent treatment. Water Air Soil Pollut. 231:45. 10.1007/s11270-020-4400-x.
  • Ali A, Gul A, Mannan A, Zia M. 2018. Efficient metal adsorption and microbial reduction from Rawal Lake wastewater using metal nanoparticle coated cotton. Sci Total Environ. 639:26–39. doi:10.1016/j.scitotenv.2018.05.133.
  • Alizadeh N, Shariati S, Besharati N. 2017. Adsorption of crystal violet and methylene blue on azolla and fig leaves modified with magnetite iron oxide nanoparticles. Int J Environ Res. 11(2):197–206. doi:10.1007/s41742-017-0019-1.
  • Aljeboree AM, Alshirifi AN, Alkaim AF. 2017. Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arab J Chem. 10:S3381–S3393. doi:10.1016/j.arabjc.2014.01.020.
  • Alqadami AA, Naushad M, Abdalla MA, Khan MR, Alothman ZA. 2016. Adsorptive removal of toxic dye using Fe 3 O 4 –TSC nanocomposite: equilibrium, kinetic, and thermodynamic studies. J Chem Eng Data. 61(11):3806–3813. doi:10.1021/acs.jced.6b00446.
  • Anastopoulos I, Hosseini-Bandegharaei A, Fu J, Mitropoulos AC, Kyzas GZ. 2018. Use of nanoparticles for dye adsorption: review. J Dispers Sci Technol. 39(6):836–847. doi:10.1080/01932691.2017.1398661.
  • Ani JU, Akpomie KG, Okoro UC, Aneke LE, Onukwuli OD, Ujam OT. 2020. Potentials of activated carbon produced from biomass materials for sequestration of dyes, heavy metals, and crude oil components from aqueous environment. Appl Water Sci. 10:1–11. doi:10.1007/s13201-020-1149-8.
  • Arabkhani P, Asfaram A. 2020. Development of a novel three-dimensional magnetic polymer aerogel as an efficient adsorbent for malachite green removal. J Hazard Mater. 384:121394. doi:10.1016/j.jhazmat.2019.121394.
  • Ayad MM, El-Nasr AA. 2010. Adsorption of cationic dye (methylene blue) from water using polyaniline nanotubes base. J Phys Chem C. 114(34):14377–14383. doi:10.1021/jp103780w.
  • Bagbi Y, Sarswat A, Mohan D, Pandey A, Solanki PR. 2017. Lead and chromium adsorption from water using L-cysteine functionalized magnetite (Fe3O4) nanoparticles. Sci Rep. 7(1):7672. doi:10.1038/s41598-017-03380-x.
  • Besharati N, Alizadeh N. 2018. Adsorption of malachite green dye on different natural absorbents modified with magnetite nanoparticles. J Nanoanal. 5:143–155. doi:10.22034/jna.2018.551649.1048.
  • Buazar F, Baghlani-Nejazd MH, Badri M, Kashisaz M, Khaledi-Nasab A, Kroushawi F. 2016. Facile one-pot phytosynthesis of magnetic nanoparticles using potato extract and their catalytic activity. Starch Stärke. 68(7–8):796–804. doi:10.1002/star.201500347.
  • Chukwuemeka-Okorie HO, Ekemezie PN, Akpomie KG, Olikagu CS. 2018. Calcined corncob-kaolinite Combo as new sorbent for sequestration of toxic metal ions from polluted aqua media and desorption. Front Chem. 6:273–213. doi:10.3389/fchem.2018.00273.
  • Dawodu FA, Akpan BM, Akpomie KG. 2020. Sequestered capture and desorption of hexavalent chromium from solution and textile wastewater onto low cost Heinsia crinita seed coat biomass. Appl Water Sci. 10:32. 10.1007/s13201-019-1114-6.
  • Dhananasekaran S, Palanivel R, Pappu S. 2016. Adsorption of methylene blue, bromophenol blue, and coomassie brilliant blue by α-chitin nanoparticles. J Adv Res. 7(1):113–124. doi:10.1016/j.jare.2015.03.003.
  • Egbosiuba TC, Abdulkareem AS, Kovo AS, Afolabi EA, Tijani JO, Auta M, Roos WD. 2020. Ultrasonic enhanced adsorption of methylene blue onto the optimized surface area of activated carbon: adsorption isotherm, kinetics and thermodynamics. Chem Eng Res Des. 153:315–336. doi:10.1016/j.cherd.2019.10.016.
  • El-Shamy OAA, El-Azabawy RE, El-Azabawy OE. 2019. Synthesis and characterization of magnetite-alginate nanoparticles for enhancement of nickel and cobalt ion adsorption from wastewater. J Nanomater. 2019:1–8. doi:10.1155/2019/6326012.
  • El-Zahhar AA, Awwad NS, El-Katori EE. 2014. Removal of bromophenol blue dye from industrial waste water by synthesizing polymer-clay composite. J Mol Liq. 199:454–461. doi:10.1016/j.molliq.2014.07.034.
  • Enenebeaku CK, Ukaga IC, Okorocha NJ, Onyeachu BI. 2018. Adsorption, equilibrium and kinetic studies of the removal of methyl violet from aqueous solution using white potato peel powder. Int Lett Chem Phys Astronomy. 80:17–29. doi:10.18052/www.scipress.com/ILCPA.80.17.
  • Eze SI, Akpomie KG, Ezekoye OM, Chukwujindu CN, Ojo FK, Ani JU, Ujam OT. 2020. Antibiotic adsorption by acid enhanced Dialium guineense seed waste. Arab J Sci Eng. doi:10.1007/s13369-020-04771-5.
  • Ezekoye OM, Akpomie KG, Eze SI, Chukwujindu CN, Ani JU, Ujam OT. 2020. Biosorptive interaction of alkaline modified Dialium guineense seed powders with ciprofloxacin in contaminated solution: central composite, kinetics, isotherm, thermodynamics, and desorption. Int J Phytoremed. 0:1–10. doi:10.1080/15226514.2020.1725869.
  • Feiqiang G, Xiaolei L, Xiaochen J, Xingmin Z, Chenglong G, Zhonghao R. 2018. Characteristics and toxic dye adsorption of magnetic activated carbon prepared from biomass waste by modified one-step synthesis. Colloids Surf A Physicochem Eng Asp. 555:43–54. doi:10.1016/j.colsurfa.2018.06.061.
  • Ferreira AM, Coutinho JAP, Fernandes AM, Freire MG. 2014. Complete removal of textile dyes from aqueous media using ionic-liquid-based aqueous two-phase systems. Sep Purif Technol. 128:58–66. doi:10.1016/j.seppur.2014.02.036.
  • Foo KY, Hameed BH. 2010. Insights into the modeling of adsorption isotherm systems. Chem Eng J. 156(1):2–10. doi:10.1016/j.cej.2009.09.013.
  • Gao S, Zhang W, Zhou H, Chen D. 2018. Magnetic composite Fe3O4/CeO2 for adsorption of azo dye. J Rare Earths. 36(9):986–993. doi:10.1016/j.jre.2018.04.002.
  • Gautam RK, Mudhoo A, Lofrano G, Chattopadhyaya MC. 2014. Biomass-derived biosorbents for metal ions sequestration: adsorbent modification and activation methods and adsorbent regeneration. J Environ Chem Eng. 2(1):239–259. doi:10.1016/j.jece.2013.12.019.
  • Ge M, Xi Z, Zhu C, Liang G, Hu G, Jamal L, Jahangir Alam SM. 2019. Preparation and characterization of magadiite–magnetite nanocomposite with its sorption performance analyses on removal of methylene blue from aqueous solutions. Polymers (Basel). 11(4):607. doi:10.3390/polym11040607.
  • Guechi EK, Hamdaoui O. 2016a. Sorption of malachite green from aqueous solution by potato peel: kinetics and equilibrium modeling using non-linear analysis method. Arab J Chem. 9:S416–S424. doi:10.1016/j.arabjc.2011.05.011.
  • Guechi EK, Hamdaoui O. 2016b. Biosorption of methylene blue from aqueous solution by potato (Solanum tuberosum) peel: equilibrium modelling, kinetic, and thermodynamic studies. Desalin Water Treat. 57(22):10270–10285. doi:10.1080/19443994.2015.1035338.
  • Gupta N, Kushwaha AK, Chattopadhyaya MC. 2016. Application of potato (Solanum tuberosum) plant wastes for the removal of methylene blue and malachite green dye from aqueous solution. Arab J Chem. 9:S707–S716. doi:10.1016/j.arabjc.2011.07.021.
  • Hardani K, Buazar F, Ghanemi K, Kashisaz M, Badri M. 2015. Removal of toxic mercury (II) from water via Fe3O4/hydroxyapatite nanoadsorbent: an efficient, economic and rapid approach. AASCIT J Nanosci. 1:11–18.
  • Hazzaa R, Hussein M. 2015. Adsorption of cationic dye from aqueous solution onto activated carbon prepared from olive stones. Environ Technol Innov. 4:36–51. doi:10.1016/j.eti.2015.04.002.
  • Hu G, Zhang W, Chen Y, Xu C, Liu R, Han Z. 2020. Removal of boron from water by GO/ZIF-67 hybrid material adsorption. Environ Sci Pollut Res. 27:28396–28407. 10.1007/s11356-020-08018-6.
  • Hussain I, Li Y, Qi J, Li J, Wang L. 2018. Nitrogen-enriched carbon sheet for Methyl blue dye adsorption. J Environ Manage. 215:123–131. doi:10.1016/j.jenvman.2018.03.051.
  • Jafari Harandi Z, Ghanavati Nasab S, Teimouri A. 2019. Synthesis and characterisation of magnetic activated carbon/diopside nanocomposite for removal of reactive dyes from aqueous solutions: experimental design and optimisation. Int J Environ Anal Chem. 99(6):568–594. doi:10.1080/03067319.2019.1597867.
  • Jiang C, Wang X, Qin D, Da W, Hou B, Hao C, Wu J. 2019. Construction of magnetic lignin-based adsorbent and its adsorption properties for dyes. J Hazard Mater. 369:50–61. doi:10.1016/j.jhazmat.2019.02.021.
  • Jiao Y, Han D, Lu Y, Rong Y, Fang L, Liu Y, Han R. 2017. Characterization of pine-sawdust pyrolytic char activated by phosphoric acid through microwave irradiation and adsorption property toward CDNB in batch mode. Desalinat Water Treat. 77:247–255. doi:10.5004/dwt.2017.20780.
  • Khan B, Nawaz M, Waseem M, Hussain R, Arif S, Price GJ, Haq S, Rehman W. 2019. Adsorption of methylene blue onto size controlled magnetite nanoparticles. Mater Res Express. 6(9):095511. doi:10.1088/2053-1591/ab2ef9.
  • Khoshsang H, Ghaffarinejad A, Kazemi H, Wang Y, Arandiyan H. 2018. One-pot synthesis of S-doped Fe2O3/C magnetic nanocomposite as an adsorbent for anionic dye removal: equilibrium and kinetic studies. J Nanostruct Chem. 8(1):23–32. doi:10.1007/s40097-017-0251-4.
  • Kim H, Yun YM, Lim KH, Do QC, Kang S. 2020. Selective removal of color substances by carbon-based adsorbents in livestock wastewater effluents. Environ Geochem Health. 42:1643–1653. 10.1007/s10653-020-00547-w.
  • Kuang Y, Zhang X, Zhou S. 2020. Adsorption of Methylene blue in water onto activated carbon by surfactant modification. Water. 12(2):587. doi:10.3390/w12020587.
  • Kusrini E, Alhamid MI, Widiantoro AB, Daud NZA, Usman A. 2020. Simultaneous adsorption of multi-lanthanides from aqueous silica sand solution using pectin–activated carbon composite. Arab J Sci Eng. doi:10.1007/s13369-020-04386-w.
  • Kusrini E, Paramesti SN, Zulys A, Daud NZA, Usman A, Wilson LD, Sofyan N. 2019a. Kinetics, isotherm, thermodynamic and bioperformance of defluoridation of water using praseodymium-modified chitosan. J Environ Chem Eng. 7(6):103498. doi:10.1016/j.jece.2019.103498.
  • Kusrini E, Sofyan N, Suwartha N, Yesya G, Priadi CR. 2015. Chitosan-praseodymium complex for adsorption of fluoride ions from water. J Rare Earths. 33(10):1104–1113. doi:10.1016/S1002-0721(14)60533-0.
  • Kusrini E, Usman A, Sani FA, Wilson LD, Abdullah MAA. 2019b. Simultaneous adsorption of lanthanum and yttrium from aqueous solution by durian rind biosorbent. Environ Monit Assess. 191(8):488. doi:10.1007/s10661-019-7634-6.
  • Kusrini E, Oktavianto F, Simanjuntak A, Pasca G, Usman A. 2018a. Synthesis and characterization of graphite/magnetite composite as low cost potential adsorbent from graphite waste. E3S Web Conf. 67:03029. doi:10.1051/e3sconf/20186703029.
  • Kusrini E, Sasongko AK, Nasruddin N, Usman A. 2017. Improvement of carbon dioxide capture using graphite waste/FE3O4 composites. IJTech. 8(8):1436. doi:10.14716/ijtech.v8i8.697.
  • Kusrini E, Wicaksono W, Gunawan C, Daud NZA, Usman A. 2018b. Kinetics, mechanism, and thermodynamics of lanthanum adsorption on pectin extracted from durian rind. J Environ Chem Eng. 6(5):6580–6588. doi:10.1016/j.jece.2018.10.018.
  • Kyzas GZ, Deliyanni EA, Lazaridis NK. 2014. Magnetic modification of microporous carbon for dye adsorption. J Colloid Interface Sci. 430:166–173. doi:10.1016/j.jcis.2014.05.049.
  • Lestari I, Kurniawan E, Gusti DR, Yusnelti. 2020. Magnetite Fe3O4 -activated carbon composite as adsorbent of rhodamine B dye. IOP Conf Ser Earth Environ Sci. 483:012046. doi:10.1088/1755-1315/483/1/012046.
  • Madrakian T, Afkhami A, Ahmadi M. 2012. Adsorption and kinetic studies of seven different organic dyes onto magnetite nanoparticles loaded tea waste and removal of them from wastewater samples. Spectrochim Acta A Mol Biomol Spectrosc. 99:102–109. doi:10.1016/j.saa.2012.09.025.
  • Makarchuk OV, Dontsova TA, Astrelin IM. 2016. Magnetic nanocomposites as efficient sorption materials for removing dyes from aqueous solutions. Nanoscale Res Lett. 11(1):161. doi:10.1186/s11671-016-1364-2.
  • Mohubedu RP, Diagboya PNE, Abasi CY, Dikio ED, Mtunzi F. 2019. Magnetic valorization of biomass and biochar of a typical plant nuisance for toxic metals contaminated water treatment. J Clean Prod. 209:1016–1024. doi:10.1016/j.jclepro.2018.10.215.
  • Momina Rafatullah M, Ismail S, Ahmad A. 2019. Optimization study for the desorption of methylene blue dye from clay based adsorbent coating. Water. 11:1304. doi:10.3390/w11061304.
  • Mtshatsheni KNG, Ofomaja AE, Naidoo EB. 2019. Synthesis and optimization of reaction variables in the preparation of pine-magnetite composite for removal of methylene blue dye. South African J Chem Eng. 29:33–41. doi:10.1016/j.sajce.2019.05.002.
  • Muhammad A, Shah AHA, Bilal S, Rahman G. 2019. Basic blue dye adsorption from water using polyaniline/magnetite (Fe3O4) composites: kinetic and thermodynamic aspects. Materials (Basel). 12(11):1764. doi:10.3390/ma12111764.
  • Muinde VM, Onyari JM, Wamalwa B, Wabomba JN. 2020. Adsorption of malachite green dye from aqueous solutions using mesoporous chitosan–zinc oxide composite material. Environ Chem Ecotoxicol. 2:115–125. doi:10.1016/j.enceco.2020.07.005.
  • Potgieter JH, Pardesi C, Pearson S. 2020. A kinetic and thermodynamic investigation into the removal of methyl orange from wastewater utilizing fly ash in different process configurations. Environ Geochem Health. doi:10.1007/s10653-020-00567-6.
  • Rajput S, Pittman CU, Mohan D. 2016. Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water. J Colloid Interface Sci. 468:334–346. doi:10.1016/j.jcis.2015.12.008.
  • Rehman R, Mahmud T, Irum M. 2015. Brilliant green dye elimination from water using Psidium guajava leaves and Solanum tuberosum peels as adsorbents in environmentally benign way. J Chem. 2015:1–8. doi:10.1155/2015/126036.
  • Rehman R, Manzoor I, Mitu L. 2018. Isothermal study of Congo red dye biosorptive removal from water by Solanum tuberosum and Pisum sativum peels in economical way. Bull Chem Soc Eth. 32(2):213. doi:10.4314/bcse.v32i2.3.
  • Rokni S, Haji Seyed Mohammad Shirazi R, Miralinaghi M, Moniri E. 2020. Efficient adsorption of anionic dyes onto magnetic graphene oxide coated with polyethylenimine: kinetic, isotherm, and thermodynamic studies. Res Chem Intermed. 46(4):2247–2274. doi:10.1007/s11164-020-04090-2.
  • Sakin Omer O, Hussein MA, Hussein BHM, Mgaidi A. 2018. Adsorption thermodynamics of cationic dyes (methylene blue and crystal violet) to a natural clay mineral from aqueous solution between 293.15 and 323.15 K. Arab J Chem. 11(5):615–623. doi:10.1016/j.arabjc.2017.10.007.
  • Saleh TA, Al-Absi AA. 2017. Kinetics, isotherms and thermodynamic evaluation of amine functionalized magnetic carbon for methyl red removal from aqueous solutions. J Mol Liq. 248:577–585. doi:10.1016/j.molliq.2017.10.064.
  • Shabaan OA, Jahin HS, Mohamed GG. 2020. Removal of anionic and cationic dyes from wastewater by adsorption using multiwall carbon nanotubes. Arab J Chem. 13(3):4797–4810. doi:10.1016/j.arabjc.2020.01.010.
  • Singh S, Kumar V, Datta S, Dhanjal DS, Sharma K, Samuel J, Singh J. 2020. Current advancement and future prospect of biosorbents for bioremediation. Sci Total Environ. 709:135895. doi:10.1016/j.scitotenv.2019.135895.
  • Singh S, Sidhu GK, Singh H. 2017. Removal of methylene blue dye using activated carbon prepared from biowaste precursor. Indian Chem Eng. 61:28–39. doi:10.1080/00194506.2017.1408431.
  • Sivashankar R, Sathya AB, Vasantharaj K, Sivasubramanian V. 2014. Magnetic composite an environmental super adsorbent for dye sequestration – a review. Environ Nanotechnol Monit Manag. 1–2:36–49. doi:10.1016/j.enmm.2014.06.001.
  • Stavrinou A, Aggelopoulos CA, Tsakiroglou CD. 2018. Exploring the adsorption mechanisms of cationic and anionic dyes onto agricultural waste peels of banana, cucumber and potato: adsorption kinetics and equilibrium isotherms as a tool. J Environ Chem Eng. 6(6):6958–6970. doi:10.1016/j.jece.2018.10.063.
  • Suc NV, Kim Chi D. 2017. Removal of rhodamine B from aqueous solution via adsorption onto microwave-activated rice husk ash. J Dispers Sci Technol. 38(2):216–222. doi:10.1080/01932691.2016.1155153.
  • Taleb K, Markovski J, Veličković Z, Rusmirović J, Rančić M, Pavlović V, Marinković A. 2019. Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: effect of functionalization and media size. Arab J Chem. 12(8):4675–4693. doi:10.1016/j.arabjc.2016.08.006.
  • Tran HN, You SJ, Nguyen TV, Chao HP. 2017. Insight into the adsorption mechanism of cationic dye onto biosorbents derived from agricultural wastes. Chem Eng Commun. 204(9):1020–1036. doi:10.1080/00986445.2017.1336090.
  • Trinh VT, Nguyen TMP, Van HT, Hoang LP, Nguyen TV, Ha LT, Vu XH, Pham TT, Nguyen TN, Quang NV, et al. 2020. Phosphate adsorption by silver nanoparticles-loaded activated carbon derived from tea residue. Sci Rep. 10(1):3634. doi:10.1038/s41598-020-60542-0.
  • Wang Z, Gao M, Li X, Ning J, Zhou Z, Li G. 2020. Efficient adsorption of methylene blue from aqueous solution by graphene oxide modified persimmon tannins. Mater Sci Eng C Mater Biol Appl. 108:110196. doi:10.1016/j.msec.2019.110196.
  • Wong S, Yac’cob NAN, Ngadi N, Hassan O, Inuwa IM. 2018. From pollutant to solution of wastewater pollution: synthesis of activated carbon from textile sludge for dye adsorption. Chin J Chem Eng. 26(4):870–878. doi:10.1016/j.cjche.2017.07.015.
  • Yadav S, Asthana A, Chakraborty R, Jain B, Singh AK, Carabineiro SAC, Susan MABH. 2020. Cationic dye removal using novel magnetic/activated charcoal/β-cyclodextrin/alginate polymer nanocomposite. Nanomaterials. 10(1):170. doi:10.3390/nano10010170.
  • Zhang J, Lin S, Han M, Su Q, Xia L, Hui Z. 2020. Adsorption properties of magnetic magnetite nanoparticle for coexistent Cr(VI) and Cu(II) in mixed solution. Water. 12(2):446. doi:10.3390/w12020446.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.