Remediation of Explosive-Contaminated Soils: Alkaline Hydrolysis and Subcritical Water Degradation

References

• Bajpai, R., Parekh, D., Herrmann, S., Popovic, M., Paca, J., and Qasim, M. 2004. A kinetic model of aquoeus-phase alkali hydrolysis of 2,4,6-trinitrotoluene. J. Hazard. Mater. 106B, 55–66.
   Web of Science ®Google Scholar
• Balakrishnan, V.K., Halasz, A., and Hawari, J. 2003. Alkaline hydrolysis of the cyclic nitramine explosives RDX, HMX, and CL-20: New insight into degradation pathways obtained by the observation of novel intermediates. Environ. Sci. Technol. 37, 1838–1843.
   PubMed Web of Science ®Google Scholar
• Bernasconi, C.F. 1971. Kinetic and spectral study of some reactions of 2,4,6-trinitrotoluene in basic solution. I. Deprotonation and Janovsky complex formation. J. Org. Chem. 36, 1671–1679.
   Web of Science ®Google Scholar
• Bradley, P.M. and Chapelle, F.H. 1995. Factors affecting microbial 2,4,6-trinitrotoluene mineralization in contaminated soil. Environ. Sci. Technol. 29, 802–806.
   PubMed Web of Science ®Google Scholar
• Bruns-Nagel, D., Drzyzga, O., Steinbach, K., Schmidt, T.C., Von Löw, E., Gorontzy, T., Blotevogel, K.H., and Gemsa, D. 1998. Anaerobic/aerobic composting of 2,4,6-trinitrotoluene-contaminated soil in a reactor system. Environ. Sci. Technol. 32, 1676–1679.
   Web of Science ®Google Scholar
• Certini, G., Scalenghe, R., and Woods, W.I. 2013. The impact of warfare on the soil environment. Earth-Science Reviews 127, 1–15.
   Web of Science ®Google Scholar
• Dadkhah, A.A. and Akgerman, A. 2002. Hot water extraction with in situ wet oxidation: PAHs removal from soil. J. Hazard. Mater. B93, 307–320.
   Web of Science ®Google Scholar
• DeBano, L.F., Neary, D.G., and Folliott, P.F. 1998. Fire Effects on Ecosystems, Wiley, New York.
   Google Scholar
• Emmrich, M. 1999. Kinetics of the alkaline hydrolysis of 2,4,6-trinitrotoluene in aqueous solution and highly contaminated soils. Environ. Sci. Technol. 33, 3802–3805.
   Web of Science ®Google Scholar
• Emmrich, M. 2001. Kinetics of the alkaline hydrolysis of important nitroaromatic co-contaminants of 2,4,6-trinitrotoluene in highly contaminated soils. Environ. Sci. Technol. 35, 874–877.
   PubMed Web of Science ®Google Scholar
• Felt, D.R., Larson, S.L., and Valente, E.J. 2002. UV-VIS spectroscopy of 2,4,6-trinitrotoluene-hydroxide reaction. Chemosphere 49, 287–295.
   PubMed Web of Science ®Google Scholar
• Hashimoto, S., Watanabe, K., Nose, K., and Morita, M. 2004. Remediation of soil contaminated with dioxins by subcritical water extraction. Chemosphere 54, 89–96.
   PubMed Web of Science ®Google Scholar
• Hawthorne, S.B., Lagadec, A.J. M., Kalderis, D., Lilke, A.V., and Miller, D.J. 2000. Pilot-scale destruction of TNT, RDX, and HMX on contaminated soils using subcritical water. Environ. Sci. Technol. 34, 3224–3228.
   Web of Science ®Google Scholar
• Heilmann, H.M., Wiesmann, U., and Stenstrom, M.K. 1996. Kinetics of the alkaline hydrolysis of high explosives RDX and HMX in aqueous solution and adsorbed to activated carbon. Environ. Sci. Technol. 30, 1485–1492.
   Web of Science ®Google Scholar
• Hill, F.C., Sviatenko, L.K., Gorb, L., Okovytyy, S.I., Blaustein, G.S., and Leszczynski, J. 2012. DFT M06–2X investigation of alkaline hydrolysis of nitroaromatic compounds. Chemosphere 88, 635–643.
   PubMed Web of Science ®Google Scholar
• Hoffsommer, J.C., Kubose, D.A., and Glover, D.J. 1977. Kinetic isotope effects and intermediate formation for the aqueous alkaline homogeneous hydrolysis of 1,3,5-triaza-1,3,5-trinirocyclohexane (RDX). J. Phys. Chem. 81, 380–385.
   Web of Science ®Google Scholar
• Hwang, S., Ruff, T.J., Bouwer, E.J., Larson, S.L., and Davis, J.L. 2005. Applicability of alkaline hydrolysis for remediation of TNT-contaminated water. Water Res. 39, 4503–4511.
   PubMed Web of Science ®Google Scholar
• Juhasz, A.L. and Naidu, R. 2007. Explosives: Fate, dynamics, and ecological impact in terrestrial and marine environments. Rev. Environ. Contam. Toxicol. 191, 163–215.
   PubMed Web of Science ®Google Scholar
• Jung, J.W., Lee, G., Im, S., and Nam, K. 2013, Human health risk assessment of a civilian-accessible active firing range. Hum. Ecol. Risk Assess. 19, 807–818.
   Web of Science ®Google Scholar
• Kalderis, D., Hawthorne, S.B., Clifford, A.A., and Gidarakos, E. 2008. Interaction of soil, water and TNT during degradation of TNT on contaminated soil using subcritical water. J. Hazard. Mater. 159, 329–334.
   PubMed Web of Science ®Google Scholar
• Kronholm, J., Metsälä, H., Hartonen, K., and Riekkola, M.L. 2001. Oxidation of 4-chloro-3-methylphenol in pressurized hot/supercritical water with potassium persulfate as oxidant. Environ. Sci. Technol. 35, 3247–3251.
   PubMed Web of Science ®Google Scholar
• Kubátová, A., Lagadec, A.J. M., and Hawthorne, S.B. 2002. Dechlorination of lindane, dieldrin, tetrachloroethane, trichloroethene, and PVC in subcritical water. Environ. Sci. Technol. 36, 1337–1343.
   PubMed Web of Science ®Google Scholar
• Kuhlmann, B., Arnett, E.M., and Siskin, M. 1994. Classical organic reactions in pure superheated water. J. Org. Chem. 59, 3098–3101.
   Web of Science ®Google Scholar
• Lagadec, A.J. M., Miller, D.J., Lilke, A.V., and Hawthorne, S.B. 2000. Pilot-scale subcritical water remediation of polycyclic aromatic hydrocarbon- and pesticide-contaminated soil. Environ. Sci. Technol. 34, 1542–1548.
   Web of Science ®Google Scholar
• LaGrega, M.D., Buckingham, P.L., and Evans, J.C. 2000. Hazardous Waste Management, 2nd ed., McGraw-Hill, New York.
   Google Scholar
• Li, Z.M., Comfort, S.D., and Shea, P.J. 1997. Destruction of 2,4,6-trinitrotoluene by Fenton oxidation. J. Environ. Qual. 26, 480–487.
   Web of Science ®Google Scholar
• McLellan, W., Hartley, W.R., and Brower, M. 1988. Health Advisory for Hexahydro-1,3,5-trinitro-1,3,5-triazine, Technical Report No. PB90-273533, Office of Drinking Water, U. S. Environmental Protection Agency, Washington, DC.
   Google Scholar
• Mills, A., Setha, A., and Peters, G. 2003. Alkaline hydrolysis of trinitrotoluene, TNT. Phys. Chem. Chem. Phys. 5, 3921–3927.
   Web of Science ®Google Scholar
• Oh, S.Y. and Shin, D.S. 2014. Treatment of diesel-contaminated soil by Fenton and persulfate oxidation with zero-valent iron. Soil Sediment Contam. 23, 180–193.
   Web of Science ®Google Scholar
• Oh, S.Y., Yoon, M.K., Kim, I.H., Kim, J.Y., and Bae, W. 2011. Chemical extraction of arsenic from contaminated soil under subcritical conditions. Sci. Total Environ. 409, 3066–3072.
   PubMed Web of Science ®Google Scholar
• Roberts, D.J., Ahman, F., and Pendharkar, S. 1996. Optimization of an aerobic polishing stage to complete the anaerobic treatment of munitions-contaminated soils. Environ. Sci. Technol. 30, 2021–2026.
   Web of Science ®Google Scholar
• Rogers, J.D. and Bunce, N.J. 2001. Treatment methods for the remediation of nitroaromatic explosives. Water Res. 35, 2101–2111.
   PubMed Web of Science ®Google Scholar
• Siskin, M., Brons, G., Katritzky, A.R., and Balasubramanian, M. 1990. Aquatic organic chemistry. 1. Aquathermolysis: Comparison with thermolysis in the reactivity of aliphatic compounds. Energy & Fuels 4, 475–482.
   Web of Science ®Google Scholar
• Thompson, P.L., Ramer, L.A., and Schnoor, J.L. 1998. Uptake and transformation of TNT by hybrid poplar trees. Environ. Sci. Technol. 32, 975–980.
   Web of Science ®Google Scholar
• Thorne, P.G., Jenkins, T.F., and Brown, M.K. 2004. Continuous Treatment of Low Levels of TNT and RDX in Range Soils Using Surface Liming, ERDC/CRRER TR-04-4, US Army Corps of Engineers Engineer Research and Development Center, Cold Regions Research and Engineering Laboratory, Hanover, NH.
   Google Scholar
• Weber, R., Yoshida, S., and Miwa, K. 2002. PCB destruction in subcritical and supercritical water-evaluation of PCDF formation and initial steps of degradation mechanisms. Environ. Sci. Technol. 36, 1839–1844.
   PubMed Web of Science ®Google Scholar
• Yinon, J. 1990. Toxicity and Metabolism of Explosives, CRC Press, Boca Raton, FL.
   Google Scholar